One-pot production of diethyl maleate via catalytic conversion of raw lignocellulosic biomass was written by Cai, Zhenping;Chen, Rujia;Zhang, Hao;Li, Fukun;Long, Jinxing;Jiang, Lilong;Li, Xuehui. And the article was included in Green Chemistry in 2021.Product Details of 763-69-9 The following contents are mentioned in the article:
The conversion of lignocellulose into a value-added chem. with high selectivity is of great significance but is a big challenge due to the structural diversities of biomass components. Here, we have reported an efficient approach for the one-step conversion of raw lignocellulose into di-Et maleate by the polyoxometalate ionic liquid [BSmim]CuPW12O40 in ethanol under mild conditions. The results reveal that all of the fractions in biomass, i.e., cellulose, lignin and hemicellulose, were simultaneously converted into di-Et maleate (DEM), achieving a 329.6 mg g-1 yield and 70.3% selectivity from corn stalk. Importantly, the performance of the ionic liquid catalyst [BSmim]CuPW12O40 was nearly twice that of CuPW12O40, which can be attributed to the lower incorporation of the Cu2+ site in [BSmim]CuPW12O40. Hence, this process opens a promising route for producing bio-based bulk chems. from raw lignocellulose without any pretreatment. This study involved multiple reactions and reactants, such as Ethyl 3-ethoxypropanoate (cas: 763-69-9Product Details of 763-69-9).
Ethyl 3-ethoxypropanoate (cas: 763-69-9) belongs to esters. Esters are widespread in nature and are widely used in industry. In nature, fats are in general triesters derived from glycerol and fatty acids. Esters are responsible for the aroma of many fruits. Cyclic esters are called lactones, regardless of whether they are derived from an organic or inorganic acid. One example of an organic lactone is γ-valerolactone.Product Details of 763-69-9
Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics