Category: 37905-02-5

Confirmation of the Connectivity of 4,8,12,16,20-Pentamethylpentacosylphoshoryl β-D-Mannopyranoside, an Unusual β-Mannosyl Phosphoisoprenoid from Mycobacterium avium, through Synthesis was written by Crich, David;Dudkin, Vadim. And the article was included in Journal of the American Chemical Society in 2002.Category: esters-buliding-blocks The following contents are mentioned in the article:

The synthesis of the title glycolipid is reported. Comparison of the electrospray and high-energy collision-induced dissociation mass spectra of the synthetic material with those reported for the isolate confirm the structure of this unusual antigenic substance with its modified isoprenoid chain. This study involved multiple reactions and reactants, such as (2E,6E)-3,7-Dimethyl-8-oxoocta-2,6-dien-1-yl acetate (cas: 37905-02-5Category: esters-buliding-blocks).

(2E,6E)-3,7-Dimethyl-8-oxoocta-2,6-dien-1-yl acetate (cas: 37905-02-5) belongs to esters. Esters perform as high-grade solvents for a broad array of plastics, plasticizers, resins, and lacquers, and are one of the largest classes of synthetic lubricants on the commercial market. Cyclic esters are called lactones, regardless of whether they are derived from an organic or inorganic acid. One example of an organic lactone is γ-valerolactone.Category: esters-buliding-blocks

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

The highly stereoselective synthesis of all-trans and 13-cis vitamin A via double elimination reaction was written by Otera, Junzo;Misawa, Hiromitsu;Mandai, Tadakatsu;Onishi, Takashi;Suzuki, Shigeaki;Fujita, Yoshiji. And the article was included in Chemistry Letters in 1985.Related Products of 37905-02-5 The following contents are mentioned in the article:

Stereocontrolled convergent synthesis of stereoisomeric retinols I was achieved by the double elimination method employing sulfone II and stereoisomeric aldehydes III as starting materials. Thus, the all-trans and 13-cis isomers were obtained with stereochem. purity of 95 and 90%, resp. This study involved multiple reactions and reactants, such as (2E,6E)-3,7-Dimethyl-8-oxoocta-2,6-dien-1-yl acetate (cas: 37905-02-5Related Products of 37905-02-5).

(2E,6E)-3,7-Dimethyl-8-oxoocta-2,6-dien-1-yl acetate (cas: 37905-02-5) belongs to esters. Esters perform as high-grade solvents for a broad array of plastics, plasticizers, resins, and lacquers, and are one of the largest classes of synthetic lubricants on the commercial market. Polyesters are important plastics, with monomers linked by ester moieties. Esters are more polar than ethers but less polar than alcohols. They participate in hydrogen bonds as hydrogen-bond acceptors, but cannot act as hydrogen-bond donors, unlike their parent alcohols. This ability to participate in hydrogen bonding confers some water-solubility.Related Products of 37905-02-5

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

Preparation, NMR Characterization, and Labeling Reactions of Tritiated Triacetoxy Sodium Borohydride was written by Than, Chit;Morimoto, Hiromi;Williams, Philip G.;Chehade, Kareem A. H.;Andres, Douglas A.;Spielmann, H. Peter. And the article was included in Journal of Organic Chemistry in 2001.Reference of 37905-02-5 The following contents are mentioned in the article:

Deuterium or tritium labeled NaBH(OAc)₃ was prepared from NaBH₄ by thermal exchange with deuterium or tritium gas followed by treatment with acetic acid. Once the deuterium- or tritium-labeled NaBH(OAc)₃ reagent was prepared, it was used to reduce a simple aldehyde to demonstrate the utility of the reagent. This study involved multiple reactions and reactants, such as (2E,6E)-3,7-Dimethyl-8-oxoocta-2,6-dien-1-yl acetate (cas: 37905-02-5Reference of 37905-02-5).

(2E,6E)-3,7-Dimethyl-8-oxoocta-2,6-dien-1-yl acetate (cas: 37905-02-5) belongs to esters. Esters are widespread in nature and are widely used in industry. In nature, fats are in general triesters derived from glycerol and fatty acids. Esters are responsible for the aroma of many fruits. Esters contain a carbonyl center, which gives rise to 120° C–C–O and O–C–O angles. Unlike amides, esters are structurally flexible functional groups because rotation about the C–O–C bonds has a low barrier. Their flexibility and low polarity is manifested in their physical properties; they tend to be less rigid (lower melting point) and more volatile (lower boiling point) than the corresponding amides. Reference of 37905-02-5

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

A short and efficient total synthesis of (±)-ascofuranone was written by Haga, Yasushi;Tonoi, Takayuki;Anbiru, Yoshihide;Takahashi, Yuki;Tamura, Sayuri;Yamamoto, Masaichi;Ifuku, Shinsuke;Morimoto, Minoru;Saimoto, Hiroyuki. And the article was included in Chemistry Letters in 2010.Quality Control of (2E,6E)-3,7-Dimethyl-8-oxoocta-2,6-dien-1-yl acetate The following contents are mentioned in the article:

Ascofuranone is a potent inhibitor of trypanosome alternative oxidase. A short and efficient total synthesis of (±)-ascofuranone (I) was accomplished in only seven steps starting with geranyl acetate. The synthetic concept and methodol. described in detail here provide a short and simple synthesis for ascofuranone and its derivatives This study involved multiple reactions and reactants, such as (2E,6E)-3,7-Dimethyl-8-oxoocta-2,6-dien-1-yl acetate (cas: 37905-02-5Quality Control of (2E,6E)-3,7-Dimethyl-8-oxoocta-2,6-dien-1-yl acetate).

(2E,6E)-3,7-Dimethyl-8-oxoocta-2,6-dien-1-yl acetate (cas: 37905-02-5) belongs to esters. Esters are widespread in nature and are widely used in industry. In nature, fats are in general triesters derived from glycerol and fatty acids. Esters are responsible for the aroma of many fruits, including apples, durians, pears, bananas, pineapples, and strawberries. Esters contain a carbonyl center, which gives rise to 120° C–C–O and O–C–O angles. Unlike amides, esters are structurally flexible functional groups because rotation about the C–O–C bonds has a low barrier. Their flexibility and low polarity is manifested in their physical properties; they tend to be less rigid (lower melting point) and more volatile (lower boiling point) than the corresponding amides. Quality Control of (2E,6E)-3,7-Dimethyl-8-oxoocta-2,6-dien-1-yl acetate

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

Biomimetic total synthesis of Rubiginosin meroterpenoids was written by Burchill, Laura;Day, Aaron J.;Yahiaoui, Oussama;George, Jonathan H.. And the article was included in Organic Letters in 2021.Safety of (2E,6E)-3,7-Dimethyl-8-oxoocta-2,6-dien-1-yl acetate The following contents are mentioned in the article:

Total synthesis of the Rhododendron meroterpenoids Rubiginosins A and G, which both contain unusual 6-6-6-4 ring systems, has been achieved using a bioinspired cascade approach. Stepwise synthesis of these natural products, and the related 6-6-5-4 meroterpenoids Fastinoid B and Rhodonoid B, from naturally occurring chromene precursors is also reported. This study involved multiple reactions and reactants, such as (2E,6E)-3,7-Dimethyl-8-oxoocta-2,6-dien-1-yl acetate (cas: 37905-02-5Safety of (2E,6E)-3,7-Dimethyl-8-oxoocta-2,6-dien-1-yl acetate).

(2E,6E)-3,7-Dimethyl-8-oxoocta-2,6-dien-1-yl acetate (cas: 37905-02-5) belongs to esters. Esters typically have a pleasant smell; those of low molecular weight are commonly used as fragrances and are found in essential oils and pheromones. Many esters have the potential for conformational isomerism, but they tend to adopt an s-cis (or Z) conformation rather than the s-trans (or E) alternative, due to a combination of hyperconjugation and dipole minimization effects. The preference for the Z conformation is influenced by the nature of the substituents and solvent, if present. Lactones with small rings are restricted to the s-trans (i.e. E) conformation due to their cyclic structure.Safety of (2E,6E)-3,7-Dimethyl-8-oxoocta-2,6-dien-1-yl acetate

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

Exploiting the Synthetic Potential of Sesquiterpene Cyclases for Generating Unnatural Terpenoids was written by Oberhauser, Clara;Harms, Vanessa;Seidel, Katja;Schroeder, Benjamin;Ekramzadeh, Kimia;Beutel, Sascha;Winkler, Sven;Lauterbach, Lukas;Dickschat, Jeroen S.;Kirschning, Andreas. And the article was included in Angewandte Chemie, International Edition in 2018.SDS of cas: 37905-02-5 The following contents are mentioned in the article:

The substrate flexibility of eight purified sesquiterpene cyclases (STCs) was evaluated using six new heteroatom-modified farnesyl pyrophosphates, and the formation of six new heteroatom-modified macrocyclic and tricyclic sesquiterpenoids is described. Gas chromatog.-olfactory (GC-O) anal. revealed that tricyclic THF exhibits an ethereal, peppery, and camphor-like olfactoric scent. This study involved multiple reactions and reactants, such as (2E,6E)-3,7-Dimethyl-8-oxoocta-2,6-dien-1-yl acetate (cas: 37905-02-5SDS of cas: 37905-02-5).

(2E,6E)-3,7-Dimethyl-8-oxoocta-2,6-dien-1-yl acetate (cas: 37905-02-5) belongs to esters. Esters are also usually derived from carboxylic acids. It may also be obtained by reaction of acid anhydride or acid halides with alcohols or by the reaction of salts of carboxylic acids with alkyl halides. Esterification is the general name for a chemical reaction in which two reactants (typically an alcohol and an acid) form an ester as the reaction product. Esters are common in organic chemistry and biological materials.SDS of cas: 37905-02-5

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

Catalytic allylic oxidation with a recyclable, fluorous seleninic acid was written by Crich, David;Zou, Yekui. And the article was included in Organic Letters in 2004.Formula: C12H18O3 The following contents are mentioned in the article:

In conjunction with iodoxybenzene as reoxidant, perfluorooctylseleninic acid (I) catalyzed the allylic oxidation of alkenes to enones, in moderate to good yield. After a reductive workup with sodium metabisulfite, the catalyst was recovered by fluorous extraction in the form of bis(perfluorooctyl) diselenide, which, itself, serves as a convenient catalyst precursor. This study involved multiple reactions and reactants, such as (2E,6E)-3,7-Dimethyl-8-oxoocta-2,6-dien-1-yl acetate (cas: 37905-02-5Formula: C12H18O3).

(2E,6E)-3,7-Dimethyl-8-oxoocta-2,6-dien-1-yl acetate (cas: 37905-02-5) belongs to esters. Volatile esters with characteristic odours are used in synthetic flavours, perfumes, and cosmetics. Certain volatile esters are used as solvents for lacquers, paints, and varnishes. Liquid esters of low volatility serve as softening agents for resins and plastics. Esters also include many industrially important polymers. Polymethyl methacrylate is a glass substitute sold under the names Lucite and Plexiglas; polyethylene terephthalate is used as a film (Mylar) and as textile fibres sold as Terylene, Fortrel, and Dacron.Formula: C12H18O3

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

Ubiquinone and related compounds. XXXVIII. Biological oxidation of ubiquinone was written by Morimoto, Hiroshi;Kurimoto, Kuniko;Imada, Isuke. And the article was included in Chemical & Pharmaceutical Bulletin in 1985.COA of Formula: C12H18O3 The following contents are mentioned in the article:

Ubiquinone-2 (I) was oxidized to 6-[7-carboxy-3-methyl-(2E,6E)-2,6-octadienyl]-2,3-dimethoxy-5-methyl-1,4-benzoquinone and 6-[6,7-dihydroxy-3,7-dimethyl-(E)-2-octenyl]-2,3-dimethoxy-5-methyl-1,4-benzoquinone by the 6000-g supernatant of guinea pig liver homogenate in the presence of NAD and NADPH-generating systems. This study involved multiple reactions and reactants, such as (2E,6E)-3,7-Dimethyl-8-oxoocta-2,6-dien-1-yl acetate (cas: 37905-02-5COA of Formula: C12H18O3).

(2E,6E)-3,7-Dimethyl-8-oxoocta-2,6-dien-1-yl acetate (cas: 37905-02-5) belongs to esters. Esters typically have a pleasant smell; those of low molecular weight are commonly used as fragrances and are found in essential oils and pheromones. Esters are more polar than ethers but less polar than alcohols. They participate in hydrogen bonds as hydrogen-bond acceptors, but cannot act as hydrogen-bond donors, unlike their parent alcohols. This ability to participate in hydrogen bonding confers some water-solubility.COA of Formula: C12H18O3

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

Preparation of (2E,6E)-10,11-dihydrofarnesol via a (bisphenyl)dithioacetal reduction was written by Mechelke, Mark F.;Wiemer, David F.. And the article was included in Tetrahedron Letters in 1998.Recommanded Product: (2E,6E)-3,7-Dimethyl-8-oxoocta-2,6-dien-1-yl acetate The following contents are mentioned in the article:

Reduction of (bisphenyl)dithioacetal, (E,E)- Me₂CHCH₂C(SPh)₂CH₂CMe:CH(CH₂)₂CMe:CHCH₂OH, with sodium/isopropyl alc. in THF allows preparation of (2E,6E)-10,11-dihydrofarnesol, Me₂CH(CH₂)₃CMe:CH(CH₂)₂CMe:CHCH₂OH, in high yield. This study involved multiple reactions and reactants, such as (2E,6E)-3,7-Dimethyl-8-oxoocta-2,6-dien-1-yl acetate (cas: 37905-02-5Recommanded Product: (2E,6E)-3,7-Dimethyl-8-oxoocta-2,6-dien-1-yl acetate).

(2E,6E)-3,7-Dimethyl-8-oxoocta-2,6-dien-1-yl acetate (cas: 37905-02-5) belongs to esters. Esters are widespread in nature and are widely used in industry. In nature, fats are in general triesters derived from glycerol and fatty acids. Esters are responsible for the aroma of many fruits, including apples, durians, pears, bananas, pineapples, and strawberries. Many esters have the potential for conformational isomerism, but they tend to adopt an s-cis (or Z) conformation rather than the s-trans (or E) alternative, due to a combination of hyperconjugation and dipole minimization effects. The preference for the Z conformation is influenced by the nature of the substituents and solvent, if present. Lactones with small rings are restricted to the s-trans (i.e. E) conformation due to their cyclic structure.Recommanded Product: (2E,6E)-3,7-Dimethyl-8-oxoocta-2,6-dien-1-yl acetate

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

Intramolecular Formal oxa-[3 + 3] Cycloaddition Approach to the ABD System of Phomactin A was written by Cole, Kevin P.;Hsung, Richard P.. And the article was included in Organic Letters in 2003.Related Products of 37905-02-5 The following contents are mentioned in the article:

The ABD-ring I of phomactin A was synthesized using an intramol. formal oxa-[3 + 3] cycloaddition of an α,β-unsaturated iminium salt tethered to a 1,3-diketone. This represents the first time that the 12-membered ring has been formed simultaneously with the 1-oxadecalin and should afford a facile route to the challenging structure of phomactin A. This study involved multiple reactions and reactants, such as (2E,6E)-3,7-Dimethyl-8-oxoocta-2,6-dien-1-yl acetate (cas: 37905-02-5Related Products of 37905-02-5).

(2E,6E)-3,7-Dimethyl-8-oxoocta-2,6-dien-1-yl acetate (cas: 37905-02-5) belongs to esters. Esters typically have a pleasant smell; those of low molecular weight are commonly used as fragrances and are found in essential oils and pheromones. Esterification is the general name for a chemical reaction in which two reactants (typically an alcohol and an acid) form an ester as the reaction product. Esters are common in organic chemistry and biological materials.Related Products of 37905-02-5

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics