Category: 872-36-6

In 2022,Kasakado, Takayoshi; Fukuyama, Takahide; Nakagawa, Tomohiro; Taguchi, Shinji; Ryu, Ilhyong published an article in Beilstein Journal of Organic Chemistry. The title of the article was 《High-speed C-H chlorination of ethylene carbonate using a new photoflow setup》.Product Details of 872-36-6 The author mentioned the following in the article:

Reported the high-speed C-H chlorination of ethylene carbonate, which gives chloroethylene carbonate, a precursor to vinylene carbonate. A novel photoflow setup designed for a gas-liquid biphasic reaction turned out to be useful for the direct use of chlorine gas. The setup employed sloped channels so as to make the liquid phase thinner, ensured a high surface-to-volume ratio. When ethylene carbonate were introduced to the reactor, the residence time were measured to be 15 or 30 s, depending on the slope of the reactor set at 15 or 5°, resp. Such short time of exposition sufficed the photo C-H chlorination. The partial irradiation of the flow channels also sufficed for the C-H chlorination, which was consistent with the requirement of photoirradiation for the purpose of radical initiation. Near-complete selectivity for single chlorination required the low conversion of ethylene carbonate such as 9%, which were controlled by limited introduction of chlorine gas. At a higher conversion of ethylene carbonate such as 61%, the selectivity for monochlorinated ethylene carbonate over dichlorinated ethylene carbonate was 86%. Also found that the substrate contamination with water neg. influenced the performance of the C-H chlorination. The results came from multiple reactions, including the reaction of Vinylene carbonate(cas: 872-36-6Product Details of 872-36-6)

Vinylene carbonate(cas: 872-36-6) belongs to esters. Alkyl carbonates find applications as solvents for lithium ion battery electrolytes and the use of high quality battery grade electrolytes having extremely low water (<10 ppm) and acid (<10 ppm) contents are critical for achieving high electrochemical performance.Product Details of 872-36-6

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

The author of 《SEI grown on MCMB-electrode with fluoroethylene carbonate and vinylene carbonate additives as probed by in situ DRIFTS》 were Yohannes, Yonas Beyene; Lin, Shawn D.; Wu, Nae-Lih; Hwang, Bing-Joe. And the article was published in Journal of the Electrochemical Society in 2019. Formula: C3H2O3 The author mentioned the following in the article:

The formation of solid electrolyte interphase (SEI) on electrodes of Lithium ion batteries (LiBs) is known to influence the electrochem. performance of LiBs. In this work, the effect of fluoroethylene carbonate (FEC) and vinylene carbonate (VC) on the SEI formation on mesocarbon microbeads (MCMB) anode is examined by in situ DRIFTS (diffuse reflectance IR Fourier-transformed spectroscopy). Formation of SEI species on MCMB starts in the first lithiation cycle with an onset potential corresponding to the electrochem. reduction potential of the additive. However, both VC and FEC result in continuous SEI formation in subsequent cycles with no onset potential. Similar SEI species are found in the first lithiation cycle and in the subsequent cycles. This suggests the presence of an electrochem. initiation of SEI species formation with a subsequent propagation, similar with what we found previously over Si-based anode. The contribution of the observed SEI species for the improved electrochem. impedances through cycling and its implications are discussed. The experimental part of the paper was very detailed, including the reaction process of Vinylene carbonate(cas: 872-36-6Formula: C3H2O3)

Vinylene carbonate(cas: 872-36-6) belongs to esters. Alkyl carbonates find applications as solvents for lithium ion battery electrolytes and the use of high quality battery grade electrolytes having extremely low water (<10 ppm) and acid (<10 ppm) contents are critical for achieving high electrochemical performance.Formula: C3H2O3

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

Wang, Chang; Fan, Xiaodong; Chen, Fan; Qian, Peng-Cheng; Cheng, Jiang published an article in 2021. The article was titled 《Vinylene carbonate: beyond the ethyne surrogate in rhodium-catalyzed annulation with amidines toward 4-methylquinazolines》, and you may find the article in Chemical Communications (Cambridge, United Kingdom).Recommanded Product: Vinylene carbonate The information in the text is summarized as follows:

In this paper, a rhodium-catalyzed annulation of vinylene carbonate with amidines RNHC(=NH)R1 (R = 2-chlorophenyl, 4-tert-butylphenyl, naphthalen-1-yl, etc.; R1 = t-Bu, cyclopropyl, thiophen-2-yl, naphthalen-1-yl, etc.), leading to 4-methylquinazolines I (R2 = H, Me, F, t-Bu, etc.; R3 = H, Cl; R4 = H, Cl; R3R4 = -CH=CHCH=CH-) with moderate to excellent yields have been developed. This procedure proceeded by sequential ortho-acylation and annulation, where vinylene carbonate served as the acetylation reagent rather than the ethyne surrogate. In addition to this study using Vinylene carbonate, there are many other studies that have used Vinylene carbonate(cas: 872-36-6Recommanded Product: Vinylene carbonate) was used in this study.

Vinylene carbonate(cas: 872-36-6) belongs to esters. Alkyl carbonates find applications as solvents for lithium ion battery electrolytes and the use of high quality battery grade electrolytes having extremely low water (<10 ppm) and acid (<10 ppm) contents are critical for achieving high electrochemical performance.Recommanded Product: Vinylene carbonate

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

Kato, Moena; Ghosh, Koushik; Nishii, Yuji; Miura, Masahiro published an article in 2021. The article was titled 《Rhodium-catalysed direct formylmethylation using vinylene carbonate and sequential dehydrogenative esterification》, and you may find the article in Chemical Communications (Cambridge, United Kingdom).Application In Synthesis of Vinylene carbonate The information in the text is summarized as follows:

A rhodium-catalyzed direct formylmethylation adopting vinylene carbonate as an ethynol equivalent was reported. The developed catalytic system was further utilized for the oxidant-free production of esters with the liberation of hydrogen gas. Some control experiments were conducted to elucidate the reaction mechanism. In the experimental materials used by the author, we found Vinylene carbonate(cas: 872-36-6Application In Synthesis of Vinylene carbonate)

Vinylene carbonate(cas: 872-36-6) belongs to esters. Alkyl carbonates find applications as solvents for lithium ion battery electrolytes and the use of high quality battery grade electrolytes having extremely low water (<10 ppm) and acid (<10 ppm) contents are critical for achieving high electrochemical performance.Application In Synthesis of Vinylene carbonate

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

Quality Control of Vinylene carbonateIn 2019 ,《One-step preparation of poly(ionic liquid)-based flexible electrolytes by in-situ polymerization for dendrite-free lithium ion batteries》 appeared in Chemical Engineering Journal (Amsterdam, Netherlands). The author of the article were Huang, Teng; Long, Man-Cheng; Wang, Xiu-Li; Wu, Gang; Wang, Yu-Zhong. The article conveys some information:

Solid-state battery (SSB) has a new application prospect in the fields of safe energy storage, but the solid electrolyte usually fails to maintain excellent ionic conductivity, good mech. properties and close interfacial contact with the electrode materials simultaneously. A newly-designed poly(ionic liquid)-based quasi solid electrolyte (PIL-QSE) is prepared via 1-step in-situ cross-linked polymerizing 1-vinyl-3-dodecylimidazolium bis(trifluoromethanesulfonyl) imide (VDIM-TFSI), which is filled in poly(vinylidene fluoride-hexafluoropropylene) (PVdF-HFP) porous membrane prepared via phase inversion. The leakage-free PIL-QSE containing a compact cross-linked network structure exhibits optimal performances with outstanding flexibility, favorable thermal stability and improved electrochem. performances including a high room-temperature ionic conductivity of 0.70 mS cm-1, a superior electrochem. window up to 5.0 V as well as a high Li ion transference of 0.52. Also, the PIL-QSE can suppress dendrite formation leading to a good battery performance. The LiFePO4|PIL-QSE|Li cells can maintain a discharge capacity 140.7 mA-h g-1 at 0.05 C with 99.8% coulomb efficiency after 200 cycles and 125.9 mA-h g-1 at 0.1 C with 98.9% capacity contention after 100 cycles at 25°. Because of the flexibility of PIL-QSE, the pouch-type battery based on PIL-QSE cannot only light the red LED lamp in a normal state, but also in a bended/cut state. Both of the excellent performance and easy fabrication of PIL-QSE make it potentially as one of the most promising electrolyte materials for SSPB. In addition to this study using Vinylene carbonate, there are many other studies that have used Vinylene carbonate(cas: 872-36-6Quality Control of Vinylene carbonate) was used in this study.

Vinylene carbonate(cas: 872-36-6) belongs to esters. Alkyl carbonates find applications as solvents for lithium ion battery electrolytes and the use of high quality battery grade electrolytes having extremely low water (<10 ppm) and acid (<10 ppm) contents are critical for achieving high electrochemical performance.Quality Control of Vinylene carbonate

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

The author of 《Approaching the maximum capacity of nickel-rich LiNi0.8Co0.1Mn0.1O2 cathodes by charging to high-voltage in a non-flammable electrolyte of propylene carbonate and fluorinated linear carbonates》 were Pham, Hieu Quang; Hwang, Eui-Hyung; Kwon, Young-Gil; Song, Seung-Wan. And the article was published in Chemical Communications (Cambridge, United Kingdom) in 2019. Quality Control of Vinylene carbonate The author mentioned the following in the article:

We report a promising approach to achieve the maximum capacity (>230 mA h g-1) and high capacity retention (95% during 100 cycles) of a nickel-rich cathode of LiNi0.8Co0.1Mn0.1O2 (NCM811) by charging to 4.5 V in a non-flammable electrolyte of propylene carbonate and fluorinated linear carbonates. Our electrolyte permits the stabilization of the cathode-electrolyte interface and cathode structure at high-voltage, enabling stable and safe operation of the Ni-rich cathode for high-energy d. and high-safety lithium-ion and lithium metal batteries. The experimental part of the paper was very detailed, including the reaction process of Vinylene carbonate(cas: 872-36-6Quality Control of Vinylene carbonate)

Vinylene carbonate(cas: 872-36-6) belongs to esters. Alkyl carbonates find applications as solvents for lithium ion battery electrolytes and the use of high quality battery grade electrolytes having extremely low water (<10 ppm) and acid (<10 ppm) contents are critical for achieving high electrochemical performance.Quality Control of Vinylene carbonate

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

《Suppressing lithium dendrite growth by a synergetic effect of uniform nucleation and inhibition》 was written by Wu, Li-Na; Peng, Jun; Han, Fa-Ming; Sun, Ya-Ke; Sheng, Tian; Li, Yang-Yang; Zhou, Yao; Huang, Ling; Li, Jun-Tao; Sun, Shi-Gang. Related Products of 872-36-6 And the article was included in Journal of Materials Chemistry A: Materials for Energy and Sustainability in 2020. The article conveys some information:

The lithium dendrites issue presents a major challenge limiting the commercialization of Li metal anodes for high-energy-d. batteries. Herein, an AgPF6-LiNO3 hybrid electrolyte additive was introduced into a carbonate electrolyte, which was found to induce the formation of a homogeneous dense layer of Ag-Li alloy seeds with small sizes on the Li metal surface. The formation mechanism of such fine Ag-Li alloy seeds on the Li metal substrate was evaluated, which revealed an interesting synergistic effect between AgPF6 and LiNO3. The occurrence of such a dense layer of Ag-Li alloy seeds was found to play a significant pos. role in homogeneous nucleation and growth of Li dendrites, and LiNO3 could inhibit the growth of Li and act as a grain refiner during a repetitive plating/stripping process, thus enabling profoundly improved structural stability and excellent long-term cycle performance for the Li anode during the cycling process. With the co-presence of AgPF6-LiNO3 in the electrolyte, the relevant sym. cells could work steadily for 3000 h with slight polarization at a d. of 0.5 mA cm-2; and the Li-graphite battery can exhibit good cycle performances and deliver a specific energy d. of 374 W h kg-1 at a power d. of 747 W kg-1. The experimental process involved the reaction of Vinylene carbonate(cas: 872-36-6Related Products of 872-36-6)

Vinylene carbonate(cas: 872-36-6) belongs to esters. Alkyl carbonates find applications as solvents for lithium ion battery electrolytes and the use of high quality battery grade electrolytes having extremely low water (<10 ppm) and acid (<10 ppm) contents are critical for achieving high electrochemical performance.Related Products of 872-36-6

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

In 2022,Chen, Zifeng; Su, Hai; Sun, Pengfei; Bai, Panxing; Yang, Jixing; Li, Mengjie; Deng, Yunfeng; Liu, Yang; Geng, Yanhou; Xu, Yunhua published an article in Proceedings of the National Academy of Sciences of the United States of America. The title of the article was 《A nitroaromatic cathode with an ultrahigh energy density based on six-electron reaction per nitro group for lithium batteries》.Synthetic Route of C3H2O3 The author mentioned the following in the article:

Organic electrode materials have emerged as promising alternatives to conventional inorganic materials because of their structural diversity and environmental friendliness feature. However, their low energy densities, limited by the single-electron reaction per active group, have plagued the practical applications. Here, we report a nitroarom. cathode that performs a six-electron reaction per nitro group, drastically improving the specific capacity and energy d. compared with the organic electrodes based on single-electron reactions. Based on such a reaction mechanism, the organic cathode of 1,5-dinitronaphthalene demonstrates an ultrahigh specific capacity of 1,338 mAh·g-1 and energy d. of 3,273 Wh·kg-1, which surpass all existing organic cathodes. The reaction path was verified as a conversion from nitro to amino groups. Our findings open up a pathway, in terms of battery chem., for ultrahigh-energy-d. Li-organic batteries. In the experimental materials used by the author, we found Vinylene carbonate(cas: 872-36-6Synthetic Route of C3H2O3)

Vinylene carbonate(cas: 872-36-6) belongs to esters. Alkyl carbonates find applications as solvents for lithium ion battery electrolytes and the use of high quality battery grade electrolytes having extremely low water (<10 ppm) and acid (<10 ppm) contents are critical for achieving high electrochemical performance.Synthetic Route of C3H2O3

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

《Realizing a high-performance LiNi0.6Mn0.2Co0.2O2/silicon-graphite full lithium ion battery cell via a designer electrolyte additive》 was published in Journal of Materials Chemistry A: Materials for Energy and Sustainability in 2020. These research results belong to Aupperle, Felix; Eshetu, Gebrekidan Gebresilassie; Eberman, Kevin W.; Xioa, Ang; Bridel, Jean-Sebastien; Figgemeier, Egbert. Application In Synthesis of Vinylene carbonate The article mentions the following:

An optimized dosage of (2-cyanoethyl)triethoxysilane (TEOSCN), is investigated as the electrode/electrolyte interface (EEI) modulating electrolyte additive to improve electrochem. performance of LiN0.6Mn0.2Co0.2O2(NMC622)/silicon(Si)-graphite(Gr) battery cells at a high temperature (45°). The addition of 1 wt% of TEOSCN to 1 M LiPF6 in EC:DEC + 5 wt% FEC/2 wt% VC electrolyte is found to significantly improve the long-term cyclability, capacity retention and coulombic efficiency of NMC622/Si-Gr cells at 45°. Pouch cells cycled in a nitrile-functionalized silane bearing electrolyte show superior capacity retention (∼ 75.95%) compared to those with FEC/VC (∼ 8.05%) and without additives (EC:DEC, ∼19.23%) electrolytes at the 364th cycle. Chem. mimicking and XPS anal. proved that the enhanced electrochem. performance is attributed to the formation of -C≡N reduction/oxidation induced robust EEI layers, both on the anode and cathode compartments, thus mitigating the escorted prevailing challenges. This work provides a highly promising electrolyte additive enabling the large-scale com. deployment of Si-containing high-energy lithium-ion full cell batteries. In the experiment, the researchers used many compounds, for example, Vinylene carbonate(cas: 872-36-6Application In Synthesis of Vinylene carbonate)

Vinylene carbonate(cas: 872-36-6) belongs to esters. Alkyl carbonates find applications as solvents for lithium ion battery electrolytes and the use of high quality battery grade electrolytes having extremely low water (<10 ppm) and acid (<10 ppm) contents are critical for achieving high electrochemical performance.Application In Synthesis of Vinylene carbonate

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics