Tag: M.W=250-300

Wu, Kaiyun published the artcileOne-pot efficient preparation of microcapsules based on photopolymerization for self-healing coatings, Name: Trimethylolpropane triacrylate, the publication is Colloids and Surfaces, A: Physicochemical and Engineering Aspects (2022), 128660, database is CAplus.

Self-healing microcapsules are currently one of the most promising functional materials due to their excellent performance. The preparation of self-healing microcapsules via photopolymerization is quite attractive considering its efficiency and environmental-friendliness. However, the influence of the preparation process and shell-formation materials on the formation and the morphol. of microcapsule have not been systematically researched. This work combines photopolymerization technol. and solvent evaporation to prepare microcapsule, and comprehensively explores the influence of process conditions and shell-formation materials on the microcapsules. Two preparation processes, UV-SR (photopolymerization first and then solvent removal) and SR-UV (solvent removal first and then photopolymerization), have been employed to prepare microcapsules. The SR-UV method is more suitable for preparing microcapsules with high core content and spherical core-shell morphol. The particle size distribution of microcapsules is related to the shear strength during initial emulsion preparation, and the size of microcapsules can be effectively controlled. At the same time, the effect of the shell-formation materials is also systematically studied. The method is universal for the preparation of microcapsules based on com. UV-curable prepolymers, but the introduction of UV-curable monomers may lead to the transformation of microcapsules from core-shell structure to multi-core structure. Microcapsules can be uniformly dispersed in water-borne epoxy, and the coating based on microcapsules exhibits excellent self-healing properties.

Colloids and Surfaces, A: Physicochemical and Engineering Aspects published new progress about 15625-89-5. 15625-89-5 belongs to esters-buliding-blocks, auxiliary class Polymerization Reagents,Crosslinkers, name is Trimethylolpropane triacrylate, and the molecular formula is C8H10O2, Name: Trimethylolpropane triacrylate.

Referemce:
https://en.wikipedia.org/wiki/Ester,
Ester – an overview | ScienceDirect Topics

Chen, Shuqing published the artcileRedox-neutral ortho-C-H amination of pinacol arylborates via palladium(II)/norbornene catalysis for aniline synthesis, Synthetic Route of 1293284-58-8, the publication is Chemical Science (2019), 10(36), 8384-8389, database is CAplus and MEDLINE.

A palladium(II)/norbornene cooperative catalysis enabled redox-neutral ortho-C-H amination of pinacol aryl- or heteroarylborates for the synthesis of structurally diverse anilines was reported. The method was scalable, robust (tolerance of air and moisture), phosphine ligand-free and compatible with a wide range of functionalities. These practical features made this reaction amenable for industry. A plethora of synthetically very useful halogenated anilines which often cannot be prepared via other transition-metal-catalyzed aminations were readily produced using this method. Particularly, the orthogonal reactivity between pinacol arylborates and aryl iodides was demonstrated. Preliminary deuterium-labeling studies revealed a redox-neutral ipso-protonation mechanism of this process, which will surely inspire the future development of this field. Overall, the exceptionally broad scope (47 examples) and reliability of this procedure, together with the wide availability of pinacol arylborates made this chem. a valuable addition to the existing methods for aniline synthesis.

Chemical Science published new progress about 1293284-58-8. 1293284-58-8 belongs to esters-buliding-blocks, auxiliary class Fluoride,Boronic acid and ester,Benzene,Ester,Benzene Compounds,Boronate Esters,Boronic Acids,Boronic acid and ester, name is Methyl 5-fluoro-2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)benzoate, and the molecular formula is C14H18BFO4, Synthetic Route of 1293284-58-8.

Referemce:
https://en.wikipedia.org/wiki/Ester,
Ester – an overview | ScienceDirect Topics

Wu, Hao published the artcileDesign of High-Humidity-Proof Hierarchical Porous P-ZIF-67(Co)-Polymer Composite Materials by Surface Modification for Highly Efficient Volatile Organic Compound Adsorption, COA of Formula: C15H20O6, the publication is Industrial & Engineering Chemistry Research (2022), 61(10), 3591-3600, database is CAplus.

The ubiquitous water vapor in industrial gas is a challenge for volatile organic compound (VOC) adsorbents. Herein, we have developed a strategy to improve the hydrophobicity and water stability of ZIF-67(Co) through internal and external modification. Through amine modification of the carrier surface rich in nanoscale roughness, the shape and size of ZIF-67(Co) are changed. ZIF-67(Co) is uniformly anchored on the macroporous surface of polyacrylates (PA) through interface coordination, forming a unique hierarchical porous structure. Compared with the original ZIF-67(Co), the toluene adsorption efficiency of ZIF-67(Co)@PA is increased by 2.75 times at 298 K and at a toluene partial pressure of P/P₀ = 0.005. Furthermore, to inhibit undesired water adsorption due to the rich defect sites, hydrophobically modified ZIF-67(Co)@PA (yielding P-ZIF-67(Co)@PA) has also been prepared, which exhibits a slight decrease in toluene adsorption and maintains the advantages of low water vapor adsorption and high hydrophobicity to improve the water stability of ZIF-67(Co).

Industrial & Engineering Chemistry Research published new progress about 15625-89-5. 15625-89-5 belongs to esters-buliding-blocks, auxiliary class Polymerization Reagents,Crosslinkers, name is Trimethylolpropane triacrylate, and the molecular formula is C8H8O3, COA of Formula: C15H20O6.

Referemce:
https://en.wikipedia.org/wiki/Ester,
Ester – an overview | ScienceDirect Topics

Sun, Bingyan published the artcileFully cross-linked UV-induced peelable acrylic PSA prepared from a dual curable castor oil based urethane acrylate oligomer for wafer dicing, Category: esters-buliding-blocks, the publication is Progress in Organic Coatings (2022), 106680, database is CAplus.

For UV-induced peelable PSA used in the wafer dicing process, improving the peel performance can effectively increase the process reliability and the yield of subsequent packaging process. In this work, a NCO-containing castor oil-based urethane acrylate oligomer called CO-PUB with dual curable functions (UV-induced polymerization and NCO/OH reaction) was obtained by partially sealing a castor oil-based urethane oligomer with hydroxyethyl acrylate. Fourier transform IR spectroscopy (FTIR) and NMR spectrometer (NMR) results indicated that CO-PUB was successfully prepared CO-PUB, OH-containing acrylic copolymer, multifunctional acrylate monomer and photo-initiator were used to construct a UV-induced peelable adhesive for silicon wafer dicing. The results showed that NCO groups in CO-PUB underwent the NCO/OH reaction with the acrylic copolymer to obtain a vinyl pendant cross-linked acrylic copolymer. The peel strength of this peelable adhesive before UV irradiation could exceed 20 N/25 mm. After UV irradiation, the unsaturated vinyl bonds contained in it were copolymerized with the multifunctional acrylate monomer to form a fully cross-linked adhesive film and the peel strength could be reduced to below 1 N/25 mm. Compared with UV-induced peelable adhesives prepared by other reported curing agents, the adhesive prepared from CO-PUB reduced UV dose required for curing. The crosslinking degree of cured adhesive film was also increased and the gel content was up to 95%. The residual adhesive after peeling off could be reduced to about 0.32%. In addition, CO-PUB used renewable castor oil as polyol and did not need to add any organic solvent during the preparation process, providing a new idea for the green preparation of UV-induced peelable adhesive with excellent performances.

Progress in Organic Coatings published new progress about 15625-89-5. 15625-89-5 belongs to esters-buliding-blocks, auxiliary class Polymerization Reagents,Crosslinkers, name is Trimethylolpropane triacrylate, and the molecular formula is C3H8N2S, Category: esters-buliding-blocks.

Referemce:
https://en.wikipedia.org/wiki/Ester,
Ester – an overview | ScienceDirect Topics

Liang, Shaofeng published the artcileRecyclable, UV-Blocking, and Radiative Cooling Multifunctional Composite Membranes, HPLC of Formula: 15625-89-5, the publication is ACS Omega (2022), 7(29), 25244-25252, database is CAplus and MEDLINE.

It is well known that UV radiation can cause human health problems and that energy consumption can lead to human survival problems. Here, we prepared a composite membrane that can block UV radiation as well as reduce energy consumption. Carbon dots (CDs) and acrylates were prepared from xylose and epoxidized soybean oil as biomass feedstocks, resp., and the composite membrane was prepared by a self-assembly strategy. The first layer of the membrane is composed of CDs and epoxy resin. Its main function is not only to weaken UV rays and the aggregation-induced quenching effect of CDs but also to reduce the absorption of UV rays by the second layer of the membrane. The second layer consists of barium sulfate (BaSO₄) and acrylate. Compared to TiO₂ (3.2 eV), BaSO₄ (~6 eV) has a higher electronic band gap, which reduces the absorption of UV light by the membrane. The composite membrane exhibits excellent UV-blocking and radiative cooling performance, shielding 99% of UV rays. In addition, the membrane can reduce 4.4°C in radiative cooling tests, achieving a good cooling effect. Finally, the recyclability of the BaSO₄/acrylate membrane is discussed, and 95% recovery rate provides sustainable utilization of the membrane. The composite membrane is expected to be popularized and used in low latitudes and areas with high temperature and high UV radiation near the equator.

ACS Omega published new progress about 15625-89-5. 15625-89-5 belongs to esters-buliding-blocks, auxiliary class Polymerization Reagents,Crosslinkers, name is Trimethylolpropane triacrylate, and the molecular formula is C15H20O6, HPLC of Formula: 15625-89-5.

Referemce:
https://en.wikipedia.org/wiki/Ester,
Ester – an overview | ScienceDirect Topics

Xiao, Dingtian published the artcileDevelopment of agricultural waste/recycled plastic/waste oil bio-composite wallpaper based on two-phase dye and liquefaction filling technology, Application In Synthesis of 142-90-5, the main research area is agricultural waste recycled plastic oil biocomposite dye liquefaction technol; Garbage reuse; Green products; Novel dyeing technology; Processing system.

In this paper, a complete biomass composite processing system based on agricultural waste powders, recycled plastics, and waste oil is proposed. The wood-colored wallpaper, the green wallpaper, and the blue wallpaper are produced by this processing system. These wallpapers are new products with low cost, high added value, and environmental friendliness. These wallpapers have also been systematically tested. Based on the anal. of test results, a 3D model of material formation mechanism, liquefaction filling technol., and hybrid network model construction technol. are obtained. The experiment found the reasonable RLDPE and RLLDPE ratio (1:0.26), the reasonable ratio of biomass to specialty solvents (1:1.5), the reasonable dose of the solid dye (3%), and the reasonable concentration of dye solutions Wood-colored bio-composite wallpaper products have a smooth surface, wood color (ΔE = 36.7), natural aroma, and good comprehensive mech. properties (tensile strength 9.255 MPa; elongation at break 20.998%; Young’s modulus 2229.475 MPa). The processing system and wallpaper products in this article not only promote the plastic recycling economy and sustainable agricultural development but also provide new channels for the development of waste oil reuse and new ideas for the development of high value-added biocomposite materials.

Environmental Science and Pollution Research published new progress about Agricultural wastes. 142-90-5 belongs to class esters-buliding-blocks, name is Dodecyl 2-methylacrylate, and the molecular formula is C16H30O2, Application In Synthesis of 142-90-5.

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

Marquez-Lemus, Mario published the artcileAssessment of the variation of the volatile compound composition and antioxidant activity in Opuntia fruits liquors during the maceration process, Computed Properties of 41114-00-5, the main research area is volatile compound antioxidant Opuntia fruit liquor maceration.

Opuntia genus belongs to the Cactaceae family, Mexico is the major producer in the world. Due to Opuntia’s phytochem. content and their health-related benefits, was proposed the elaboration of liquor using Opuntia fruit. Phenolic content, volatile aromatic profile, antioxidant activity, and sensory evaluation were carried out to characterize the liquor. Sensorial evaluation results showed that L-2D (2 day-macerated liquor) has the higher consumers’ acceptance. Moreover, L-2D had the highest content of volatile compounds (348 mg/L), and the highest antioxidant activity (1.29, 1.63 and 2.05 mmol Trolox/L, according to ABTS, DPPH and FRAP methods, resp.). We could identify and quantify 29 volatile compounds, being Et acetate and D-limonene those with the highest content. Quercitrin was the most abundant phenolic compound in the liquor. The findings of this study demonstrate that Opuntia liquor is a rich source of phenolics and aromatic compounds that would be a drink with the probability of being commercialize.

CyTA–Journal of Food published new progress about Alcoholic beverages. 41114-00-5 belongs to class esters-buliding-blocks, name is Ethyl pentadecanoate, and the molecular formula is C17H34O2, Computed Properties of 41114-00-5.

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

Wan, Xizi published the artcileWET-Induced Layered Organohydrogel as Bioinspired “”Sticky-Slippy Skin”” for Robust Underwater Oil-Repellency, Application In Synthesis of 142-90-5, the main research area is nanoclay organohydrogel underwater superoleophobicity; anti-oil-fouling; interfacial adhesion; sticky−slippy skin; underwater superoleophobicity; wetting-enabled-transfer.

Underwater superoleophobic surfaces featuring anti-oil-fouling properties are of great significance in widespread fields. However, their complicated engineering process and weak interfacial adhesion strength with underlying substrates severely hamper these ideal surfaces toward practical applications. Here, a moss-inspired sticky-slippy skin composed of layered organohydrogel is reported through a one-step wetting-enabled-transfer (WET) strategy, which unprecedentedly integrates robust inherent adhesion with durable anti-oil-fouling properties. The sticky organogel layer can be simply attached to various substrates, from metals and plastics to glass, independent of any surface pretreatment. The slippy hydrogel layer enables stable underwater superoleophobicity and ultralow oil adhesion for diverse kinds of oils. The sticky-slippy skin features outstanding comprehensive properties including easy-pasting, anti-swelling/anti-bending, compatibility with com. adhesives, acid/alkali resistance, environmental friendliness, and substrate universality. The design strategy with integrated functions provides a clue to accelerate the development of bioinspired multifunctional interfacial materials toward real-world applications.

Advanced Materials (Weinheim, Germany) published new progress about Abrasion resistance. 142-90-5 belongs to class esters-buliding-blocks, name is Dodecyl 2-methylacrylate, and the molecular formula is C16H30O2, Application In Synthesis of 142-90-5.

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

Cai, Liqin published the artcileChanges of bioactive substances in lactic acid bacteria and yeasts fermented kiwifruit extract during the fermentation, Recommanded Product: Ethyl pentadecanoate, the main research area is lactic acid bacteria yeast kiwifruit extract fermentation bioactive substance.

Probiotic fermented fruit extract is a new kind of food with potential health care efficacy. In this study, transformation of bioactive substances in Lactic acid bacteria (LAB) and yeast fermented kiwifruit extract were researched. The highest levels of total polyphenol, superoxide dismutase (SOD) were found in Lactobacillus paracasei LG0260 fermented kiwifruit extract with 2.31 ± 0.06 mgGAE/g, 369 ± 12.73 U.mL-1, resp. LAB fermented kiwifruit extract dramatically had a highest vitamin C (VitC) concentration during the fermentation, while yeast and natural fermented samples were decline steadily. Another interesting founding, a highest level of γ-aminobutyric acid (GABA) was found in Saccharomyces cerevisiae J2861 fermented kiwifruit extract with 24.132 ± 1.01μg/mL. Furthermore, the main organic acids in fresh kiwifruit and yeast fermented kiwifruit extract were citric acid and malic acid. However, lactic acid and citric acid were the main organic acids in LAB fermented kiwifruit extract A total of 43 kinds of flavor compounds in fresh kiwifruit and 88 kinds of flavor compounds in fermented kiwifruit extract were identified. Esters and alcs. in fermented kiwifruit system increased by the fermentation of selected bacteria which improved the taste and flavor.

LWT–Food Science and Technology published new progress about Actinidia chinensis. 41114-00-5 belongs to class esters-buliding-blocks, name is Ethyl pentadecanoate, and the molecular formula is C17H34O2, Recommanded Product: Ethyl pentadecanoate.

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

Seto, Ryota published the artcileSynthesis of block copolymers through umpolung or treatment of propagating end of living cationic polytetrahydrofuran, Computed Properties of 142-90-5, the main research area is living polytetrahydrofuran anionic radical block polymerization diblock copolymer.

Block copolymers containing polyTHF segments were synthesized by umpolung or propagating end of the cationic living polymer and successive anionic polymerization of methacrylates (RMAs) or radical polymerization of RMAs, acrylonitrile (AN), and styrene (St). Living polyTHF (poly-THF) was prepared by cationic polymerization of THF, whose propagation end was reduced by Sm(II) iodide (SmI2). Anionic polymerizations of RMAs were conducted by addition of the monomers to the reduced poly-THF to obtain poly(THF-b-RMAs). However, the 2-bromoisobutyrate group, which can act as an initiator of radical polymerization, was introduced to the cationic propagating end of poly-THF by adding Na 2-bromoisobutyrate. Block copolymers were synthesized by living radical polymerization of RMAs, St, or AN using the 2-bromoisobutyrate-capped poly-THF as a macroinitiator and Cu(I) bromide (CuBr) as a catalyst.

Polymer Bulletin (Heidelberg, Germany) published new progress about Block polymerization. 142-90-5 belongs to class esters-buliding-blocks, name is Dodecyl 2-methylacrylate, and the molecular formula is C16H30O2, Computed Properties of 142-90-5.

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics