Category: 37905-02-5

Synthesis and biological activity of the sex pheromone components and their structural analogs of the click beetles Agriotes was written by Laats, Koit;Siirde, Kaarel;Kudryavtsev, Igor;Kogerman, Avo;Rang, Heino;Erm, Ants;Teng, Signe;Ismailov, Vladimir;Pristavko, Valeri. And the article was included in Eesti Teaduste Akadeemia Toimetised, Keemia in 1992.Category: esters-buliding-blocks The following contents are mentioned in the article:

The biol. active components of six species of the click beetle Agriotes – esters of geraniol, nerol, 8-hydroxygeraniol, (E,E)-farnesol as well as their structural isomers – were synthesized. The relationship between the isomeric composition of the synthesized compounds or their mixtures and the sex behavior of the most harmful species, viz., A. gurgistanus F., A. sputator L., A. lineatus L. (two subspecies), A. obscurus L., A. ustulatus S., A. tauricus Heyd., was established. On this basis optimum synthesis paths were chosen and attractant compositions developed for monitoring click beetles by means of pheromone traps. This study involved multiple reactions and reactants, such as (2E,6E)-3,7-Dimethyl-8-oxoocta-2,6-dien-1-yl acetate (cas: 37905-02-5Category: esters-buliding-blocks).

(2E,6E)-3,7-Dimethyl-8-oxoocta-2,6-dien-1-yl acetate (cas: 37905-02-5) belongs to esters. Esters typically have a pleasant smell; those of low molecular weight are commonly used as fragrances and are found in essential oils and pheromones. Esterification is the general name for a chemical reaction in which two reactants (typically an alcohol and an acid) form an ester as the reaction product. Esters are common in organic chemistry and biological materials.Category: esters-buliding-blocks

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

Stereoselective synthesis of solanesol and all-trans-decaprenol was written by Sato, Kikumasa;Inoue, Seiichi;Onishi, Akira;Uchida, Nobuhiko;Minowa, Nobuto. And the article was included in Journal of the Chemical Society in 1981.Quality Control of (2E,6E)-3,7-Dimethyl-8-oxoocta-2,6-dien-1-yl acetate The following contents are mentioned in the article:

Stereochem. pure 1,5-dienes were prepared in moderate to good yields by coupling of allylic p-tolyl sulfones with an allylic bromide. E.g., coupling reaction of all-trans-bromogeranyl acetate (I) with the sulfone II and with higher isoprene analogs, followed by reductive elimination of p-MeC₆H₄SO₂, gave all-trans-polyprenols and decaprenol (III; n = 10) stereoselectively. Solanesol (III; n = 9) was similarly prepared through coupling of ClCH₂CMe:CHCH₂OAc. This study involved multiple reactions and reactants, such as (2E,6E)-3,7-Dimethyl-8-oxoocta-2,6-dien-1-yl acetate (cas: 37905-02-5Quality Control of (2E,6E)-3,7-Dimethyl-8-oxoocta-2,6-dien-1-yl acetate).

(2E,6E)-3,7-Dimethyl-8-oxoocta-2,6-dien-1-yl acetate (cas: 37905-02-5) belongs to esters. Carboxylic acid esters of low molecular weight are colourless, volatile liquids with pleasant odours, slightly soluble in water. Acyl chlorides and acid anhydrides alcoholysis is another way to produce esters. Acyl chlorides and acid anhydrides react with alcohols to produce esters. Anydrous conditions are recommended since both acyl chlorides and acid anhydrides react with water.Quality Control of (2E,6E)-3,7-Dimethyl-8-oxoocta-2,6-dien-1-yl acetate

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

Application of [3 + 2] nitrile oxide cycloaddition chemistry to the construction of retinoid skeleton and to a new formal synthesis of (±)-ascofuranone and geiparvarin was written by Baraldi, Pier Giovanni;Bigoni, Angelica;Guarneri, Mario;Manfredini, Stefano;Pollini, Gian Piero;Simoni, Daniele. And the article was included in Farmaco in 1993.Category: esters-buliding-blocks The following contents are mentioned in the article:

A flexible approach to the construction of the C-20 retinoid carbon skeleton involving the intermol. [3 + 2] cycloaddition of the nitriles oxide I derived from a C-14 aldehyde component with (E)-HCCCMe:CHCH₂OAc or (E,E)-CH₂:CHCMe:CHCH₂OAc, followed by Mo(CO)₆-promoted ring opening of the derived 3,5-disubstituted isoxazoline or isoxazole ring systems, has been accomplished. The same strategy has been also successfully applied as a tool for the crucial carbon-carbon bond forming step to the formal synthesis of (±)-ascofuranone and to a new synthesis of geiparvarin. This study involved multiple reactions and reactants, such as (2E,6E)-3,7-Dimethyl-8-oxoocta-2,6-dien-1-yl acetate (cas: 37905-02-5Category: esters-buliding-blocks).

(2E,6E)-3,7-Dimethyl-8-oxoocta-2,6-dien-1-yl acetate (cas: 37905-02-5) belongs to esters. Esters typically have a pleasant smell; those of low molecular weight are commonly used as fragrances and are found in essential oils and pheromones. Many esters have the potential for conformational isomerism, but they tend to adopt an s-cis (or Z) conformation rather than the s-trans (or E) alternative, due to a combination of hyperconjugation and dipole minimization effects. The preference for the Z conformation is influenced by the nature of the substituents and solvent, if present. Lactones with small rings are restricted to the s-trans (i.e. E) conformation due to their cyclic structure.Category: esters-buliding-blocks

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

Efficient Total Synthesis of Lycophyll (ψ,ψ-Carotene-16,16′-diol) was written by Jackson, Henry L.;Nadolski, Geoffry T.;Braun, Cristi;Lockwood, Samuel F.. And the article was included in Organic Process Research & Development in 2005.HPLC of Formula: 37905-02-5 The following contents are mentioned in the article:

A practical procedure is described for the total synthesis of lycophyll (16,16′-dihydroxy-lycopene; ψ,ψ-carotene-16,16′-diol), based on a C10 + C20 + C10 synthetic methodol. using the com. available materials geraniol (C10) and crocetindialdehyde (C20). A late-stage double Wittig olefination on crocetindialdehyde was used to form the desired lycophyll scaffold in eight linear synthetic steps, while generating a mixture of polyenic geometric isomers that could be effectively separated using HPLC. All-trans lycophyll was subsequently separated to >95% purity by semipreparative chromatog. using a C30 carotenoid column. This study involved multiple reactions and reactants, such as (2E,6E)-3,7-Dimethyl-8-oxoocta-2,6-dien-1-yl acetate (cas: 37905-02-5HPLC of Formula: 37905-02-5).

(2E,6E)-3,7-Dimethyl-8-oxoocta-2,6-dien-1-yl acetate (cas: 37905-02-5) belongs to esters. Esters are widespread in nature and are widely used in industry. In nature, fats are in general triesters derived from glycerol and fatty acids. Esters are responsible for the aroma of many fruits, including apples, durians, pears, bananas, pineapples, and strawberries. Because of their lack of hydrogen-bond-donating ability, esters do not self-associate. Consequently, esters are more volatile than carboxylic acids of similar molecular weight.HPLC of Formula: 37905-02-5

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

Studies on monoterpene glucosides and related natural products. XXXVII. Biosynthesis of the iridoid glucosides in Lamium amplexicaule, Deutzia crenata and Galium spurium var. echinospermon was written by Inouye, Hiroyuki;Ueda, Shinichi;Uesato, Shinichi;Kobayashi, Koji. And the article was included in Chemical & Pharmaceutical Bulletin in 1978.Category: esters-buliding-blocks The following contents are mentioned in the article:

Administration of 10-hydroxygeraniol (I)-10–³H, iridodial (II)-10–³H, II–11–³H₂, II–10–³H glucoside, and II–11–³H to L. amplexicaule, D. crenata, and G. spurium var echinospermon established that lamioside (III) deutzioside, lamiide, and asperuloside are biosynthesized in these plants via I and II. This study involved multiple reactions and reactants, such as (2E,6E)-3,7-Dimethyl-8-oxoocta-2,6-dien-1-yl acetate (cas: 37905-02-5Category: esters-buliding-blocks).

(2E,6E)-3,7-Dimethyl-8-oxoocta-2,6-dien-1-yl acetate (cas: 37905-02-5) belongs to esters. Esters perform as high-grade solvents for a broad array of plastics, plasticizers, resins, and lacquers, and are one of the largest classes of synthetic lubricants on the commercial market. Esterification is the general name for a chemical reaction in which two reactants (typically an alcohol and an acid) form an ester as the reaction product. Esters are common in organic chemistry and biological materials.Category: esters-buliding-blocks

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

Farnesyl Diphosphate Analogues with ω-Bioorthogonal Azide and Alkyne Functional Groups for Protein Farnesyl Transferase-Catalyzed Ligation Reactions was written by Labadie, Guillermo R.;Viswanathan, Rajesh;Poulter, C. Dale. And the article was included in Journal of Organic Chemistry in 2007.Safety of (2E,6E)-3,7-Dimethyl-8-oxoocta-2,6-dien-1-yl acetate The following contents are mentioned in the article:

Eleven farnesyl diphosphate analogs, which contained ω-azide or alkyne substituents suitable for bioorthogonal Staudinger and Huisgen [3+2] cycloaddition coupling reactions, were synthesized. The analogs were evaluated as substrates for the alkylation of peptide cosubstrates by yeast protein farnesyl transferase. Five of the diphosphates were good alternative substrates for farnesyl diphosphate (FPP). Steady-state kinetic constants were measured for the active compounds, and the products were characterized by HPLC and LC-MS. Two of the analogs gave steady-state kinetic parameters (k_cat and K_m) very similar to those of the natural substrate. This study involved multiple reactions and reactants, such as (2E,6E)-3,7-Dimethyl-8-oxoocta-2,6-dien-1-yl acetate (cas: 37905-02-5Safety of (2E,6E)-3,7-Dimethyl-8-oxoocta-2,6-dien-1-yl acetate).

(2E,6E)-3,7-Dimethyl-8-oxoocta-2,6-dien-1-yl acetate (cas: 37905-02-5) belongs to esters. Esters perform as high-grade solvents for a broad array of plastics, plasticizers, resins, and lacquers, and are one of the largest classes of synthetic lubricants on the commercial market. Acyl chlorides and acid anhydrides alcoholysis is another way to produce esters. Acyl chlorides and acid anhydrides react with alcohols to produce esters. Anydrous conditions are recommended since both acyl chlorides and acid anhydrides react with water.Safety of (2E,6E)-3,7-Dimethyl-8-oxoocta-2,6-dien-1-yl acetate

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

Regio- and enantioselective functionalization of acyclic polyprenoids was written by Barrero, Alejandro F.;Quilez del Moral, Jose F.;Herrador, Maria del Mar;Sanchez, Elena M.;Arteaga, Jesus F.. And the article was included in Journal of the Mexican Chemical Society in 2006.Recommanded Product: (2E,6E)-3,7-Dimethyl-8-oxoocta-2,6-dien-1-yl acetate The following contents are mentioned in the article:

Results obtained in the positional selective functionalization of the double bond located at the terminal isopropylidene unit of acyclic polyprenoids were presented. Studies were undertaken to introduce hydroxyl or related oxygenated functions using oxidation with SeO₂ or catalytic procedures employing Pd(II) catalysts. This functionalization is found in many natural or synthetic acyclic terpenes and would permit subsequent regio- and stereoselective epoxidation reactions. Furthermore, the asym. dihydroxylation procedure was optimized using various polyprenoids in order to generalize this methodol. as the key step for the enantioselective synthesis of epoxides. This study involved multiple reactions and reactants, such as (2E,6E)-3,7-Dimethyl-8-oxoocta-2,6-dien-1-yl acetate (cas: 37905-02-5Recommanded Product: (2E,6E)-3,7-Dimethyl-8-oxoocta-2,6-dien-1-yl acetate).

(2E,6E)-3,7-Dimethyl-8-oxoocta-2,6-dien-1-yl acetate (cas: 37905-02-5) belongs to esters. Esters perform as high-grade solvents for a broad array of plastics, plasticizers, resins, and lacquers, and are one of the largest classes of synthetic lubricants on the commercial market. Because of their lack of hydrogen-bond-donating ability, esters do not self-associate. Consequently, esters are more volatile than carboxylic acids of similar molecular weight.Recommanded Product: (2E,6E)-3,7-Dimethyl-8-oxoocta-2,6-dien-1-yl acetate

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

Useful Catalytic Enantioselective Cationic Double Annulation Reactions Initiated at an Internal π-Bond: Method and Applications was written by Surendra, Karavadhi;Rajendar, Goreti;Corey, E. J.. And the article was included in Journal of the American Chemical Society in 2014.Product Details of 37905-02-5 The following contents are mentioned in the article:

The 1:1 complex of o,o’-dichloro-R-BINOL and SbCl₅ initiates the enantioselective cationic polycyclization of polyunsaturated substrates at a predictable π-bond which may be either terminal or, as shown herein, internal (e.g., I â†?II). The extension of this powerful construction to internal π-bonds expands the scope of this method and opens up very short pathways to numerous chiral polycyclic mols., including natural products and their analogs. Especially simple synthetic routes are disclosed that provide access to dysideapalaunic acid, dehydroabietic acid, and epi-podocarpic acid and illustrate the value of this enantioselective approach. This study involved multiple reactions and reactants, such as (2E,6E)-3,7-Dimethyl-8-oxoocta-2,6-dien-1-yl acetate (cas: 37905-02-5Product Details of 37905-02-5).

(2E,6E)-3,7-Dimethyl-8-oxoocta-2,6-dien-1-yl acetate (cas: 37905-02-5) belongs to esters. Esters typically have a pleasant smell; those of low molecular weight are commonly used as fragrances and are found in essential oils and pheromones. Esters are more polar than ethers but less polar than alcohols. They participate in hydrogen bonds as hydrogen-bond acceptors, but cannot act as hydrogen-bond donors, unlike their parent alcohols. This ability to participate in hydrogen bonding confers some water-solubility.Product Details of 37905-02-5

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

Reductive radical cyclizations of bromo acetals and (bromomethyl)silyl ethers of terpenoid alcohols was written by Lee, Edward R.;Lakomy, Ivo;Bigler, Peter;Scheffold, Rolf. And the article was included in Helvetica Chimica Acta in 1991.Application In Synthesis of (2E,6E)-3,7-Dimethyl-8-oxoocta-2,6-dien-1-yl acetate The following contents are mentioned in the article:

The tin hydride promoted and the reductive vitamin B₁₂ catalyzed radical cyclization of mixed 2-bromoacetaldehyde acetals and of (2-bromomethyl)dimethylsilyl ethers of allylic terpenoid alcs. was investigated: 3-oxadeca-5,9-dien-1-yl radicals undergo 5-exo cyclization to oxolanes, 3-oxa-2-siladeca-5,9-dien-1-yl radicals sequential 6-endoâ†?-exo tandem cyclization to cis-3-oxa-4-silabicyclo[4.3.0]nonanes I (R² = H, CH₂CO₂Me), and 3-oxa-2-silatetradeca-5,9,13-trien-1-yl radicals sequential 6-endoâ†?-endoâ†?-exo triple cyclization to trans-transoid-trans-12-oxa-11-silatricyclo[7.4.0.0^2,6]tridecanes (II). This study involved multiple reactions and reactants, such as (2E,6E)-3,7-Dimethyl-8-oxoocta-2,6-dien-1-yl acetate (cas: 37905-02-5Application In Synthesis of (2E,6E)-3,7-Dimethyl-8-oxoocta-2,6-dien-1-yl acetate).

(2E,6E)-3,7-Dimethyl-8-oxoocta-2,6-dien-1-yl acetate (cas: 37905-02-5) belongs to esters. Esters are widespread in nature and are widely used in industry. In nature, fats are in general triesters derived from glycerol and fatty acids. Esters are responsible for the aroma of many fruits, including apples, durians, pears, bananas, pineapples, and strawberries. Liquid esters of low volatility serve as softening agents for resins and plastics. Esters also include many industrially important polymers. Polymethyl methacrylate is a glass substitute sold under the names Lucite and Plexiglas; polyethylene terephthalate is used as a film (Mylar) and as textile fibres sold as Terylene, Fortrel, and Dacron.Application In Synthesis of (2E,6E)-3,7-Dimethyl-8-oxoocta-2,6-dien-1-yl acetate

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

Rhodium carbenoid mediated cyclizations. Part 4. Synthetic approaches to oxepanes related to zoapatanol was written by Davies, Martin J.;Heslin, Julie C.;Moody, Christopher J.. And the article was included in Journal of the Chemical Society in 1989.Quality Control of (2E,6E)-3,7-Dimethyl-8-oxoocta-2,6-dien-1-yl acetate The following contents are mentioned in the article:

Synthetic approaches to the oxepane diterpene zoapatanol (I) are described in which the key step is the formation of the 7-membered cyclic ether by a Rh carbenoid cyclization. The approaches to the functionalized side chain of I centered on allylic alcs., (E)RCMe:CHCH₂OH [R = CH₂CH₂CH₂CHMeCHO, CH₂CH₂CH:CMeCH₂OH-(E)], prepared from geraniol. After asym. epoxidation, these substrates were converted to diazo alcs. II. Finally, cyclization with Rh(OAc)₂ gave oxepanes III which were characterized as silyl enol ethers IV. This study involved multiple reactions and reactants, such as (2E,6E)-3,7-Dimethyl-8-oxoocta-2,6-dien-1-yl acetate (cas: 37905-02-5Quality Control of (2E,6E)-3,7-Dimethyl-8-oxoocta-2,6-dien-1-yl acetate).

(2E,6E)-3,7-Dimethyl-8-oxoocta-2,6-dien-1-yl acetate (cas: 37905-02-5) belongs to esters. Carboxylic acid esters of low molecular weight are colourless, volatile liquids with pleasant odours, slightly soluble in water. Many esters have the potential for conformational isomerism, but they tend to adopt an s-cis (or Z) conformation rather than the s-trans (or E) alternative, due to a combination of hyperconjugation and dipole minimization effects. The preference for the Z conformation is influenced by the nature of the substituents and solvent, if present. Lactones with small rings are restricted to the s-trans (i.e. E) conformation due to their cyclic structure.Quality Control of (2E,6E)-3,7-Dimethyl-8-oxoocta-2,6-dien-1-yl acetate

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics