Category: 936-03-8

Recommanded Product: 936-03-8On June 3, 2004, Fache, Fabienne; Piva, Olivier published an article in Synlett. The article was 《Hexafluoroisopropanol: A powerful solvent for the hydrogenation of functionalized aromatic compounds》. The article mentions the following:

Various substituted aromatic compounds have been reduced under H2 using RuCl3. The fluorous solvent hexafluoroisopropanol turned out to be particularly efficient in the case of compounds difficult to reduce in organic solvents. In the experiment, the researchers used many compounds, for example, Cis-methyl 2-hydroxycyclohexanecarboxylate(cas: 936-03-8Recommanded Product: 936-03-8)

Cis-methyl 2-hydroxycyclohexanecarboxylate(cas: 936-03-8) belongs to esters. They are important in biology, being one of the main classes of lipids and comprising the bulk of animal fats and vegetable oils.Recommanded Product: 936-03-8 They perform as high-grade solvents for a broad array of plastics, plasticizers, resins, and lacquers, and are one of the largest classes of synthetic lubricants on the commercial market. Polyesters are important plastics, with monomers linked by ester moieties.

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

In 1967,Tetrahedron included an article by Baumann, Helmut; Franklin, Norman C.; Moehrle, Hans. Related Products of 936-03-8. The article was titled 《Configurations and conformations of 2-carboxycyclopentanols and the corresponding methyl and ethyl esters》. The information in the text is summarized as follows:

The N.M.R. spectra of cis- and trans-2-carboxycyclopentanol and the corresponding methyl and ethyl esters were measured, and from the chem. shift of the proton adjacent to the OH group and the band width of this signal, it was possible to assign the configurations of these pairs of isomers. The difference in chem. shift for this proton in the two isomers was considerably smaller than that found in the corresponding cyclohexane derivatives, a pair of which were measured. Thus, only when the compounds are extremely pure is it possible to assign the configurations in this way. The most stable conformations of trans-2-carboxycyclopentanol are I, II, and III. In the experiment, the researchers used Cis-methyl 2-hydroxycyclohexanecarboxylate(cas: 936-03-8Related Products of 936-03-8)

Cis-methyl 2-hydroxycyclohexanecarboxylate(cas: 936-03-8) belongs to esters. Esters are more polar than ethers but less polar than alcohols. Related Products of 936-03-8 They participate in hydrogen bonds as hydrogen-bond acceptors, but cannot act as hydrogen-bond donors, unlike their parent alcohols.

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

Liardo, Elisa; Rios-Lombardia, Nicolas; Moris, Francisco; Gonzalez-Sabin, Javier; Rebolledo, Francisca published an article in Organic Letters. The title of the article was 《Developing a Biocascade Process: Concurrent Ketone Reduction-Nitrile Hydrolysis of 2-Oxocycloalkanecarbonitriles》.Related Products of 936-03-8 The author mentioned the following in the article:

A stereoselective bioreduction of 2-oxocycloalkanecarbonitriles was concurrently coupled to a whole cell-catalyzed nitrile hydrolysis in one-pot. The first step, mediated by ketoreductases, involved a dynamic reductive kinetic resolution, which led to 2-hydroxycycloalkanenitriles in very high enantio- and diastereomeric ratios. Then, the simultaneous exposure to nitrile hydratase and amidase from whole cells of Rhodococcus rhodochrous provided the corresponding 2-hydroxycycloalkanecarboxylic acids with excellent overall yield and optical purity for the all-enzymic cascade. The results came from multiple reactions, including the reaction of Cis-methyl 2-hydroxycyclohexanecarboxylate(cas: 936-03-8Related Products of 936-03-8)

Cis-methyl 2-hydroxycyclohexanecarboxylate(cas: 936-03-8) belongs to esters. They are important in biology, being one of the main classes of lipids and comprising the bulk of animal fats and vegetable oils.Related Products of 936-03-8 Polyesters are important plastics, with monomers linked by ester moieties.

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

SDS of cas: 936-03-8On September 17, 1999 ,《Efficient cyclization of ω-oxo-α,β-unsaturated esters using lithium thiolate-initiated Michael-aldol tandem reaction》 was published in Tetrahedron Letters. The article was written by Ono, Masashi; Nishimura, Katsumi; Nagaoka, Yasuo; Tomioka, Kiyoshi. The article contains the following contents:

The reaction of ω-oxo-α,β-unsaturated esters with lithium thiolates afforded the Michael-aldol tandem cyclization products in good to perfect stereoselectivity depending on the nature of thiolates. For example, cyclization of 7-oxo-2-heptenoic acid Me ester with lithium phenylthiolate gave (1R,2S,6S)-rel-2-Hydroxy-6-(phenylthio)cyclohexanecarboxylic acid Me ester and (1R,2R,6S)-rel-2-Hydroxy-6-(phenylthio)cyclohexanecarboxylic acid Me ester. The latter were transformed into cis-2-hydroxycyclohexanecarboxylic acid Me ester and cis-2-hydroxycyclohexanecarboxylic acid Me ester, resp.Cis-methyl 2-hydroxycyclohexanecarboxylate(cas: 936-03-8SDS of cas: 936-03-8) was used in this study.

Cis-methyl 2-hydroxycyclohexanecarboxylate(cas: 936-03-8) belongs to esters. Esters are more polar than ethers but less polar than alcohols. SDS of cas: 936-03-8 They participate in hydrogen bonds as hydrogen-bond acceptors, but cannot act as hydrogen-bond donors, unlike their parent alcohols.

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

The author of 《Conversion of isoxazolines to β-hydroxy esters. Synthesis of 2-deoxy-D-ribose》 were Caldirola, P.; Ciancaglione, M.; De Amici, M.; De Micheli, C.. And the article was published in Tetrahedron Letters in 1986. Related Products of 936-03-8 The author mentioned the following in the article:

A simple and efficient preparation of β-hydroxy esters with a well-defined stereochem. was developed using 3-bromoisoxazolines as key-intermediates. A synthesis of 2-deoxy-D-ribose is also reported. Thus, BuCH:CH2 underwent cycloaddition with BrNCO to give the isoxazoline I (R = Br), which was treated with MeOLi and the resulting I (R = MeO) underwent hydrogenolysis-hydrolysis to give BuCH(OH)CH2CO2Me. In the experiment, the researchers used many compounds, for example, Cis-methyl 2-hydroxycyclohexanecarboxylate(cas: 936-03-8Related Products of 936-03-8)

Cis-methyl 2-hydroxycyclohexanecarboxylate(cas: 936-03-8) belongs to esters. They are important in biology, being one of the main classes of lipids and comprising the bulk of animal fats and vegetable oils.Related Products of 936-03-8 They perform as high-grade solvents for a broad array of plastics, plasticizers, resins, and lacquers, and are one of the largest classes of synthetic lubricants on the commercial market.

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

《Diastereoselective and enantioselective microbial reduction of cyclic α-alkyl β-keto esters》 was published in Tetrahedron Letters in 1986. These research results belong to Buisson, Didier; Azerad, Robert. Safety of Cis-methyl 2-hydroxycyclohexanecarboxylate The article mentions the following:

The reduction of racemic cyclopenta- and cyclohexanone 2-carboxyesters by various yeast and mold strains produced different amounts of isomeric β-hydroxyesters with predominant (1S) stereochem. With several strains, only one optically pure cis or trans stereoisomer was obtained in high yield, indicating a diastereoselective and enantioselective reduction In the part of experimental materials, we found many familiar compounds, such as Cis-methyl 2-hydroxycyclohexanecarboxylate(cas: 936-03-8Safety of Cis-methyl 2-hydroxycyclohexanecarboxylate)

Cis-methyl 2-hydroxycyclohexanecarboxylate(cas: 936-03-8) belongs to esters. Esters are more polar than ethers but less polar than alcohols. Safety of Cis-methyl 2-hydroxycyclohexanecarboxylate They participate in hydrogen bonds as hydrogen-bond acceptors, but cannot act as hydrogen-bond donors, unlike their parent alcohols. This ability to participate in hydrogen bonding confers some water-solubility.

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

The author of 《Favorskii reactions of α-halo-α,β-unsaturated monocyclic ketones》 were Khawd, Ibrahim E.; Iskander, George M.. And the article was published in Revue Roumaine de Chimie in 1980. Electric Literature of C8H14O3 The author mentioned the following in the article:

I (R = Br, Cl) undergoes the Favorskii reaction in MeONa-MeOH to give II (R = OH, OMe), and III, formed via the intermediacy of IV which is itself the eventual product of V itself formed in the initial double bond isomerization of I. VI under these conditions gives VII and VIII gives IX in methanolic acid. The experimental process involved the reaction of Cis-methyl 2-hydroxycyclohexanecarboxylate(cas: 936-03-8Electric Literature of C8H14O3)

Cis-methyl 2-hydroxycyclohexanecarboxylate(cas: 936-03-8) belongs to esters. They are important in biology, being one of the main classes of lipids and comprising the bulk of animal fats and vegetable oils.Electric Literature of C8H14O3 Polyesters are important plastics, with monomers linked by ester moieties.

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

Reference of Cis-methyl 2-hydroxycyclohexanecarboxylateOn September 21, 1984 ,《Reduction of substituted Δ2-isoxazolines. Synthesis of β-hydroxy acid derivatives》 was published in Journal of Organic Chemistry. The article was written by Curran, Dennis P.; Scanga, Susan A.; Fenk, Christopher J.. The article contains the following contents:

Three methods are reported for the preparation of β-hydroxy acid derivatives from readily available substituted Δ2-isoxazolines. Cycloaddition of nitrile oxide Me3CCNO with a variety of olefins followed by reductive cleavage gave α’-tert-Bu β-hydroxy ketones, which are cleaved to β-hydroxy tert-Bu esters by Baeyer-Villiger oxidation with CF3CO2OH. Thus, use of styrene gave isoxazoline I, PhCH(OH)CH2COCMe3, and then PhCH(OH)CH2CO2CMe3. In the 2nd approach, α’,β-dihydroxy ketones are generated via cycloaddition of olefins with Me3SiOCMe2CNO, followed by reductive ring opening. Standard periodic acid cleavage gives β-hydroxy acids. Finally, 3-methoxy-substituted Δ2-isoxazolines, readily available via benzenesulfonylcarbonitrile oxide-olefin cycloaddition and methoxide displacement, are directly reduced to β-hydroxy esters. The experimental process involved the reaction of Cis-methyl 2-hydroxycyclohexanecarboxylate(cas: 936-03-8Reference of Cis-methyl 2-hydroxycyclohexanecarboxylate)

Cis-methyl 2-hydroxycyclohexanecarboxylate(cas: 936-03-8) belongs to esters. They are important in biology, being one of the main classes of lipids and comprising the bulk of animal fats and vegetable oils.Reference of Cis-methyl 2-hydroxycyclohexanecarboxylate They perform as high-grade solvents for a broad array of plastics, plasticizers, resins, and lacquers, and are one of the largest classes of synthetic lubricants on the commercial market. Polyesters are important plastics, with monomers linked by ester moieties.

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

The author of 《An infrared study of methyl cis- and trans-2-hydroxycycloalkanecarboxylates》 were Castells, Jose; Palau, Jaime. And the article was published in Journal of the Chemical Society in 1964. Name: Cis-methyl 2-hydroxycyclohexanecarboxylate The author mentioned the following in the article:

The positions and shapes of the OH and CO ir absorption bands of the cis and trans isomers of Me 2-hydroxycyclopentanecarboxylate, 2-hydroxycyclohexanecarboxylate, and 2-hydroxycycloheptanecarboxylate have been studied under successive dilutions in CCl4. The clear-cut distinction found between the behavior of the cis and trans isomers, which can be rationalized on the basis of intra- and/or intermol. H-bonding, may be used for diagnostic purposes. The finer details of the spectra are discussed with relation to the geometry of the rings. In the experimental materials used by the author, we found Cis-methyl 2-hydroxycyclohexanecarboxylate(cas: 936-03-8Name: Cis-methyl 2-hydroxycyclohexanecarboxylate)

Cis-methyl 2-hydroxycyclohexanecarboxylate(cas: 936-03-8) belongs to esters. They are important in biology, being one of the main classes of lipids and comprising the bulk of animal fats and vegetable oils.Name: Cis-methyl 2-hydroxycyclohexanecarboxylate They perform as high-grade solvents for a broad array of plastics, plasticizers, resins, and lacquers, and are one of the largest classes of synthetic lubricants on the commercial market.

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

COA of Formula: C8H14O3On March 31, 2014, Gaudin, Jean-Marc published an article in Flavour and Fragrance Journal. The article was 《The quest for odorants having salicylate notes》. The article mentions the following:

We describe the synthesis and sensory characterization of a series of compounds which we anticipated would possess the olfactory notes of salicylates. We explored carba-analogs, cyclic β-keto esters and cyclic β-diketones as salicylate analogs. Applying the simple concept of three-dimensional structure similarity was very fruitful. Salicylate carba-analogs and β-keto esters, especially compounds 5, 7 and 10 for the first series and 27 and 28 for the second series, proved to be the most interesting type of compounds For example, 1-(2-hydroxyphenyl)-3-phenyl-1-propanone (10), which can be found in nature, is nicely diffusive and has an excellent olfactory profile with an interesting dual floral-animal note. In general, these compounds may offer a first credible alternative to the popular salicylates. Copyright © 2013 John Wiley & Sons, Ltd. After reading the article, we found that the author used Cis-methyl 2-hydroxycyclohexanecarboxylate(cas: 936-03-8COA of Formula: C8H14O3)

Cis-methyl 2-hydroxycyclohexanecarboxylate(cas: 936-03-8) belongs to esters. They are important in biology, being one of the main classes of lipids and comprising the bulk of animal fats and vegetable oils.COA of Formula: C8H14O3 They perform as high-grade solvents for a broad array of plastics, plasticizers, resins, and lacquers, and are one of the largest classes of synthetic lubricants on the commercial market.

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics