Category: 37905-02-5

Didehydrogeranylgeranyl (ΔΔGG): A fluorescent probe for protein prenylation was written by Liu, Xiao-hui;Prestwich, Glenn D.. And the article was included in Journal of the American Chemical Society in 2002.Reference of 37905-02-5 The following contents are mentioned in the article:

The first intrinsically fluorescent analog of geranylgeraniol, (2E,6E,8E,10E,12E,14E)-geranylgeraniol (all-trans-ΔΔGGOH) has been synthesized stereoselectively and shown to substitute for the geranylgeranyl (GG) moiety in prenyltransferase reactions and in protein-ligand binding assays. All-trans-ΔΔGGOH showed blue fluorescence in methanol, with λ_ex = 310 nm and λ_em = 410 nm (ε₃₁₀ = 2.4 × 10⁴ M^-1 cm^-1), but was only weakly fluorescent in aqueous solution The prenyltransferase efficiency for the diphosphate analog ΔΔGGPP as a substrate for yeast protein geranylgeranyltransferase (PGGTase-I) was 60% relative to that for GGPP. The binding of ΔΔGG-AcCysMe to the recombinant Rho GTPase dissociation inhibitor (RhoGDI) had a K_D of 15.1 μM, 6-fold lower than the affinity of GG-AcCysMe. Thus, the ΔΔGG moiety is a novel fluorophore suitable for studying the interaction and subcellular localization of prenylated small GTPase proteins in signaling complexes. This study involved multiple reactions and reactants, such as (2E,6E)-3,7-Dimethyl-8-oxoocta-2,6-dien-1-yl acetate (cas: 37905-02-5Reference of 37905-02-5).

(2E,6E)-3,7-Dimethyl-8-oxoocta-2,6-dien-1-yl acetate (cas: 37905-02-5) belongs to esters. Volatile esters with characteristic odours are used in synthetic flavours, perfumes, and cosmetics. Certain volatile esters are used as solvents for lacquers, paints, and varnishes. Esterification is the general name for a chemical reaction in which two reactants (typically an alcohol and an acid) form an ester as the reaction product. Esters are common in organic chemistry and biological materials.Reference of 37905-02-5

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The aphid sex pheromone cyclopentanoids: synthesis in the elucidation of structure and biosynthetic pathways was written by Dawson, Glenn W.;Pickett, John a.;Smiley, Diane W. M.. And the article was included in Bioorganic & Medicinal Chemistry in 1996.Synthetic Route of C12H18O3 The following contents are mentioned in the article:

Identification of a range of aphid sex pheromones as comprising the cyclopentanoids (4aS,7S,7aR)-nepetalactone (I), (1R,4aS,7S,7aR)-nepetalactol (II) and the (1S)- and (1R,4aR,7S,7aS)-nepetalactols (III) required samples authenticated by ¹H and ¹³C NMR. These and related compounds were provided by small scale synthesis and extraction from plants in the genus Nepeta (Lamiaceae). The subsequent discovery that the synthetic sex pheromones could attract males, and also parasitic wasps that attack aphids, has created a need for large scale syntheses of the cyclopentanoids. This is afforded by cyclization of the 8-oxo-1-enamine of citronellal as originally developed by Schreiber and co-workers (1986). Investigation into the biosynthesis of the cyclopentanoids by plants for exploiting aphid sex pheromones in crop protection by means of mol. biol. required synthesis of putative biosynthetic intermediates, some with radioactive isotopic labeling, particularly 8-oxidized monoterpene alcs. and aldehydes. This study involved multiple reactions and reactants, such as (2E,6E)-3,7-Dimethyl-8-oxoocta-2,6-dien-1-yl acetate (cas: 37905-02-5Synthetic Route of C12H18O3).

(2E,6E)-3,7-Dimethyl-8-oxoocta-2,6-dien-1-yl acetate (cas: 37905-02-5) belongs to esters. Esters are widespread in nature and are widely used in industry. In nature, fats are in general triesters derived from glycerol and fatty acids. Esters are responsible for the aroma of many fruits. Esters contain a carbonyl center, which gives rise to 120° C–C–O and O–C–O angles. Unlike amides, esters are structurally flexible functional groups because rotation about the C–O–C bonds has a low barrier. Their flexibility and low polarity is manifested in their physical properties; they tend to be less rigid (lower melting point) and more volatile (lower boiling point) than the corresponding amides. Synthetic Route of C12H18O3

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Ester – Wikipedia,
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Oxidation of olefins with 2-pyridineseleninic anhydride was written by Barton, Derek H. R.;Crich, David. And the article was included in Tetrahedron in 1985.Recommanded Product: 37905-02-5 The following contents are mentioned in the article:

2-Pyridineseleninic anhydride (I) prepared in situ by oxidation of the corresponding diselenide with iodoxybenzene, is an efficient reagent for the conversion of olefins to unsaturated ketones with retention of the original position of the double bond. Thus, oxidation of β-pinene gave 95% (+)-pinocarvone. This reagent is much more reactive towards olefins than benzeneseleninic anhydride. This study involved multiple reactions and reactants, such as (2E,6E)-3,7-Dimethyl-8-oxoocta-2,6-dien-1-yl acetate (cas: 37905-02-5Recommanded Product: 37905-02-5).

(2E,6E)-3,7-Dimethyl-8-oxoocta-2,6-dien-1-yl acetate (cas: 37905-02-5) belongs to esters. Esters perform as high-grade solvents for a broad array of plastics, plasticizers, resins, and lacquers, and are one of the largest classes of synthetic lubricants on the commercial market. Polyesters are important plastics, with monomers linked by ester moieties. Because of their lack of hydrogen-bond-donating ability, esters do not self-associate. Consequently, esters are more volatile than carboxylic acids of similar molecular weight.Recommanded Product: 37905-02-5

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

Stereocontrolled synthesis and configurational assignment of (R)-all-trans-11,12-dihydro-3-hydroxyretinol was written by Rivas, Aurea;Alvarez, Rosana;de Lera, Angel R.. And the article was included in Tetrahedron Letters in 2019.Quality Control of (2E,6E)-3,7-Dimethyl-8-oxoocta-2,6-dien-1-yl acetate The following contents are mentioned in the article:

The synthesis of (R)-all-trans-11,12-dihydro-3-hydroxyretinol I and putative metabolites of the side-chain functional group has been achieved in a stereocontrolled manner via the Suzuki-Hiyama cross-coupling reaction of an enantiopure (hydroxycyclohexenyl)alkenyl iodide and non-conjugated pinacolboranedienoate, which allowed the absolute configuration of this natural product to be confirmed. This study involved multiple reactions and reactants, such as (2E,6E)-3,7-Dimethyl-8-oxoocta-2,6-dien-1-yl acetate (cas: 37905-02-5Quality Control of (2E,6E)-3,7-Dimethyl-8-oxoocta-2,6-dien-1-yl acetate).

(2E,6E)-3,7-Dimethyl-8-oxoocta-2,6-dien-1-yl acetate (cas: 37905-02-5) belongs to esters. Esters are also usually derived from carboxylic acids. It may also be obtained by reaction of acid anhydride or acid halides with alcohols or by the reaction of salts of carboxylic acids with alkyl halides. Liquid esters of low volatility serve as softening agents for resins and plastics. Esters also include many industrially important polymers. Polymethyl methacrylate is a glass substitute sold under the names Lucite and Plexiglas; polyethylene terephthalate is used as a film (Mylar) and as textile fibres sold as Terylene, Fortrel, and Dacron.Quality Control of (2E,6E)-3,7-Dimethyl-8-oxoocta-2,6-dien-1-yl acetate

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Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

Allylic oxidation of olefins by catalytic and stoichiometric selenium dioxide with tert-butyl hydroperoxide was written by Umbreit, M. A.;Sharpless, K. B.. And the article was included in Journal of the American Chemical Society in 1977.Synthetic Route of C12H18O3 The following contents are mentioned in the article:

Reactive olefins were oxidized to the allylic alcs. and carbonyl compounds by catalytic SeO2 in the presence of excess Me3COOH (I). Olefins normally unreactive toward SeO2 were readily oxidized at room temperature to the unrearranged allylic products in good yields by stoichiometric SeO2 and I. I suppresses generation of Se(0) and Se(II) species, which ordinarily complicate the reaction of SeO2 with olefins. This study involved multiple reactions and reactants, such as (2E,6E)-3,7-Dimethyl-8-oxoocta-2,6-dien-1-yl acetate (cas: 37905-02-5Synthetic Route of C12H18O3).

(2E,6E)-3,7-Dimethyl-8-oxoocta-2,6-dien-1-yl acetate (cas: 37905-02-5) belongs to esters. Carboxylic acid esters of low molecular weight are colourless, volatile liquids with pleasant odours, slightly soluble in water. Because of their lack of hydrogen-bond-donating ability, esters do not self-associate. Consequently, esters are more volatile than carboxylic acids of similar molecular weight.Synthetic Route of C12H18O3

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Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

Synthesis of 8-Hydroxygeraniol was written by Ippoliti, Francesca M.;Barber, Joyann S.;Tang, Yi;Garg, Neil K.. And the article was included in Journal of Organic Chemistry in 2018.Related Products of 37905-02-5 The following contents are mentioned in the article:

An operationally simple protocol for the conversion of geranyl acetate to 8-hydroxygeraniol is reported. The convenient two-step procedure relies on an efficient, chemo- and regioselective SeO₂-promoted oxidation, followed by straightforward deacetylation. This facile means to prepare 8-hydroxygeraniol is expected to enable biosynthetic studies pertaining to thousands of monoterpene indole alkaloids. This study involved multiple reactions and reactants, such as (2E,6E)-3,7-Dimethyl-8-oxoocta-2,6-dien-1-yl acetate (cas: 37905-02-5Related Products of 37905-02-5).

(2E,6E)-3,7-Dimethyl-8-oxoocta-2,6-dien-1-yl acetate (cas: 37905-02-5) belongs to esters. Esters are widespread in nature and are widely used in industry. In nature, fats are in general triesters derived from glycerol and fatty acids. Esters are responsible for the aroma of many fruits, including apples, durians, pears, bananas, pineapples, and strawberries. Because of their lack of hydrogen-bond-donating ability, esters do not self-associate. Consequently, esters are more volatile than carboxylic acids of similar molecular weight.Related Products of 37905-02-5

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

Bakers’ yeast hydrogenation of carbonyl activated double bonds. Enantioselective synthesis of the (S)-form of the dihydroterpenediol secreted by Danaus chrysippus and of a pheromone of Callosobruchus chinensis L was written by Gramatica, Paola;Giardina, Giuseppe;Speranza, Giovanna;Manitto, Paolo. And the article was included in Chemistry Letters in 1985.Synthetic Route of C12H18O3 The following contents are mentioned in the article:

The (S)-form of (E)-3,7-dimethyl-2-octene-1,8-diol (I) (secreted by male danaid butterflies) and of (E)-3,7-dimethyl-2-octene-1,8-dioic acid (II) (a pheromone of the azuki bean weevil) were synthesized via stereoselective hydrogenation by baker’s yeast of the carbonyl activated double bond of achiral precursors III and IV. This study involved multiple reactions and reactants, such as (2E,6E)-3,7-Dimethyl-8-oxoocta-2,6-dien-1-yl acetate (cas: 37905-02-5Synthetic Route of C12H18O3).

(2E,6E)-3,7-Dimethyl-8-oxoocta-2,6-dien-1-yl acetate (cas: 37905-02-5) belongs to esters. Esters perform as high-grade solvents for a broad array of plastics, plasticizers, resins, and lacquers, and are one of the largest classes of synthetic lubricants on the commercial market. Polyesters are important plastics, with monomers linked by ester moieties. Liquid esters of low volatility serve as softening agents for resins and plastics. Esters also include many industrially important polymers. Polymethyl methacrylate is a glass substitute sold under the names Lucite and Plexiglas; polyethylene terephthalate is used as a film (Mylar) and as textile fibres sold as Terylene, Fortrel, and Dacron.Synthetic Route of C12H18O3

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

Geraniol and nerol in organic synthesis. Useful intermediates for the synthesis of C17-juvenile hormone was written by Grieco, Paul A.. And the article was included in Journal of the Chemical Society, Chemical Communications in 1972.Application In Synthesis of (2E,6E)-3,7-Dimethyl-8-oxoocta-2,6-dien-1-yl acetate The following contents are mentioned in the article:

Ozonolysis of cis-AcOCH2CH:CMe(CH2)2CH:CMe2 (I) at -78° in CH2Cl2 followed by treatment with Me2S gave 60% AcOCH2CH:CMe(CH2)2CHO which with (PPh3)3RhCl in C6H6 or CH2Cl2 gave 70% cis-AcOCH2CH:CMPr (II). SeO2 oxidation of the trans isomer of I followed by NaBH4 reduction in 95% EtOH at 0° gave 40% trans-trans-AcOCH2CH:CMe(CH2)2CH:CMeCH2OH (III). II and III are intermediates for the synthesis of C17-juvenile hormone. This study involved multiple reactions and reactants, such as (2E,6E)-3,7-Dimethyl-8-oxoocta-2,6-dien-1-yl acetate (cas: 37905-02-5Application In Synthesis of (2E,6E)-3,7-Dimethyl-8-oxoocta-2,6-dien-1-yl acetate).

(2E,6E)-3,7-Dimethyl-8-oxoocta-2,6-dien-1-yl acetate (cas: 37905-02-5) belongs to esters. Esters typically have a pleasant smell; those of low molecular weight are commonly used as fragrances and are found in essential oils and pheromones. Cyclic esters are called lactones, regardless of whether they are derived from an organic or inorganic acid. One example of an organic lactone is γ-valerolactone.Application In Synthesis of (2E,6E)-3,7-Dimethyl-8-oxoocta-2,6-dien-1-yl acetate

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

Integrated chemical process: an extremely concise synthesis of vitamin A was written by Orita, Akihiro;Yamashita, Yasuo;Toh, Akiji;Otera, Junzo. And the article was included in Angewandte Chemie, International Edition in English in 1997.Formula: C12H18O3 The following contents are mentioned in the article:

A one-pot procedure conducted stepwise under basic conditions gave an improved yield via an integrated chem. process. Lithium salt of a cyclogeranylsulfone treated with a dimethyloctadienal gave the addition product I which was converted to the MOM ether, underwent double elimination when exposed to MeOK to yield vitamin A. Addition of cyclohexane as a cosolvent in the elimination step increased the yield slightly. This study involved multiple reactions and reactants, such as (2E,6E)-3,7-Dimethyl-8-oxoocta-2,6-dien-1-yl acetate (cas: 37905-02-5Formula: C12H18O3).

(2E,6E)-3,7-Dimethyl-8-oxoocta-2,6-dien-1-yl acetate (cas: 37905-02-5) belongs to esters. Esters perform as high-grade solvents for a broad array of plastics, plasticizers, resins, and lacquers, and are one of the largest classes of synthetic lubricants on the commercial market. Polyesters are important plastics, with monomers linked by ester moieties. Esters contain a carbonyl center, which gives rise to 120° C–C–O and O–C–O angles. Unlike amides, esters are structurally flexible functional groups because rotation about the C–O–C bonds has a low barrier. Their flexibility and low polarity is manifested in their physical properties; they tend to be less rigid (lower melting point) and more volatile (lower boiling point) than the corresponding amides. Formula: C12H18O3

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

Preparation of aromatic geraniol analogues via a Cu(I)-mediated grignard coupling was written by Paz, J. Luis;Rodrigues, J. Augusto R.. And the article was included in Journal of the Brazilian Chemical Society in 2003.Name: (2E,6E)-3,7-Dimethyl-8-oxoocta-2,6-dien-1-yl acetate The following contents are mentioned in the article:

Difunctional allylic terpenes are important synthetic building blocks. Functionalization of protected geranyl derivatives by SeO₂/t-BuO₂H adsorbed on SiO₂ provides a convenient route to such compounds The chosen protecting groups clearly influence the oxidation process. Also, an efficient synthesis of 2-geranylphenol derivatives via a Cu(I)-mediated Grignard coupling of 2-lithiophenols and geranyl substrates was developed. This study involved multiple reactions and reactants, such as (2E,6E)-3,7-Dimethyl-8-oxoocta-2,6-dien-1-yl acetate (cas: 37905-02-5Name: (2E,6E)-3,7-Dimethyl-8-oxoocta-2,6-dien-1-yl acetate).

(2E,6E)-3,7-Dimethyl-8-oxoocta-2,6-dien-1-yl acetate (cas: 37905-02-5) belongs to esters. Esters are widespread in nature and are widely used in industry. In nature, fats are in general triesters derived from glycerol and fatty acids. Esters are responsible for the aroma of many fruits. Esterification is the general name for a chemical reaction in which two reactants (typically an alcohol and an acid) form an ester as the reaction product. Esters are common in organic chemistry and biological materials.Name: (2E,6E)-3,7-Dimethyl-8-oxoocta-2,6-dien-1-yl acetate

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics