872-36-6 Archives - Page 6 of 10 - Esters-buliding-blocks

Aupperle, Felix’s team published research in ACS Applied Energy Materials in 2019 | CAS: 872-36-6

Vinylene carbonate(cas: 872-36-6) belongs to esters. Alkyl carbonates find applications as solvents for lithium ion battery electrolytes and the use of high quality battery grade electrolytes having extremely low water (<10 ppm) and acid (<10 ppm) contents are critical for achieving high electrochemical performance.Product Details of 872-36-6

The author of 《The Role of Electrolyte Additives on the Interfacial Chemistry and Thermal Reactivity of Si-Anode-Based Li-Ion Battery》 were Aupperle, Felix; von Aspern, Natascha; Berghus, Debbie; Weber, Felix; Eshetu, Gebrekidan Gebresilassie; Winter, Martin; Figgemeier, Egbert. And the article was published in ACS Applied Energy Materials in 2019. Product Details of 872-36-6 The author mentioned the following in the article:

Si has gained huge attention as an anode material for next-generation high-capacity Li-ion batteries (LIBs). However, despite its overwhelming beneficial features, its large-scale commercialization is hampered due to unavoidable challenges such as colossal volume change during (de)alloying, inherent low electronic and ionic conductivities, low Coulombic efficiency, unstable/dynamic solid electrolyte interphase (SEI), electrolyte drying and so forth. Among other strategies, the use of a fraction dose of chem. additives is hailed as the most effective, economic and scalable approach to realize Si-anode-based LIBs. Functional additives can modify the nature and chem. composition of the SEI, which in turn dictates the obtainable capacity, rate capability, Coulombic/energy efficiency, safety, and so forth of the battery system. Thus, we report a systematic and comparative study of various electrolyte additives, namely, tetraethoxysilane (TEOS), (2-cyanoethyl)triethoxysilane (TEOSCN), vinylene carbonate (VC), fluoroethylene carbonate (FEC), and a blend of TEOSCN, VC, and FEC (i.e., VC/FEC/TEOSCN) using electrochem. anal., XPS, d. functional theory calculation, and differential scanning calorimetry. The ternary mixture (FEC/VC/TEOSCN) results in a thinner SEI layer consisting of high shear modulus SEI-building species (mainly LiF). It also provides much improved thermal stability amid all tested additives, showing its potentiality to enable high capacity and safer Si-based anode LIBs. Thus, nitrile-functionalized silanes are highly promising electrolyte additives to boost the electrochem. performance and safety-induced risks of Si-based anode LIBs, emanating from the formation of a robust SEI layer. After reading the article, we found that the author used Vinylene carbonate(cas: 872-36-6Product Details of 872-36-6)

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

Arai, Hajime’s team published research in Journal of Physical Chemistry C in 2021 | CAS: 872-36-6

Arai, Hajime; Yaguchi, Atsuko; Nishimura, Yoshihiro; Akimoto, Yuya; Ikezawa, Atsunori published an article in 2021. The article was titled 《Operando Optical Analysis of LiFePO4 Composite Electrodes》, and you may find the article in Journal of Physical Chemistry C.Quality Control of Vinylene carbonate The information in the text is summarized as follows:

Elucidating reaction inhomogeneity of composite electrodes is key to improve the performances of batteries such as rate capability and durability. Because the reaction inhomogeneity often disappears after a certain relaxation period, operando anal. techniques are indispensable. We hereby propose that operando optical anal. as a common lab method can be applied to visualize the reaction inhomogeneity of LiFePO4 composite electrodes for lithium-ion batteries with sufficient space and time resolutions The results indicate that the brightness of the charged phase was higher than that of the discharged phases, which can be used to sep. the phases and thus to elucidate the reaction inhomogeneity in the cross section of the composite electrode. A metastable phase Li3/4FePO4 was also captured at a low temperature with the optical anal. In the experiment, the researchers used Vinylene carbonate(cas: 872-36-6Quality Control of Vinylene carbonate)

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

Wang, Hui’s team published research in ACS Applied Materials & Interfaces in 2021 | CAS: 872-36-6

Formula: C3H2O3In 2021 ,《InSitu-Formed Artificial Solid Electrolyte Interphase for Boosting the Cycle Stability of Si-Based Anodes for Li-Ion Batteries》 was published in ACS Applied Materials & Interfaces. The article was written by Wang, Hui; Miao, Mouren; Li, Hui; Cao, Yuliang; Yang, Hanxi; Ai, Xinping. The article contains the following contents:

Si is being actively developed as one of the most promising high-capacity anodes for next-generation lithium-ion batteries (LIBs). However, low cycling coulombic efficiency (CE) due to the repetitive growth of the solid electrolyte interphase (SEI) film is still an issue for its application in full batteries. Here, we propose a strategy to in situ form an artificial solid electrolyte interphase (ASEI) on the ferrosilicon/carbon (FeSi/C) anode surface by a purposely designed nucleophilic reaction of polysulfides with vinylene carbonate (VC) and fluoroethylene carbonate (FEC) mols. The as-formed ASEI layer is mech. dense and ionically conducting and therefore can effectively prevent the electrolyte infiltration and decomposition while allowing Li+ transport across, thus stabilizing the interface of the FeSi/C anode. As a result, the ASEI-modified FeSi/C anode exhibits a large reversible capacity of 1409.4 mA h g-1, an excellent cycling stability over 650 cycles, and a greatly elevated cycling CE of 99.8%, possibly serving as a high-capacity anode of LIBs. The results came from multiple reactions, including the reaction of Vinylene carbonate(cas: 872-36-6Formula: C3H2O3)

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

Chen, Suli’s team published research in ACS Applied Materials & Interfaces in 2019 | CAS: 872-36-6

《Poly(vinylene carbonate)-Based Composite Polymer Electrolyte with Enhanced Interfacial Stability To Realize High-Performance Room-Temperature Solid-State Sodium Batteries》 was written by Chen, Suli; Che, Haiying; Feng, Fan; Liao, Jianping; Wang, Hong; Yin, Yimei; Ma, Zi-Feng. Category: esters-buliding-blocksThis research focused onvinylene carbonate composite polymer electrolyte rechargeable sodium battery safety; composite polymer electrolyte; high ionic conductivity; in situ solidification; interfacial stability; poly(vinylene carbonate); solid-state sodium batteries. The article conveys some information:

Solid-state rechargeable batteries using polymer electrolytes have been considered, which can avoid safety issues and enhance energy d. However, com. application of the polymer electrolyte solid-state battery is still significantly limited by the low room-temperature ionic conductivity, poor mech. properties, and weak interfacial compatibility between the electrolyte and electrode, especially for the room-temperature solid-state rechargeable battery. In this work, a poly(vinylene carbonate)-based composite polymer electrolyte (PVC-CPE) is reported for the first time to realize room-temperature solid-state sodium batteries with high performances. This in situ solidified PVC-CPE possesses superior ionic conductivity (0.12 mS cm-1 at 25°), high Na+ transference number of 0.60, as well as enhanced electrode/electrolyte interfacial stability. Notably, the composite cathode NaNi1/3Fe1/3Mn1/3O2 (c-NFM) is designed through the in situ growth of the polymer electrolyte inside the electrode to decrease interfacial resistance and facilitate effective ion transport in electrode/electrolyte interfaces. It is demonstrated that the solid-state c-NFM/PVC-CPE/Na battery assembled by a one-step in situ solidification method exhibits remarkably enhanced cell performances at room temperature compared with a reference NFM/PVC-CPE/Na assembled through a conventional ex situ method. The battery presents a high initial specific capacity of 104.2 mA h g-1 at 0.2 C with a capacity retention of 86.8% over 250 cycles and ∼80.2 mA h g-1 at 1 C. This study suggests that PVC-CPE is a very promising electrolyte for solid-state sodium batteries. This study also suggests a new method to design high-performance polymer electrolytes for other solid-state rechargeable batteries to realize high safety and considerable electrochem. performance at room temperature In addition to this study using Vinylene carbonate, there are many other studies that have used Vinylene carbonate(cas: 872-36-6Category: esters-buliding-blocks) was used in this study.

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

Wang, Liang’s team published research in Asian Journal of Organic Chemistry in 2021 | CAS: 872-36-6

Wang, Liang; Jiang, Kuan-chang; Zhang, Nana; Zhang, Zhi-hui published an article in 2021. The article was titled 《Rhodium-Catalyzed Synthesis of Isoquinolino[1,2-b]Quinazolines via C-H Annulation in Biomass-Derived γ-Valerolactone》, and you may find the article in Asian Journal of Organic Chemistry.Synthetic Route of C3H2O3 The information in the text is summarized as follows:

A rhodium-catalyzed synthesis of isoquinolino[1,2-b]quinazolines via C-H annulation using vinylene carbonate as an oxidizing acetylene surrogate in biomass-derived γ-valerolactone (GVL) was developed. The reactions proceeded smoothly to give the corresponding products in moderate to good yields without any external oxidant and base. This protocol was applied for the synthesis of 5,6-dihydro-8H-isoquinolino[1,2-b]quinazolin-8-ones. In the part of experimental materials, we found many familiar compounds, such as Vinylene carbonate(cas: 872-36-6Synthetic Route of C3H2O3)

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

Parhizi, Mohammad’s team published research in Energies (Basel, Switzerland) in 2022 | CAS: 872-36-6

In 2022,Parhizi, Mohammad; Caceres-Martinez, Louis Edwards; Modereger, Brent A.; Kenttamaa, Hilkka I.; Kilaz, Gozdem; Ostanek, Jason K. published an article in Energies (Basel, Switzerland). The title of the article was 《Determining the Composition of Carbonate Solvent Systems Used in Lithium-Ion Batteries without Salt Removal》.SDS of cas: 872-36-6 The author mentioned the following in the article:

In this work, two methods were investigated for determining the composition of carbonate solvent systems used in lithium-ion (Li-ion) battery electrolytes. One method was based on comprehensive two-dimensional gas chromatog. with electron ionization time-of-flight mass spectrometry (GCxGC/EI TOF MS), which often enables unknown compound identification by their electron ionization (EI) mass spectra. The other method was based on comprehensive two-dimensional gas chromatog. with flame ionization detection (GCxGC/FID). Both methods were used to determine the concentrations of six different commonly used carbonates in Li-ion battery electrolytes i.e., ethylene carbonate (EC), propylene carbonate (PC), di-Me carbonate (DMC), di-Et carbonate (DEC), Et Me carbonate (EMC), and vinylene carbonate (VC) in model compound mixtures (MCMs), single-blind samples (SBS), and a com. obtained electrolyte solution (COES). Both methods were found to be precise (uncertainty < 5%), accurate (error < 5%), and sensitive (limit of detection <0.12 ppm for FID and <2.7 ppm for MS). Furthermore, unlike the previously reported methods, these methods do not require removing lithium hexafluorophosphate salt (LiPF6) from the sample prior to anal. Removal of the lithium salt was avoided by diluting the electrolyte solutions prior to anal. (1000-fold dilution) and using minimal sample volumes (0.1μL) for anal. In the experiment, the researchers used many compounds, for example, Vinylene carbonate(cas: 872-36-6SDS of cas: 872-36-6)

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

Schmidt, Florian’s team published research in Magnetic Resonance in Chemistry in 2020 | CAS: 872-36-6

Electric Literature of C3H2O3In 2020 ,《Spectral deconvolution in electrophoretic NMR to investigate the migration of neutral molecules in electrolytes》 was published in Magnetic Resonance in Chemistry. The article was written by Schmidt, Florian; Pugliese, Andrea; Santini, Catherine C.; Castiglione, Franca; Schoenhoff, Monika. The article contains the following contents:

Electrophoretic NMR (eNMR) is a powerful tool in studies of nonaqueous electrolytes, such as ionic liquids It delivers electrophoretic mobilities of the ionic constituents and thus sheds light on ion correlations. In applications of liquid electrolytes, uncharged additives are often employed, detectable via 1H NMR. Characterizing their mobility and coordination to charged entities is desirable; however, it is often hampered by small intensities and 1H signals overlapping with major constituents of the electrolyte. In this work, we evaluate methods of phase anal. of overlapping resonances to yield electrophoretic mobilities even for minor constituents. We use phase-sensitive spectral deconvolution via a set of Lorentz distributions for the investigation of the migration behavior of additives in two different ionic liquid-based lithium salt electrolytes. For vinylene carbonate as an additive, no field-induced drift is observed; thus, its coordination to the Li+ ion does not induce a correlated drift with Li+. On the other hand, in a solvate ionic liquid with tetraglyme (G4) as an additive, a correlated migration of tetraglyme with lithium as a complex solvate cation is directly proven by eNMR. The phase evaluation procedure of superimposed resonances thus broadens the applicability of eNMR to application-relevant complex electrolyte mixtures containing neutral additives with superimposed resonances. The experimental process involved the reaction of Vinylene carbonate(cas: 872-36-6Electric Literature of C3H2O3)

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

Zhang, Zhenyu’s team published research in ACS Applied Materials & Interfaces in 2020 | CAS: 872-36-6

Computed Properties of C3H2O3In 2020 ,《Operando Electrochemical Atomic Force Microscopy of Solid-Electrolyte Interphase Formation on Graphite Anodes: The Evolution of SEI Morphology and Mechanical Properties》 was published in ACS Applied Materials & Interfaces. The article was written by Zhang, Zhenyu; Smith, Keenan; Jervis, Rhodri; Shearing, Paul R.; Miller, Thomas S.; Brett, Daniel J. L.. The article contains the following contents:

Understanding and ultimately controlling the properties of the solid-electrolyte interphase (SEI) layer at the graphite anode/liquid electrolyte boundary are of great significance for maximizing the performance and lifetime of lithium-ion batteries (LIBs). However, comprehensive in situ monitoring of SEI formation and evolution, alongside measurement of the corresponding mech. properties, is challenging due to the limitations of the characterization techniques commonly used. This work provides a new insight into SEI formation during the first lithiation and delithiation of graphite battery anodes using operando electrochem. at. force microscopy (EC-AFM). Highly oriented pyrolytic graphite (HOPG) is investigated first as a model system, exhibiting unique morphol. and nanomech. behavior dependent on the various electrolytes and com. relevant additives used. Then, to validate these findings with respect to real-world battery electrodes, operando EC-AFM of individual graphite particles like those in com. systems are studied. Vinylene carbonate (VC) and fluoroethylene carbonate (FEC) are shown to be effective additives to enhance SEI layer stability in 1 M LiPF6/ethylene carbonate/ethyl Me carbonate (EC/EMC) electrolytes, attributed to their role in improving its structure, d., and mech. strength. This work therefore presents an unambiguous picture of SEI formation in a real battery environment, contributes a comprehensive insight into SEI formation of electrode materials, and provides a visible understanding of the influence of electrolyte additives on SEI formation. The results came from multiple reactions, including the reaction of Vinylene carbonate(cas: 872-36-6Computed Properties of C3H2O3)

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

Kuai, Dacheng’s team published research in ACS Applied Materials & Interfaces in 2022 | CAS: 872-36-6

Product Details of 872-36-6In 2022 ,《Solvent Degradation and Polymerization in the Li-Metal Battery: Organic-Phase Formation in Solid-Electrolyte Interphases》 appeared in ACS Applied Materials & Interfaces. The author of the article were Kuai, Dacheng; Balbuena, Perla B.. The article conveys some information:

The products of solvent polymerization and degradation are crucial components of the Li-metal battery solid-electrolyte interphase. However, in-depth mechanistic studies of these reactions are still scarce. Here, we model the polymerization of common lithium battery electrolyte solvents-ethylene carbonate (EC) and vinylene carbonate (VC)-near the anode surface. Being consistent with the mol. calculation, ab initio mol. dynamic (AIMD) simulations reveal fast solvent decompositions upon contact with the Li anode. Addnl., we assessed the thermochem. impacts of decarboxylation reactions as well as the lithium bonding with reaction intermediates. In both EC and VC polymerization pathways, lithium bonding demonstrated profound catalytic effects while different degrees of decarboxylation were observed The VC polymerization pathways with and without ring-opening events were evaluated systematically, and the latter one which leads to poly(VC) formation was proven to dominate the oligomerization process. Both the decomposition and polymerization reactivities of VC are found to be higher than EC, while the cross-coupling between EC and VC has an even lower-energy barrier. These findings are in good agreement with exptl. evidence and explanatory toward the enhanced performance of VC-added lithium-metal batteries. In addition to this study using Vinylene carbonate, there are many other studies that have used Vinylene carbonate(cas: 872-36-6Product Details of 872-36-6) was used in this study.

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

Kum, Lenin W.’s team published research in ACS Applied Materials & Interfaces in 2022 | CAS: 872-36-6

In 2022,Kum, Lenin W.; Gogia, Ashish; Vallo, Nick; Singh, Deependra Kumar; Kumar, Jitendra published an article in ACS Applied Materials & Interfaces. The title of the article was 《Enhancing Electrochemical Performances of Rechargeable Lithium-Ion Batteries via Cathode Interfacial Engineering》.Formula: C3H2O3 The author mentioned the following in the article:

Li-ion batteries (LIBs) have transformed modern electronics and rapidly advancing elec. vehicles (EVs) due to their high energy and power densities, cycle-life, and acceptable safety. However, the comprehensive commercialization of EVs necessitates the invention of LIBs with much enhanced and stable electrochem. performances, including higher energy/power d., cycle-life, and operational safety, but at a lower cost. Herein, the authors report a simple method for improving the high-voltage (up to 4.5 V) charge capability of LIBs by applying a Li+-ion-conducting artificial cathode-electrolyte interface (Li+-ACEI) on the state-of-the-art cathode, LiCoO2 (LCO). A superionic ceramic single Li+ ion conductor, Li Al Ge phosphate (Li1.5Al0.5Ge1.5(PO4)3, LAGP), was used as a novel Li+-ACEI. The application of Li+-ACEI on LCO involves a scalable and straightforward wet chem. process (sol-gel method). Cycling performance, including high voltage charge, of bare and LAGP-coated cathodes was determined against the most energy-dense anode (Li, Li metal) and state-of-the-art carbonate-based organic liquid electrolyte (OLE). The application of an LAGP-based Li+-ACEI on LCO displays many improvements: (i) reduced charge-transfer and interfacial resistance; (ii) higher discharge capacity (167.5 vs. 155 mA-h g-1) at 0.2 C; (iii) higher Coulombic efficiency (98.9 vs. 97.8%) over 100 cycles; and (iv) higher rate capability (143 vs. 80.1 mA-h g-1) at 4C. Structural and morphol. characterizations have substantiated the improved electrochem. behavior of bare and Li+-ACEI LCO cathodes against the Li anode. The results came from multiple reactions, including the reaction of Vinylene carbonate(cas: 872-36-6Formula: C3H2O3)

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics