Absorbent selection based on the COSMO-RS method for carbon capture in integrated gasification combined cycle plant was written by Li, Yun;Huang, Weijia;Zheng, Danxing;Mi, Yue. And the article was included in Beijing Huagong Daxue Xuebao, Ziran Kexueban in 2014.Application In Synthesis of Ethyl 3-ethoxypropanoate The following contents are mentioned in the article:
Around 150 commonly used industrial solvents, with and without N atoms in their mols., have been compared as absorbents at T=298.15 K for carbon capture in IGCC plants according to the feed gas characteristics. Henry’s constants of the CO2+absorbent systems were calculated using the COSMO-RS software. It was found that the amount of CO2 absorbed decreased with the increasing number of hydroxyl groups in the absorbent mol. Absorbents having ether, ketone or ester groups showed excellent absorption behavior for CO2. However, acids, alcs. and alkanes showed the worst dissolving ability for CO2. The isothermal synthesis method was employed for the determination of CO2 solubility in four selected absorbents with ether and ester groups at T=298.15 K and pressures up to 1.3 MPa. In addition, Henry’s constants of the above systems were calculated It was found that the exptl. data showed good agreement with the predicted values. It was found that diethylene glycol monoethyl ether acetate (carbitol acetate) was the best absorbent for CO2 and this material should be studied further for use in carbon capture in an integrated gasification combined cycle (IGCC) plant. This study involved multiple reactions and reactants, such as Ethyl 3-ethoxypropanoate (cas: 763-69-9Application In Synthesis of Ethyl 3-ethoxypropanoate).
Ethyl 3-ethoxypropanoate (cas: 763-69-9) belongs to esters. Esters perform as high-grade solvents for a broad array of plastics, plasticizers, resins, and lacquers, and are one of the largest classes of synthetic lubricants on the commercial market. Acyl chlorides and acid anhydrides alcoholysis is another way to produce esters. Acyl chlorides and acid anhydrides react with alcohols to produce esters. Anydrous conditions are recommended since both acyl chlorides and acid anhydrides react with water.Application In Synthesis of Ethyl 3-ethoxypropanoate
Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics