Reaction of terminal epoxides of α-geranyl and α-farnesyl acetates with fluorosulfonic acid was written by Ungur, N. D.;Popa, N. P.;Kul’chitskii, V. N.;Vlad, P. F.. And the article was included in Khimiya Prirodnykh Soedinenii in 1993.HPLC of Formula: 37905-02-5 The following contents are mentioned in the article:
The title reactions gave ring-cleavage products I and II. This study involved multiple reactions and reactants, such as (2E,6E)-3,7-Dimethyl-8-oxoocta-2,6-dien-1-yl acetate (cas: 37905-02-5HPLC of Formula: 37905-02-5).
(2E,6E)-3,7-Dimethyl-8-oxoocta-2,6-dien-1-yl acetate (cas: 37905-02-5) belongs to esters. Esters are widespread in nature and are widely used in industry. In nature, fats are in general triesters derived from glycerol and fatty acids. Esters are responsible for the aroma of many fruits, including apples, durians, pears, bananas, pineapples, and strawberries. Many esters have the potential for conformational isomerism, but they tend to adopt an s-cis (or Z) conformation rather than the s-trans (or E) alternative, due to a combination of hyperconjugation and dipole minimization effects. The preference for the Z conformation is influenced by the nature of the substituents and solvent, if present. Lactones with small rings are restricted to the s-trans (i.e. E) conformation due to their cyclic structure.HPLC of Formula: 37905-02-5
Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics