Morphological and structural properties of isotactic polypropylene filled with nano-zinc oxide as investigated by dynamic rheology, creep and recovery in shear was written by Liu, Jingru;Liang, Hongwei. And the article was included in Polymer Bulletin (Heidelberg, Germany) in 2022.Computed Properties of C73H108O12 This article mentions the following:
Morphol. and structural properties of nano-zinc oxide/isotactic polypropylene (nano-ZnO/iPP) composites with different nano-ZnO concentrations before and after compatibilization were investigated by SEM, dynamic rheol., shear creep and creep-recovery measurements. The complex viscosity and storage modulus of the composite melts first decrease and then increase with increasing nano-ZnO loading. The pseudo-solid-like behavior appearing in high-loaded composites could be attributed to the formation of the filler percolation network resulting from particle-particle interactions. The incorporating of maleic anhydride/styrene-grafted random copolypropylene (MPP) brings about the reduction of the number of big agglomerates of nano-ZnO, followed by the decrease in modulus and viscosity. Large nano-ZnO agglomerates or more complete percolation network formation enhances the creep resistance of iPP. This finding is explained by the existence of long relaxation time in the high-loaded system assigned to the relaxation of the iPP chains attached to the particle surface. Moreover, MPP has a pronounced influence on the shear creep and recovery behavior of the composites. Weighted relaxation spectra calculated from the dynamic frequency sweep together with shear creep and recovery curves quantify these assumptions. Dynamic rheol. and shear creep and creep-recovery measurements are sensitive tools to get insights into the dispersion state of nanoparticles in the polymer composites, as well as the interactions (i.e., particle-polymer interaction, particle-particle interaction) in such systems. In the experiment, the researchers used many compounds, for example, 2,2-Bis(((3-(3,5-di-tert-butyl-4-hydroxyphenyl)propanoyl)oxy)methyl)propane-1,3-diyl bis(3-(3,5-di-tert-butyl-4-hydroxyphenyl)propanoate) (cas: 6683-19-8Computed Properties of C73H108O12).
2,2-Bis(((3-(3,5-di-tert-butyl-4-hydroxyphenyl)propanoyl)oxy)methyl)propane-1,3-diyl bis(3-(3,5-di-tert-butyl-4-hydroxyphenyl)propanoate) (cas: 6683-19-8) belongs to esters. Esters are widespread in nature and are widely used in industry. In nature, fats are in general triesters derived from glycerol and fatty acids. Esters are responsible for the aroma of many fruits, including apples, durians, pears, bananas, pineapples, and strawberries. Because of their lack of hydrogen-bond-donating ability, esters do not self-associate. Consequently, esters are more volatile than carboxylic acids of similar molecular weight.Computed Properties of C73H108O12
Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics