Category: 85-91-6

He, Shuang; Tan, Guangying; Luo, Anping; You, Jingsong published an article in 2018, the title of the article was Rhodium-catalyzed oxidative C-H/C-H cross-coupling of aniline with heteroarene: N-nitroso group enabled mild conditions.Reference of Methyl N-Methylanthranilate And the article contains the following content:

A rhodium-catalyzed oxidative C-H/C-H cross-coupling reaction of an N-nitrosoaniline with a heteroarene under mild conditions was developed to obtain (2-aminophenyl)heteroaryls I [R1 = H, 6-MeO, 4-CF3, etc.; R2 = H, Me, i-Pr, i-Bu, Bn; R3 = benzothiophen-2-yl, 5-Me-2-thienyl, benzofuran-2-yl, etc.]. The judicious choice of the N-nitroso group as a directing group enabled heightened reactivity. The coupled products were easily transformed into various (2-aminophenyl)heteroaryl derivatives I. The experimental process involved the reaction of Methyl N-Methylanthranilate(cas: 85-91-6).Reference of Methyl N-Methylanthranilate

The Article related to aminophenyl heteroaryl preparation, nitrosoaniline heteroarene rhodium catalyst oxidative cross coupling, Heterocyclic Compounds (One Hetero Atom): Areno- and Diarenothiophenes and other aspects.Reference of Methyl N-Methylanthranilate

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

Shakam, Huda M.; Mohamed, Abeer A.; Salem, Mohamed Z. M. published an article in 2022, the title of the article was Down-regulatory effect of essential oils on fungal growth and Tri4 gene expression for some Fusarium oxysporum strains: GC-MS analysis of essential oils.SDS of cas: 85-91-6 And the article contains the following content:

The objectives of this work were to evaluate the efficacy of Eucalyptus camaldulensis green branches (GB) and Origanum majorana whole plant (WP) essential oils (EOs) on Tri4 gene expression and Fusarium oxysporum strains growth In vitro. Five strains of Fusarium oxysporum were identified molecularly through polymerase chain reaction (PCR) amplification of the internal transcript spacer (ITS) region. The efficacy of the EOs from Eucalyptus camaldulensis GB and Origanum majorana WP on Tri4 gene expression and F. oxysporum strains growth were evaluated In vitro. GC-MS anal. of the EOs referred that 1,8-cineole, and spathulenol were presented in E. camaldulensis GB, while in O. majorana WP were tricyclene, and p-cymene as abundant compounds E. camaldulensis and O. majorana EOs showed MIC of 32-64 mug/mL and 32 mug/mL, resp. E. camaldulensis EO was more suppressive against all the F. oxysporum strains. Both EOs reduced Tri4 gene expression significantly compared with control. qRT-PCR results revealed a down-regulation in Tri4 gene expression of all of F. oxysporum strains exposed to both EOs at the MIC values. The results suggest that both EOs can be used as safe and green bio-pesticide. The experimental process involved the reaction of Methyl N-Methylanthranilate(cas: 85-91-6).SDS of cas: 85-91-6

The Article related to fusarium oxysporum tri4 gene expression fungal growth essential oil, Plant Biochemistry: Photosynthesis (Algae, Bacteria, and Green Plants) and other aspects.SDS of cas: 85-91-6

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

On August 7, 2020, Zhang, Yunfei; Sim, Jae Hun; MacMillan, Samantha N.; Lambert, Tristan H. published an article.Application of 85-91-6 The title of the article was Synthesis of 1,2-Dihydroquinolines via Hydrazine-Catalyzed Ring-Closing Carbonyl-Olefin Metathesis. And the article contained the following:

The synthesis of 1,2-dihydroquinolines by the hydrazine-catalyzed ring-closing carbonyl-olefin metathesis (RCCOM) of N-prenylated 2-aminobenzaldehydes is reported. Substrates with a variety of substitution patterns are shown. With an acid-labile protecting group on the nitrogen atom, in situ deprotection and autoxidation furnish quinoline. In comparison with related oxygen-containing substrates, the cycloaddition step of the catalytic cycle is shown to be slower, but the cycloreversion is found to be more facile. The experimental process involved the reaction of Methyl N-Methylanthranilate(cas: 85-91-6).Application of 85-91-6

The Article related to alkenylaminobenzaldehyde ring closure carbonyl olefin metathesis hydrazine, dihydroquinoline preparation, hydrazine ring closing carbonyl olefin metathesis catalyst, Heterocyclic Compounds (One Hetero Atom): Quinolines and Isoquinolines and other aspects.Application of 85-91-6

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

On March 5, 2021, Minoshima, Mai; Uchida, Keisuke; Nakamura, Yu; Hosoya, Takamitsu; Yoshida, Suguru published an article.Computed Properties of 85-91-6 The title of the article was Acylalkylation of Arynes Generated from o-Iodoaryl Triflates with Hydrosilanes and Cesium Fluoride. And the article contained the following:

An efficient method to generate aryne intermediates from o-iodoaryl triflates triggered by triethylsilane and cesium fluoride is disclosed. This method realized the acylalkylation of arynes using easily available o-iodoaryl triflate-type precursors, which was difficult when using conventional nucleophilic activators. A wide range of (hetero)arenes including various fused benzothiazoles were successfully synthesized from o-iodoaryl triflates by virtue of their good accessibility and divergent transformations of aryne intermediates. The experimental process involved the reaction of Methyl N-Methylanthranilate(cas: 85-91-6).Computed Properties of 85-91-6

The Article related to iodoaryl triflate dicarbonyl compound acylalkylation cesium fluoride hydrosilane and other aspects.Computed Properties of 85-91-6

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

On September 30, 2021, Farag, Mohamed A.; Afifi, Sherif M.; Rasheed, Dalia M.; Khattab, Amira R. published an article.Electric Literature of 85-91-6 The title of the article was Revealing compositional attributes of Glossostemon bruguieri Desf. root geographic origin and roasting impact via chemometric modeling of SPME-GC-MS and NMR metabolite profiles. And the article contained the following:

Glossostemon bruguieri Desf. (Moghat, Sterculiaceae), is a shrub well-known for its thick long-tapering dark colored roots, grown in the Middle East and North Africa. Studies on Glossostemon have focused on its nutritive value and health benefits attributed to its phenolic content with no extensive anal. of secondary metabolome. NMR metabolite fingerprinting of 12 G. bruguieri root specimens of different origins using 1D and 2D experiments identified 12 major primary and secondary metabolites. Orthogonal partial least squares-discriminant anal. (OPLS-DA) of NMR aromatic regions was competent in discriminating between roots origin based on moghatin and pinoresinol levels. Quantification of 1H NMR spectra revealed enrichment of Siwa specimens in sugars i.e., sucrose and inositol (17.89 and 12.06μg/mg, resp.), as well as some secondary metabolites viz. moghatin, pinoresinol, takakin and fraxetin (7.73, 4.55, 3.81 and 3.03μg/mg, resp.), posing it for future incorporation in nutraceuticals. However, much less is known regarding aroma and roasting impact on root chem. composition Volatile profiles of 15 unroasted and roasted specimens were analyzed using headspace solid-phase microextraction coupled to mass spectrometry. 100 Volatile constituents were identified dominated by aldehydes, ethers and mono- and sesquiterpenes, whereas esters were abundant in roasted roots. OPLS-DA identified 2-ethyl-6-methylpyrazine and 5-methyl-2-furfural as roasting descriptors. The experimental process involved the reaction of Methyl N-Methylanthranilate(cas: 85-91-6).Electric Literature of 85-91-6

The Article related to glossostemon bruguieri root composition metabolite roasting chemometrics spmegcms nmr, Food and Feed Chemistry: Additives, Sweeteners, Flavorings, Condiments, and Confectionery and other aspects.Electric Literature of 85-91-6

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

On November 19, 2021, Qian, Peng; Liu, Jiaojiao; Zhang, Yan; Wang, Zhiyong published an article.Electric Literature of 85-91-6 The title of the article was Tunable Electrosynthesis of Anthranilic Acid Derivatives via a C-C Bond Cleavage of Isatins. And the article contained the following:

A facile and direct electrocatalytic C-C bond cleavage/functionalization reaction of isatins with alcs./ammonia to form 2-aminobenzoates/2-aminobenzamides I [R1 = OMe, OEt; R2 = H, 5-F, 3-Me, etc.; R3 = NH2, HNC(O)OMe, etc.] was developed. With isatins as the amino-attached C1 sources, a variety of aminobenzoates and aminobenzamides were synthesized in moderate to good yields under mild conditions. The experimental process involved the reaction of Methyl N-Methylanthranilate(cas: 85-91-6).Electric Literature of 85-91-6

The Article related to aminobenzoate or aminobenzamide green preparation, isatin alc or ammonia carbon bond cleavage, Benzene, Its Derivatives, and Condensed Benzenoid Compounds: Esters, Acyl Peroxides, Acyl Halides and other aspects.Electric Literature of 85-91-6

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

Shang, Yaping; Jonnada, Krishna; Yedage, Subhash Laxman; Tu, Hua; Zhang, Xiaofeng; Lou, Xin; Huang, Shijun; Su, Weiping published an article in 2019, the title of the article was Rhodium(III)-catalyzed indole synthesis at room temperature using the transient oxidizing directing group strategy.Category: esters-buliding-blocks And the article contains the following content:

Rh-catalyzed reactions of N-alkyl anilines with internal alkynes at room temperature have been developed using an in situ generated N-nitroso group as a transient oxidizing directing group. Due to mild reaction conditions, this method enabled synthesis of a broad range of N-alkyl indoles, including even two indole-based medicinal compds I (R1 = Me, allyl, C6H5, etc.; R2 = 5-Me, 6-CH2OMe, 5-NO2, etc.) and II (R1 = Me, Et, i-Pr, etc.; R2 = H, 5-Me, 5-CO2Me, etc.; R3 = n-Bu, C6H5, 4-MeC6H5, etc.; R4 = Me, COMe, 3-FC6H5, etc.). This work disclosed the feasibility of the transient oxidizing directing group strategy in C-H functionalization reactions, which possesses the potential to enhance overall step-economy and impart new reactivity patterns to substrates. The experimental process involved the reaction of Methyl N-Methylanthranilate(cas: 85-91-6).Category: esters-buliding-blocks

The Article related to alkyl indole preparation, internal alkyne aniline transient oxidizing directing group rhodium catalyst, Heterocyclic Compounds (One Hetero Atom): Indoles, Indolizines, Carbazoles, and Other Arenopyrroles and other aspects.Category: esters-buliding-blocks

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

On May 31, 2017, Thatte, Chittaranjan S.; Rathnam, Manapragada V.; Namdeo, Ashutosh; Rane, Kiran published an article.Related Products of 85-91-6 The title of the article was Heterogeneous catalytic solvent-free synthesis of 3,3,5-trimethyl cyclohexyl anthranilic acid esters via transesterification. And the article contained the following:

The transesterification of anthranilates with both mixtures of cis and trans and pure trans 3,3,5-tri-Me cyclohexanol was studied using ‘calcium-oxide- and magnesium-oxide’-based catalysts under ‘solvent-free’ conditions. The catalysts were characterized by XRD, CO2-TPD, BET-surface area, and FEG-SEM anal. Pure calcium oxide was found to be the most effective heterogeneous catalyst. Pure ‘calcium-oxide’-based catalyst was recycled five times without appreciable loss in the catalytic activity. The TOF after five recycles was 10.7 mol/mol of catalyst/h. The study was further extended for the synthesis of new anthranilates. The synthesized pure esters have been characterized by UV-Vis, IR-, 1H NMR-, and 13C NMR spectroscopies and mass spectrometry. The experimental process involved the reaction of Methyl N-Methylanthranilate(cas: 85-91-6).Related Products of 85-91-6

The Article related to trimethyl cyclohexyl anthranilic acid transesterification heterogeneous catalyst, Industrial Organic Chemicals, Leather, Fats, and Waxes: Manufacture Of Industrial Organic Chemicals and other aspects.Related Products of 85-91-6

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

Kang, Houng; Jemison, Adriana L.; Nigro, Erin; Kozlowski, Marisa C. published an article in 2019, the title of the article was Oxidative Coupling of 3-Oxindoles with Indoles and Arenes.Related Products of 85-91-6 And the article contains the following content:

A highly efficient method for the oxidative coupling of 2-substituted 3-oxindoles with aromatic compounds to form 2,2-disubstituted indolin-3-ones with broad scope is described. This work utilized oxygen as the terminal oxidant and a base-metal catalyst under mild conditions instead of toxic/precious-metal reagents and higher-mol.-weight oxidants. Quaternary structures were produced in modest-to-excellent yields (up to 96 %) without prefunctionalization. The experimental process involved the reaction of Methyl N-Methylanthranilate(cas: 85-91-6).Related Products of 85-91-6

The Article related to disubstituted indolinone preparation oxidative coupling indole oxindole, catalysis, coinage metals, oxidative coupling, oxygen, sustainable, Heterocyclic Compounds (One Hetero Atom): Indoles, Indolizines, Carbazoles, and Other Arenopyrroles and other aspects.Related Products of 85-91-6

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

Yuan, Zaifeng; Li, Na; Zhu, Chunyu; Xia, Chengfeng published an article in 2018, the title of the article was Copper-catalyzed synthesis of α-amino nitriles through methyl transfer from DMF to aromatic amines.Application of 85-91-6 And the article contains the following content:

Synthesis of α-amino nitriles RR1NCH2CN [R = C6H5, 4-ClC6H4, 1-naphthyl, etc.; R1 = CH3, C2H5, c-C6H11, etc.] and α-amino nitriles, e.g., I via copper-catalyzed activation of C(sp3)-H bonds of DMF at room temperature, which resulted in Me transfer to aromatic amines followed by cyanation was described. This process featured excellent functional group tolerance, broad substrate scope and high activity under ambient conditions. The experimental process involved the reaction of Methyl N-Methylanthranilate(cas: 85-91-6).Application of 85-91-6

The Article related to alpha amino nitrile preparation, secondary aromatic amine dimethyl formamide cyanation copper catalyst, Benzene, Its Derivatives, and Condensed Benzenoid Compounds: Nitriles, Isonitriles, and Acyl Cyanides and other aspects.Application of 85-91-6

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics