Category: 872-36-6

Electric Literature of C3H2O3In 2021 ,《Constructing a Reinforced and Gradient Solid Electrolyte Interphase on Si Nanoparticles by In-Situ Thiol-Ene Click Reaction for Long Cycling Lithium-Ion Batteriesã€?was published in Small. The article was written by Zhao, Liang; Zhang, Danfeng; Huang, Yongfeng; Lin, Kui; Chen, Likun; Lv, Wei; He, Yan-Bing; Kang, Feiyu. The article contains the following contents:

Constructing a stable solid electrolyte interphase (SEI) on high-specific-capacity silicon (Si) anode is one of the most effective methods to reduce the crack of SEI and improve the cycling performance of Si anode. Herein, the authors construct a reinforced and gradient SEI on Si nanoparticles by an in-situ thiol-ene click reaction. Mercaptopropyl trimethoxysilane (MPTMS) with thiol functional groups (SH) is first grafted on the Si nanoparticles through condensation reaction, which then in-situ covalently bonds with vinylene carbonate (VC) to form a reinforced and uniform SEI on Si nanoparticles. The modified SEI with sufficient elastic LixSiOy can homogenize the stress and strain during the lithiation of Si nanoparticles to reduce their expansion and prevent the SEI from cracking. The Si nanoparticles-graphite blending anode with the reinforced SEI exhibits excellent performance with an initial coulombic efficiency of �0%, a capacity of 1053.3 mA h g-1 after 500 cycles and a high capacity of 852.8 mA h g-1 even at a high c.d. of 3 A g-1. Moreover, the obtained anode shows superior cycling stability under both high loadings and lean electrolyte. The in-situ thiol-ene click reaction is a practical method to construct reinforced SEI on Si nanoparticles for next-generation high-energy-d. lithium-ion batteries. In addition to this study using Vinylene carbonate, there are many other studies that have used Vinylene carbonate(cas: 872-36-6Electric Literature of C3H2O3) was used in this study.

Vinylene carbonate(cas: 872-36-6) belongs to esters. Alkyl carbonates find applications as solvents for lithium ion battery electrolytes and the use of high quality battery grade electrolytes having extremely low water (<10 ppm) and acid (<10 ppm) contents are critical for achieving high electrochemical performance.Electric Literature of C3H2O3

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

The author of 《Effects of LiBF4 concentration in carbonate-based electrolyte on the stability of high-voltage LiNi0.5Mn1.5O4 cathodeã€?were Feng, Yaohua; Xu, Hui; Zhang, Yu; Li, Chunlei; Zhao, Dongni; Zhao, Qiuping; Mao, Liping; Zhang, Haiming; Li, Shiyou. And the article was published in Ionics in 2019. Recommanded Product: 872-36-6 The author mentioned the following in the article:

LiBF4 has attracted much attention due to its better thermal stability, lower sensitivity to environmental humidity, and lower charge transfer resistance provided by its solution, especially at high voltage. Herein, the effects of the concentration of LiBF4 salt on the stability and electrochem. properties of LiNi0.5Mn1.5O4 (LNMO) cathode material have been investigated by using the mixed solvents of LiBF4 salt, vinyl carbonate (EC), and di-Et carbonate (DEC) as electrolytes. The surface morphol. and structure of cycled LNMO electrode are studied by SEM (SEM), Raman spectroscopy, and Fourier transform IR spectroscopy (FTIR). The results show that the optimum concentration of LiBF4 salt is 1.4 M LiBF4-EC/DEC (1:5, by volume). Under optimum conditions, the LNMO cathode material has high electrochem. capacity and favorable rate performance. Meanwhile, the prepared electrolyte can easily form a thin and stable SEI film on the surface of LNMO electrode, which can effectively inhibit the continuous decomposition of the electrolyte. The experimental part of the paper was very detailed, including the reaction process of Vinylene carbonate(cas: 872-36-6Recommanded Product: 872-36-6)

Vinylene carbonate(cas: 872-36-6) belongs to esters. Alkyl carbonates find applications as solvents for lithium ion battery electrolytes and the use of high quality battery grade electrolytes having extremely low water (<10 ppm) and acid (<10 ppm) contents are critical for achieving high electrochemical performance.Recommanded Product: 872-36-6

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

《Current Density Regulated Atomic to Nanoscale Process on Li Deposition and Solid Electrolyte Interphase Revealed by Cryogenic Transmission Electron Microscopyã€?was written by Xu, Yaobin; Wu, Haiping; Jia, Hao; Zhang, Ji-Guang; Xu, Wu; Wang, Chongmin. Application In Synthesis of Vinylene carbonate And the article was included in ACS Nano in 2020. The article conveys some information:

C.d. has been perceived to play a critical rule in controlling Li deposition morphol. and solid electrolyte interphase (SEI). However, the at. level mechanism of the effect of c.d. on Li deposition and the SEI remains unclear. Here based on cryogenic transmission electron microscopy (TEM) imaging combined with energy dispersive X-ray spectroscopy (EDS) and electron energy loss spectroscopy (EELS) electronic structure analyses, we reveal the at. level correlation of Li deposition morphol. and SEI with c.d. We discover that increasing c.d. leads to increased overpotential for Li nucleation and growth, leading to the transition from growth-limited to nucleation-limited mode for Li dendrites. Independent of c.d., the electrochem. deposited Li metal (EDLi) exhibits crystalline whisker-like morphol. The SEI formed at low c.d. (0.1 mA cm-2) is monolithic amorphous; while, a c.d. of above 2 mA cm-2 leads to a mosaic structured SEI, featuring an amorphous matrix with Li2O and LiF dispersoids, and the thickness of the SEI increases with the increase of c.d. Specifically, the Li2O particles are spatially located at the top surface of the SEI, while LiF is spatially adjacent to the Li-SEI interface. These results offer possible ways of regulating crucial microstructural and chem. features of EDLi and SEI through altering deposit conditions and consequently direct correlation with battery performance. The experimental process involved the reaction of Vinylene carbonate(cas: 872-36-6Application In Synthesis of Vinylene carbonate)

Vinylene carbonate(cas: 872-36-6) belongs to esters. Alkyl carbonates find applications as solvents for lithium ion battery electrolytes and the use of high quality battery grade electrolytes having extremely low water (<10 ppm) and acid (<10 ppm) contents are critical for achieving high electrochemical performance.Application In Synthesis of Vinylene carbonate

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

The author of 《Monolithic solid-electrolyte interphases formed in fluorinated orthoformate-based electrolytes minimize Li depletion and pulverizationã€?were Cao, Xia; Ren, Xiaodi; Zou, Lianfeng; Engelhard, Mark H.; Huang, William; Wang, Hansen; Matthews, Bethany E.; Lee, Hongkyung; Niu, Chaojiang; Arey, Bruce W.; Cui, Yi; Wang, Chongmin; Xiao, Jie; Liu, Jun; Xu, Wu; Zhang, Ji-Guang. And the article was published in Nature Energy in 2019. Electric Literature of C3H2O3 The author mentioned the following in the article:

Lithium (Li) pulverization and associated large volume expansion during cycling is one of the most critical barriers for the safe operation of Li-metal batteries. Here, we report an approach to minimize the Li pulverization using an electrolyte based on a fluorinated orthoformate solvent. The solid-electrolyte interphase (SEI) formed in this electrolyte clearly exhibits a monolithic feature, which is in sharp contrast with the widely reported mosaic- or multilayer-type SEIs that are not homogeneous and could lead to uneven Li stripping/plating and fast Li and electrolyte depletion over cycling. The highly homogeneous and amorphous SEI not only prevents dendritic Li formation, but also minimizes Li loss and volumetric expansion. Furthermore, this new electrolyte strongly suppresses the phase transformation of the LiNi0.8Co0.1Mn0.1O2 cathode (from layered structure to rock salt) and stabilizes its structure. Tests of high-voltage Li||NMC811 cells show long-term cycling stability and high rate capability, as well as reduced safety concerns. In the experimental materials used by the author, we found Vinylene carbonate(cas: 872-36-6Electric Literature of C3H2O3)

Vinylene carbonate(cas: 872-36-6) belongs to esters. Alkyl carbonates find applications as solvents for lithium ion battery electrolytes and the use of high quality battery grade electrolytes having extremely low water (<10 ppm) and acid (<10 ppm) contents are critical for achieving high electrochemical performance.Electric Literature of C3H2O3

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

《Sweeping potential regulated structural and chemical evolution of solid-electrolyte interphase on Cu and Li as revealed by cryo-TEMã€?was published in Nano Energy in 2020. These research results belong to Xu, Yaobin; Wu, Haiping; Jia, Hao; Engelhard, Mark H.; Zhang, Ji-Guang; Xu, Wu; Wang, Chongmin. Product Details of 872-36-6 The article mentions the following:

A fundamental understanding of solid-electrolyte interphase (SEI) is paramount importance for controlling the cycling performance of rechargeable lithium metal batteries. The structural and chem. evolution of SEI with respect to electrochem. operating condition remains barely established. Here we develop a unique method for imaging the evolution of SEI formed on the Cu foil under sweeping electrochem. potential. By using cryogenic TEM imaging combined with energy dispersive X-ray spectroscopy and XPS electronic structure analyses, we reveal that, for the vinylene carbonate (VC)-free electrolyte, the SEI formed at 1.0 V is a monolithic amorphous structure, which evolves to amorphous matrix embedded with Li2O particles as the voltage decreases to 0 V. In the case of VC-containing electrolyte, the SEI is featured by an amorphous matrix with Li2O particles from 1.0 V to 0 V. The thickness of SEI formed on Cu foil increases with decreasing voltage. Associated with the localized charge modulation by the surface topog. feature and defects in the Cu foil, the SEI layer shows direct spatial correlation with these structural defects in the Cu. In addition, upon Li deposition, the SEI formed on the Li metal has similar thickness with, but different composition from the SEI formed on the Cu foil at 0 V. Those results provide insight toward SEI engineering for enhanced cycling stability of Li metal. The experimental part of the paper was very detailed, including the reaction process of Vinylene carbonate(cas: 872-36-6Product Details of 872-36-6)

Vinylene carbonate(cas: 872-36-6) belongs to esters. Alkyl carbonates find applications as solvents for lithium ion battery electrolytes and the use of high quality battery grade electrolytes having extremely low water (<10 ppm) and acid (<10 ppm) contents are critical for achieving high electrochemical performance.Product Details of 872-36-6

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

He, Jian; Wang, Huaping; Zhou, Qing; Qi, Shihan; Wu, Mingguang; Li, Fang; Hu, Wei; Ma, Jianmin published their research in Small Methods in 2021. The article was titled 《Unveiling the Role of Li+ Solvation Structures with Commercial Carbonates in the Formation of Solid Electrolyte Interphase for Lithium Metal Batteriesã€?Related Products of 872-36-6 The article contains the following contents:

Solid electrolyte interphase (SEI), determined by the components of electrolytes, can endow batteries with the ability to repress the growth of Li dendrites. Nevertheless, the mechanism of com. carbonates on in situ-generated SEI and the consequential effect on cycling performance is not well understood yet, although some carbonates are well used in electrolytes. In this work, quantum chem. calculations and mol. dynamics are used to reveal the formation mechanisms of SEI with carbonate-based electrolyte additives on the at. level. It is confirmed that the Li-coordinated carbonate species are the leading participant of SEI formation and their impact on battery performance is clarified. Fluoroethylene carbonate (FEC) exhibits a completely different behavior from vinyl ethylene carbonate (VEC), ethylene carbonate (EC), and vinylene carbonate (VC). High reduction potential Li+-coordinated additives, e.g. FEC and VEC can dominate the formation of SEI by excluding propylene carbonate (PC) and LiPF6 from the decomposition, and the corresponding Li||Li sym. cells show enhanced long-term performance compared with those with pure PC electrolyte, while the low reduction priority additives (e.g., EC and VC) cannot form a uniform SEI by winning the competitive reaction. In addition to this study using Vinylene carbonate, there are many other studies that have used Vinylene carbonate(cas: 872-36-6Related Products of 872-36-6) was used in this study.

Vinylene carbonate(cas: 872-36-6) belongs to esters. Alkyl carbonates find applications as solvents for lithium ion battery electrolytes and the use of high quality battery grade electrolytes having extremely low water (<10 ppm) and acid (<10 ppm) contents are critical for achieving high electrochemical performance.Related Products of 872-36-6

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

《Molecular design for electrolyte solvents enabling energy-dense and long-cycling lithium metal batteries》 was written by Yu, Zhiao; Wang, Hansen; Kong, Xian; Huang, William; Tsao, Yuchi; Mackanic, David G.; Wang, Kecheng; Wang, Xinchang; Huang, Wenxiao; Choudhury, Snehashis; Zheng, Yu; Amanchukwu, Chibueze V.; Hung, Samantha T.; Ma, Yuting; Lomeli, Eder G.; Qin, Jian; Cui, Yi; Bao, Zhenan. Safety of Vinylene carbonate And the article was included in Nature Energy in 2020. The article conveys some information:

Electrolyte engineering is critical for developing Li metal batteries. While recent works improved Li metal cyclability, a methodol. for rational electrolyte design remains lacking. Herein, we propose a design strategy for electrolytes that enable anode-free Li metal batteries with single-solvent single-salt formations at standard concentrations Rational incorporation of -CF2- units yields fluorinated 1,4-dimethoxylbutane as the electrolyte solvent. Paired with 1 M lithium bis(fluorosulfonyl)imide, this electrolyte possesses unique Li-F binding and high anion/solvent ratio in the solvation sheath, leading to excellent compatibility with both Li metal anodes (Coulombic efficiency ∼ 99.52% and fast activation within five cycles) and high-voltage cathodes (∼6 V stability). Fifty-μm-thick Li|NMC batteries retain 90% capacity after 420 cycles with an average Coulombic efficiency of 99.98%. Industrial anode-free pouch cells achieve ∼325 Wh kg-1 single-cell energy d. and 80% capacity retention after 100 cycles. Our design concept for electrolytes provides a promising path to high-energy, long-cycling Li metal batteries.Vinylene carbonate(cas: 872-36-6Safety of Vinylene carbonate) was used in this study.

Vinylene carbonate(cas: 872-36-6) belongs to esters. Alkyl carbonates find applications as solvents for lithium ion battery electrolytes and the use of high quality battery grade electrolytes having extremely low water (<10 ppm) and acid (<10 ppm) contents are critical for achieving high electrochemical performance.Safety of Vinylene carbonate

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

《Inorganic/polymer hybrid layer stabilizing anode/electrolyte interfaces in solid-state Li metal batteries》 was written by Hu, Yiran; Zhong, Yiren; Qi, Limin; Wang, Hailiang. Category: esters-buliding-blocks And the article was included in Nano Research in 2020. The article conveys some information:

Li1.5Al0.5Ge1.5(PO4)3 (LAGP) is a solid-state electrolyte with high ionic conductivity and air stability but poor chem. stability and high interfacial impedance when directly contacted with Li metal. In this work, we develop an inorganic/polymer hybrid interlayer composed of Li bis(trifluoromethylsulfonyl)imide/poly(vinylene carbonate) polymer electrolyte and SiO2 submicrospheres to stabilize the Li/LAGP interface. The polymeric component renders high ionic conductance and low interfacial resistance, whereas the inorganic component imparts flame retardancy and a phys. barrier to the known Li-LAGP side reaction, together enabling stable Li stripping/plating for more than 1,500 h at room temperature With this interlayer at both electrodes, all-solid-state Li‖LiFePO4 full cells with stable cycling performance are also demonstrated. [graphic not available: see fulltext] In addition to this study using Vinylene carbonate, there are many other studies that have used Vinylene carbonate(cas: 872-36-6Category: esters-buliding-blocks) was used in this study.

Vinylene carbonate(cas: 872-36-6) belongs to esters. Alkyl carbonates find applications as solvents for lithium ion battery electrolytes and the use of high quality battery grade electrolytes having extremely low water (<10 ppm) and acid (<10 ppm) contents are critical for achieving high electrochemical performance.Category: esters-buliding-blocks

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

In 2022,Asheim, K.; Vullum, P. E.; Wagner, N. P.; Andersen, H. F.; Maehlen, J. P.; Svensson, A. M. published an article in RSC Advances. The title of the article was 《Improved electrochemical performance and solid electrolyte interphase properties of electrolytes based on lithium bis(fluorosulfonyl)imide for high content silicon anodes》.HPLC of Formula: 872-36-6 The author mentioned the following in the article:

Electrodes containing 60 wt% micron-sized silicon were investigated with electrolytes containing carbonate solvents and either LiPF6or lithium bis(fluorosulfonyl)imide (LiFSI) salt. The electrodes showed improved performance, with respect to capacity, cycling stability, rate performance, electrode resistance and cycle life with the LiFSI salt, attributed to differences in the solid electrolyte interphase (SEI). Through impedance spectroscopy, cross sectional anal. using transmission electron microscopy (TEM) and focused ion beam (FIB) in combination with SEM (SEM), and electrode surface characterization by XPS, differences in electrode morphol. changes, SEI composition and local distribution of SEI components were investigated. The SEI formed with LiFSI has a thin, inner, primarily inorganic layer, and an outer layer dominated by organic components. This SEI appeared more homogeneous and stable, more flexible and with a lower resistivity than the SEI formed in LiPF6 electrolyte. The SEI formed in the LiPF6 electrolyte appears to be less passivating and less flexible, with a higher resistance, and with higher capacitance values, indicative of a higher interfacial surface area. Cycling in LiPF6 electrolyte also resulted in incomplete lithiation of silicon particles, attributed to the inhomogeneous SEI formed. In contrast to LiFSI, where LiF was present in small grains in-between the silicon particles, clusters of LiF were observed around the carbon black for the LiPF6electrolyte. In the experimental materials used by the author, we found Vinylene carbonate(cas: 872-36-6HPLC of Formula: 872-36-6)

Vinylene carbonate(cas: 872-36-6) belongs to esters. Alkyl carbonates find applications as solvents for lithium ion battery electrolytes and the use of high quality battery grade electrolytes having extremely low water (<10 ppm) and acid (<10 ppm) contents are critical for achieving high electrochemical performance.HPLC of Formula: 872-36-6

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

《Atomic to Nanoscale Origin of Vinylene Carbonate Enhanced Cycling Stability of Lithium Metal Anode Revealed by Cryo-Transmission Electron Microscopy》 was written by Xu, Yaobin; Wu, Haiping; He, Yang; Chen, Qingsong; Zhang, Ji-Guang; Xu, Wu; Wang, Chongmin. Quality Control of Vinylene carbonateThis research focused onvinylene carbonate enhanced cycling lithium anode cryotransmission electron microscopy; lithium ion battery vinylene carbonate electrolyte additive safety; Lithium (Li) metal; cryogenic transmission electron microscopy (cryo-TEM); electrochemical deposition; electrolyte; solid electrolyte interphase (SEI); vinylene carbonate (VC). The article conveys some information:

Batteries using lithium (Li) metal as the anode are considered promising energy storage systems because of their high specific energy densities. The crucial bottlenecks for Li metal anode are Li dendrites growth and side reactions with electrolyte inducing safety concern, low Coulombic efficiency (CE), and short cycle life. Vinylene carbonate (VC), as an effective electrolyte additive in Li-ion batteries, has been noticed to significantly enhance the CE, whereas the origin of such an additive remains unclear. Here cryogenic transmission electron microscopy imaging combing with energy dispersive X-ray spectroscopy elemental and electron energy loss spectroscopy electronic structure analyses are used to reveal the role of the VC additive. It is discovered that the electrochem. deposited Li metal (EDLi) in the VC-containing electrolyte is slightly oxidized with the solid electrolyte interphase (SEI) being a nanoscale mosaic-like structure comprised of organic species, Li2O and Li2CO3, whereas the EDLi formed in the VC-free electrolyte is featured by a combination of fully oxidized Li with Li2O SEI layer and pure Li metal with multilayer nanostructured SEI. These results highlight the possible tuning of crucial structural and chem. features of EDLi and SEI through additives and consequently direct correlation with electrochem. performance, providing valuable guidelines to rational selection, design, and synthesis of additives for new battery chemistries. After reading the article, we found that the author used Vinylene carbonate(cas: 872-36-6Quality Control of Vinylene carbonate)

Vinylene carbonate(cas: 872-36-6) belongs to esters. Alkyl carbonates find applications as solvents for lithium ion battery electrolytes and the use of high quality battery grade electrolytes having extremely low water (<10 ppm) and acid (<10 ppm) contents are critical for achieving high electrochemical performance.Quality Control of Vinylene carbonate

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics