Category: 37905-02-5

Synthetic microbial chemistry. X. Synthesis of the natural enantiomers of ascochlorin, ascofuranone and ascofuranol was written by Mori, Kenji;Takechi, Shozo. And the article was included in Tetrahedron in 1985.HPLC of Formula: 37905-02-5 The following contents are mentioned in the article:

The title compounds I–III were prepared together with (+)-ascofurarone and (+)-ascofuranol. The absolute configuration of (-)-ascofuranol (III) was confirmed to be 1”S,4”S. This study involved multiple reactions and reactants, such as (2E,6E)-3,7-Dimethyl-8-oxoocta-2,6-dien-1-yl acetate (cas: 37905-02-5HPLC of Formula: 37905-02-5).

(2E,6E)-3,7-Dimethyl-8-oxoocta-2,6-dien-1-yl acetate (cas: 37905-02-5) belongs to esters. Volatile esters with characteristic odours are used in synthetic flavours, perfumes, and cosmetics. Certain volatile esters are used as solvents for lacquers, paints, and varnishes. Esters are more polar than ethers but less polar than alcohols. They participate in hydrogen bonds as hydrogen-bond acceptors, but cannot act as hydrogen-bond donors, unlike their parent alcohols. This ability to participate in hydrogen bonding confers some water-solubility.HPLC of Formula: 37905-02-5

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Enantiospecific synthesis of the 14-membered diene unit of methyl sarcophytoate was written by Yasuda, Minoru;Ide, Mitsuaki;Matsumoto, Yuka;Nakata, Masaya. And the article was included in Synlett in 1997.Application In Synthesis of (2E,6E)-3,7-Dimethyl-8-oxoocta-2,6-dien-1-yl acetate The following contents are mentioned in the article:

The enantiospecific synthesis of the 14-membered diene unit I of sarcophytoate was achieved starting from geraniol by Sharpless asym. epoxidation, aldol reaction, oxy-Michael addition, and a modified Ito-Kodama cyclization as key steps. This study involved multiple reactions and reactants, such as (2E,6E)-3,7-Dimethyl-8-oxoocta-2,6-dien-1-yl acetate (cas: 37905-02-5Application In Synthesis of (2E,6E)-3,7-Dimethyl-8-oxoocta-2,6-dien-1-yl acetate).

(2E,6E)-3,7-Dimethyl-8-oxoocta-2,6-dien-1-yl acetate (cas: 37905-02-5) belongs to esters. Esters perform as high-grade solvents for a broad array of plastics, plasticizers, resins, and lacquers, and are one of the largest classes of synthetic lubricants on the commercial market. Cyclic esters are called lactones, regardless of whether they are derived from an organic or inorganic acid. One example of an organic lactone is γ-valerolactone.Application In Synthesis of (2E,6E)-3,7-Dimethyl-8-oxoocta-2,6-dien-1-yl acetate

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A [3+2] nitrile oxide intermolecular cycloaddition approach to 4,5-dihydro-3(2H)-furanone and 3(2H)-furanone ring systems: application to the formal synthesis of (±)-ascofuranone and geiparvarin was written by Tabrizi, M. Aghazade;Baraldi, P. G.;Guarneri, M.;Manfredini, S.;Pollini, G. P.;Simoni, D.. And the article was included in Tetrahedron Letters in 1991.Category: esters-buliding-blocks The following contents are mentioned in the article:

A unified approach to both 4,5-dihydro-3(2H)-furanone and 3(2H)-furanone ring systems centered on a [3+2] nitrile oxide cycloaddition for the C-C bond forming steps has been successfully applied to the synthesis of (±)-ascofuranone and geiparvarin from common intermediates. This study involved multiple reactions and reactants, such as (2E,6E)-3,7-Dimethyl-8-oxoocta-2,6-dien-1-yl acetate (cas: 37905-02-5Category: esters-buliding-blocks).

(2E,6E)-3,7-Dimethyl-8-oxoocta-2,6-dien-1-yl acetate (cas: 37905-02-5) belongs to esters. Esters typically have a pleasant smell; those of low molecular weight are commonly used as fragrances and are found in essential oils and pheromones. Cyclic esters are called lactones, regardless of whether they are derived from an organic or inorganic acid. One example of an organic lactone is γ-valerolactone.Category: esters-buliding-blocks

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Ester – Wikipedia,
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Highly regioselective and chemoselective titanocene mediated Barbier-type allylation reactions was written by Morcillo, Sara P.;Martinez-Peragon, Angela;Jakoby, Verena;Mota, Antonio J.;Kube, Christian;Justicia, Jose;Cuerva, Juan M.;Gansaeuer, Andreas. And the article was included in Chemical Communications (Cambridge, United Kingdom) in 2014.Recommanded Product: 37905-02-5 The following contents are mentioned in the article:

Titanocene carboxylate is an excellent chemoselective reagent for unprecedented α-regioselective Barbier-type reactions. It constitutes the first titanocene(III) able to tolerate epoxides and readily reduced carbonyl compounds, such as aromatic and α,β-unsaturated aldehydes. This study involved multiple reactions and reactants, such as (2E,6E)-3,7-Dimethyl-8-oxoocta-2,6-dien-1-yl acetate (cas: 37905-02-5Recommanded Product: 37905-02-5).

(2E,6E)-3,7-Dimethyl-8-oxoocta-2,6-dien-1-yl acetate (cas: 37905-02-5) belongs to esters. Volatile esters with characteristic odours are used in synthetic flavours, perfumes, and cosmetics. Certain volatile esters are used as solvents for lacquers, paints, and varnishes. Liquid esters of low volatility serve as softening agents for resins and plastics. Esters also include many industrially important polymers. Polymethyl methacrylate is a glass substitute sold under the names Lucite and Plexiglas; polyethylene terephthalate is used as a film (Mylar) and as textile fibres sold as Terylene, Fortrel, and Dacron.Recommanded Product: 37905-02-5

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Chemical defense mechanisms of arthropods. XXXVI. Stereospecific synthesis of gyrinidal, a norsesquiterpenoid aldehyde from gyrinid beetle was written by Meinwald, J.;Opheim, K.;Eisner, T.. And the article was included in Tetrahedron Letters in 1973.Formula: C12H18O3 The following contents are mentioned in the article:

(E,E)-AcOCH2CH:CMe(CH2)2CH:CMeCHO, prepared by SeO2 oxidation of geranyl acetate, was coupled with the di-Li salt of MeCH(OH)C:CH to give an acetylenic triol, which when treated with Na-NH3(1)-THF followed by oxidation (MnO2) gave (E,E,E)-MeCOCH:CH-COCMe:CH(CH2)2CMe:CHCHO (gyrinidal). This study involved multiple reactions and reactants, such as (2E,6E)-3,7-Dimethyl-8-oxoocta-2,6-dien-1-yl acetate (cas: 37905-02-5Formula: C12H18O3).

(2E,6E)-3,7-Dimethyl-8-oxoocta-2,6-dien-1-yl acetate (cas: 37905-02-5) belongs to esters. Esters are also usually derived from carboxylic acids. It may also be obtained by reaction of acid anhydride or acid halides with alcohols or by the reaction of salts of carboxylic acids with alkyl halides. Because of their lack of hydrogen-bond-donating ability, esters do not self-associate. Consequently, esters are more volatile than carboxylic acids of similar molecular weight.Formula: C12H18O3

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Synthesis of compounds with juvenile hormone activity. XVII. Stereoselective synthesis of dl-C17-Cecropia juvenile hormone was written by Mori, K.;Ohki, M.;Matsui, M.. And the article was included in Tetrahedron in 1974.Formula: C12H18O3 The following contents are mentioned in the article:

Me 12-homofarnesoate, whose conversion to the title hormone is documented, was prepared from EtCMe:CHCH2SPh by successive coupling with 8-tetrahydro-pyranyloxy-2,6-dimethylocta-2,6-trans,trans-dienyl bromide, removal of the tetrahydropyranyl and PhS groups, and oxidative esterification. This study involved multiple reactions and reactants, such as (2E,6E)-3,7-Dimethyl-8-oxoocta-2,6-dien-1-yl acetate (cas: 37905-02-5Formula: C12H18O3).

(2E,6E)-3,7-Dimethyl-8-oxoocta-2,6-dien-1-yl acetate (cas: 37905-02-5) belongs to esters. Esters perform as high-grade solvents for a broad array of plastics, plasticizers, resins, and lacquers, and are one of the largest classes of synthetic lubricants on the commercial market. Acyl chlorides and acid anhydrides alcoholysis is another way to produce esters. Acyl chlorides and acid anhydrides react with alcohols to produce esters. Anydrous conditions are recommended since both acyl chlorides and acid anhydrides react with water.Formula: C12H18O3

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Ester – Wikipedia,
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A formal total synthesis of taxol aided by an automated synthesizer was written by Doi, Takayuki;Fuse, Shinichiro;Miyamoto, Shigeru;Nakai, Kazuoki;Sasuga, Daisuke;Takahashi, Takashi. And the article was included in Chemistry – An Asian Journal in 2006.Safety of (2E,6E)-3,7-Dimethyl-8-oxoocta-2,6-dien-1-yl acetate The following contents are mentioned in the article:

A 36-step synthesis was carried out in automated synthesizers to provide a synthetic key intermediate of taxol. A key step involved a microwave-assisted alkylation reaction to construct the ABC ring system from an AC precursor. Subsequent formation of the D ring afforded (±)-baccatin III, a well-known precursor of taxol. This study involved multiple reactions and reactants, such as (2E,6E)-3,7-Dimethyl-8-oxoocta-2,6-dien-1-yl acetate (cas: 37905-02-5Safety of (2E,6E)-3,7-Dimethyl-8-oxoocta-2,6-dien-1-yl acetate).

(2E,6E)-3,7-Dimethyl-8-oxoocta-2,6-dien-1-yl acetate (cas: 37905-02-5) belongs to esters. Esters perform as high-grade solvents for a broad array of plastics, plasticizers, resins, and lacquers, and are one of the largest classes of synthetic lubricants on the commercial market. Polyesters are important plastics, with monomers linked by ester moieties. Esters contain a carbonyl center, which gives rise to 120° C–C–O and O–C–O angles. Unlike amides, esters are structurally flexible functional groups because rotation about the C–O–C bonds has a low barrier. Their flexibility and low polarity is manifested in their physical properties; they tend to be less rigid (lower melting point) and more volatile (lower boiling point) than the corresponding amides. Safety of (2E,6E)-3,7-Dimethyl-8-oxoocta-2,6-dien-1-yl acetate

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

Practical synthesis of 1,5-dimethyl substituted conjugated polyenes from geranyl acetate was written by Zhao, Yu-Jun;Loh, Teck-Peng. And the article was included in Tetrahedron in 2008.Application of 37905-02-5 The following contents are mentioned in the article:

A protocol to synthesize 1,5-di-Me substituted conjugated polyenes via dehydrogenation of geranyl acetate was established. C₅ unit elongation to multi-1,5-dimethyl substituted conjugated polyenes, e.g. I, was also achieved via Horner-Wadsworth-Emmons olefination in good yields and good selectivities. This study involved multiple reactions and reactants, such as (2E,6E)-3,7-Dimethyl-8-oxoocta-2,6-dien-1-yl acetate (cas: 37905-02-5Application of 37905-02-5).

(2E,6E)-3,7-Dimethyl-8-oxoocta-2,6-dien-1-yl acetate (cas: 37905-02-5) belongs to esters. Esters typically have a pleasant smell; those of low molecular weight are commonly used as fragrances and are found in essential oils and pheromones. Because of their lack of hydrogen-bond-donating ability, esters do not self-associate. Consequently, esters are more volatile than carboxylic acids of similar molecular weight.Application of 37905-02-5

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

Selenium dioxide E-methyl oxidation of suitably protected geranyl derivatives-synthesis of farnesyl mimics was written by Fairlamb, I. J. S.;Dickinson, J. M.;Pegg, M.. And the article was included in Tetrahedron Letters in 2001.HPLC of Formula: 37905-02-5 The following contents are mentioned in the article:

Difunctional allylic terpenes are important synthetic building blocks. Functionalization of protected geranyl derivatives by SeO₂ provides a convenient route to such compounds The effect of the geranyl protecting group on the oxidation of the terminal (E)-Me group was systematically investigated. This study involved multiple reactions and reactants, such as (2E,6E)-3,7-Dimethyl-8-oxoocta-2,6-dien-1-yl acetate (cas: 37905-02-5HPLC of Formula: 37905-02-5).

(2E,6E)-3,7-Dimethyl-8-oxoocta-2,6-dien-1-yl acetate (cas: 37905-02-5) belongs to esters. Volatile esters with characteristic odours are used in synthetic flavours, perfumes, and cosmetics. Certain volatile esters are used as solvents for lacquers, paints, and varnishes. Many esters have the potential for conformational isomerism, but they tend to adopt an s-cis (or Z) conformation rather than the s-trans (or E) alternative, due to a combination of hyperconjugation and dipole minimization effects. The preference for the Z conformation is influenced by the nature of the substituents and solvent, if present. Lactones with small rings are restricted to the s-trans (i.e. E) conformation due to their cyclic structure.HPLC of Formula: 37905-02-5

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Ester – Wikipedia,
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L-Proline catalyzed asymmetric aldol reactions of protected hydroxyacetone was written by Liu, Huawei;Peng, Lizeng;Zhang, Tao;Li, Yulin. And the article was included in New Journal of Chemistry in 2003.Name: (2E,6E)-3,7-Dimethyl-8-oxoocta-2,6-dien-1-yl acetate The following contents are mentioned in the article:

The proline-catalyzed asym. direct aldol reaction was extended to TBDMS protected hydroxyacetone. This important donor provides a ready access to optically active monoprotected 1,2-diol units simultaneously accompanied by stereoselective carbon-carbon bond formation in 40-90% yield and in up to 95% ee. This study involved multiple reactions and reactants, such as (2E,6E)-3,7-Dimethyl-8-oxoocta-2,6-dien-1-yl acetate (cas: 37905-02-5Name: (2E,6E)-3,7-Dimethyl-8-oxoocta-2,6-dien-1-yl acetate).

(2E,6E)-3,7-Dimethyl-8-oxoocta-2,6-dien-1-yl acetate (cas: 37905-02-5) belongs to esters. Esters perform as high-grade solvents for a broad array of plastics, plasticizers, resins, and lacquers, and are one of the largest classes of synthetic lubricants on the commercial market. Polyesters are important plastics, with monomers linked by ester moieties. Esterification is the general name for a chemical reaction in which two reactants (typically an alcohol and an acid) form an ester as the reaction product. Esters are common in organic chemistry and biological materials.Name: (2E,6E)-3,7-Dimethyl-8-oxoocta-2,6-dien-1-yl acetate

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics