Category: 583-04-0

Smeyne, Dylan published the artcileElectrochemical esterification via oxidative coupling of aldehydes and alcohols, Application In Synthesis of 583-04-0, the main research area is aldehyde alc oxidative coupling esterification electrochem.

An electrolytic method for the direct oxidative coupling of aldehydes with alcs. to produce esters is described. This method involves anodic oxidation in presence of TBAF as supporting electrolyte in an undivided electrochem. cell equipped with graphite electrodes. This method successfully couples a wide range of alcs. to benzaldehydes with yields ranging from 70 to 90%. The protocol is easy to perform at a constant voltage conditions and offers a sustainable alternative over conventional methods.

Tetrahedron Letters published new progress about Alcohols Role: RCT (Reactant), RACT (Reactant or Reagent). 583-04-0 belongs to class esters-buliding-blocks, name is Allyl benzoate, and the molecular formula is C10H10O2, Application In Synthesis of 583-04-0.

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

Nakajima, Takumi published the artcileProduction of Alkyl Aryl Sulfides from Aromatic Disulfides and Alkyl Carboxylates via a Disilathiane-Disulfide Interchange Reaction, COA of Formula: C10H10O2, the main research area is alkyl aryl sulfide preparation; aromatic disulfide alkyl carboxylate interchange; alkyl carboxylate; carbon-sulfur bond formation; disilathiane; disulfide; sulfur-sulfur bond cleavage.

The results of this study show that disilathiane was an effective mediator in the synthesis of alkyl aryl sulfides RSR1 [R = Me, Et, Bn, etc.; R1 = Ph, 4-MeC6H4, 2-naphthyl, etc.] with disulfides and alkyl carboxylates. Mechanistic studies suggested that disilathiane promotes cleavage of the sulfur-sulfur bond of disulfides to generate thiosilane as a key intermediate. Diselenides were also applicable to this transformation to produce the corresponding selenides.

Chemistry – An Asian Journal published new progress about Disulfides Role: RCT (Reactant), RACT (Reactant or Reagent). 583-04-0 belongs to class esters-buliding-blocks, name is Allyl benzoate, and the molecular formula is C10H10O2, COA of Formula: C10H10O2.

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

Yang, Xintuo published the artcilePalladium(II)-Catalyzed Enantioselective Hydrooxygenation of Unactivated Terminal Alkenes, Application In Synthesis of 583-04-0, the main research area is terminal alkene carboxylic acid palladium catalyst enantioselective hydrooxygenation; ester preparation.

A novel Pd(II)-catalyzed enantioselective Markovnikov hydrooxygenation of unactivated terminal alkenes using a substituted pyridinyl oxazoline (Pyox) ligand was developed. Herein it was discovered that the (EtO)2MeSiH/BQ redox system is vital for the highly selective and efficient hydrooxygenation, where the alkylpalladium(II) species generated from enantioselective oxypalladation step was reduced by silane. This method provides efficient access to optically pure alc. esters from easily available alkenes with excellent enantioselectivities and features a broad substrate scope.

Journal of the American Chemical Society published new progress about Alcohols Role: SPN (Synthetic Preparation), PREP (Preparation). 583-04-0 belongs to class esters-buliding-blocks, name is Allyl benzoate, and the molecular formula is C10H10O2, Application In Synthesis of 583-04-0.

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

Xu, Qi published the artcileVisible-Light-Induced Sulfur-Alkenylation of Alkenes, COA of Formula: C10H10O2, the main research area is dialkyl butenedithiol preparation diastereoselective regioselective; alkene ketene dithioacetal sulfur alkenylation trimethylphenylacridinium perchlorate photoredox catalyst.

A visible-light-induced intermol. sulfur-alkenylation of alkenes RCH=CR1R2 (R = H, Me, ethyl; R1 = H, Me, ethyl; R2 = Et, Ph, 2-naphthyl, acetyloxy, etc.; R1R2 = -(CH2)4-, -(CH2)5-; RR2 = -(CH2)3-, -(CH2)4-, -(CH2)2CH=CH-, etc.), 6,6-dimethyl-2-methylene-bicyclo[3.1.1]heptane including both activated and unactivated alkenes, mols. even induced by sunlight under ambient conditions is described. This sulfur-alkenylation reaction proceed in a highly regio- and stereospecific manner involving the visible-light-induced conversion of a ketene dithioacetal to the thiavinyl 1,3-dipole intermediate, followed by a formal [3+2] cycloaddition and C-S bond cleavage. Furthermore, it is also an efficient approach for the late-stage functionalization of natural products and complex mols., even being induced by sunlight under ambient conditions.

Organic Letters published new progress about [3+2] Cycloaddition reaction catalysts (stereo-, regioselective). 583-04-0 belongs to class esters-buliding-blocks, name is Allyl benzoate, and the molecular formula is C10H10O2, COA of Formula: C10H10O2.

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

Yadav, Suresh Kumar published the artcileCobalt(III)-Catalyzed Regioselective [4 + 2]-Annulation of N-Chlorobenzamides with Substituted Alkenes, Application In Synthesis of 583-04-0, the main research area is dihydroisoquinolinone regioselective preparation; chlorobenzamide allylic compound annulation cobalt catalyst.

Synthesis of 3,4-dihydroisoquinolinone derivatives I [R1 = H, 6-Me, 7-Cl, etc.; R2 = S(O)2Ph, OPh, CN, etc.] via Co(III)-catalyzed redox-neutral [4 + 2] annulation of N-chlorobenzamides/acrylamides with substituted alkenes at ambient temperature in good yields was demonstrated. Intriguingly, the synthetically useful functional group of allylic coupling partners such as sulfonyl, carbonate, acetate, phosphate, amide, nitrile, and silane were retained in the final cyclized product. The present annulation reaction was compatible with various substituted benzamides and allylic coupling partners. To support the proposed reaction mechanism, competition experiments, deuterium labeling studies, and kinetic isotope effect studies were performed.

Journal of Organic Chemistry published new progress about Allylic compounds Role: RCT (Reactant), RACT (Reactant or Reagent). 583-04-0 belongs to class esters-buliding-blocks, name is Allyl benzoate, and the molecular formula is C10H10O2, Application In Synthesis of 583-04-0.

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

Sieger, Simon V. published the artcileHydrofunctionalization of Propadiene – New Life for a Previously Unwanted Product, Synthetic Route of 583-04-0, the main research area is nucleophile propadiene palladium catalyst allylation; allyl preparation.

A highly versatile palladium-catalyzed allylation reaction of several pronucleophiles was reported. The use of propadiene in toluene provides an atom economic and waste-free access to allylated nucleophiles, a structural motif with almost unlimited possibilities for further functionalization. In addition to N-, O- and S-pronucleophiles, the Pd/BINAP system was capable of adding a C-pronuceophile to allene. A plausible mechanism was supported by deuterium labeling experiments

ACS Catalysis published new progress about Allyl amines Role: SPN (Synthetic Preparation), PREP (Preparation). 583-04-0 belongs to class esters-buliding-blocks, name is Allyl benzoate, and the molecular formula is C10H10O2, Synthetic Route of 583-04-0.

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

Li, Nan published the artcileCobalt-Catalyzed Deprotection of Allyl Carboxylic Esters Induced by Hydrogen Atom Transfer, Related Products of esters-buliding-blocks, the main research area is carboxylic acid preparation chemoselective; allyl carboxylic ester deprotection cobalt catalyst.

A brief, efficient method has been developed for the removal of the allyl protecting group from allyl carboxylic esters RC(O)OCH2CH=CH2 (R = cyclohexyl, Ph, thiophen-2-yl, 2H-1,3-benzodioxol-5-yl, etc.) using a Co(II)/TBHP/(Me2SiH)2O catalytic system. This facile strategy displays excellent chemoselectivity, functional group tolerance, and high yields. This transformation probably occurs through the hydrogen atom transfer process, and a Co(III)-six-membered cyclic intermediate is recommended.

Organic Letters published new progress about Carboxylic acids Role: SPN (Synthetic Preparation), PREP (Preparation). 583-04-0 belongs to class esters-buliding-blocks, name is Allyl benzoate, and the molecular formula is C10H10O2, Related Products of esters-buliding-blocks.

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

Bobrova, Angelina Yu. published the artcile(2-Fluoroallyl)pyridinium tetrafluoroborates: novel fluorinated electrophiles for Pd-catalyzed allylic substitution, Name: Allyl benzoate, the main research area is fluoroallyl pyridinium tetrafluoroborate allylic substitution palladium catalyst; amine fluoroallyl preparation.

An efficient two-step approach to 2-fluoroallyl amines was developed that involves the synthesis of (2-fluoroallyl)pyridinium tetrafluoroborates from readily available gem-bromofluorocyclopropanes and the application of the former as novel and stable 2-fluoroallyl electrophiles for Pd-catalyzed allylic substitution.

Organic & Biomolecular Chemistry published new progress about Allyl amines Role: SPN (Synthetic Preparation), PREP (Preparation) (fluoro). 583-04-0 belongs to class esters-buliding-blocks, name is Allyl benzoate, and the molecular formula is C10H10O2, Name: Allyl benzoate.

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

Nolan, Mark D. published the artcileRadical-mediated thiol-ene ‘Click’ reactions in deep eutectic solvents for bioconjugation, COA of Formula: C10H10O2, the main research area is peptide synthesis deep eutectic solvent bioconjugation thiol ene reaction; glycosylation hydrothiolation radical UV green chem recycling fluorescence.

Herein, we report the first application of deep eutectic solvents (DESs) in radical-mediated hydrothiolation reactions. Under UV and atm.-oxygen mediated conditions, the thiol-ene reaction was applied to amino acid and peptide ligation in DESs. The conditions facilitate highly-efficient synthesis of biomol. targets using a ‘green’ methodol., with complete recycling of the reaction medium. Fluorescent labeling and glycosylation of a minimal sequence mimetic of angiotensin-converting enzyme 2 capable of binding the SARS-CoV-2 spike protein is demonstrated for applications in the study of inhibition of COVID-19 infectivity.

Green Chemistry published new progress about COVID-19. 583-04-0 belongs to class esters-buliding-blocks, name is Allyl benzoate, and the molecular formula is C10H10O2, COA of Formula: C10H10O2.

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

Javaherian, Mohammad published the artcileNano-silica melamine trisulfonic acid as an efficient and reusable heterogeneous catalyst in esterification reactions, Formula: C10H10O2, the main research area is silica melamine trisulfonic acid catalyst esterification reaction.

The use of nano-silica melamine trisulfonic acid as a reusable heterogeneous solid acid catalyst in the esterification reaction of carboxylic acids and alcs. is reported. The reaction conditions were optimized by testing temperature, each component of catalyst, feedstock ratios as well as load of catalyst. The synthesized catalyst was characterized by X-ray diffraction, SEM, Fourier transform IR spectroscopy, and thermogravimetric anal. techniques. The results showed that nano-silica melamine trisulfonic acid was an efficient dehydrating agent in the condensing reactions between different kinds of aliphatic and aromatic carboxylic acids and alcs. The method was simple, rapid, straightforward, catalyst reusability, and holds potential for further application in acid-catalyzed organic synthesis and industrial requirements.

Journal of the Iranian Chemical Society published new progress about Acetylation. 583-04-0 belongs to class esters-buliding-blocks, name is Allyl benzoate, and the molecular formula is C10H10O2, Formula: C10H10O2.

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics