Category: 3063-94-3

Preparation and application of 1,1,1,3,3,3-hexafluoroisopropyl methacrylate was written by Zhao, Weijuan;Xu, Weiguo;Liu, Yulin;Zhang, Yongyao;Han, Guoqing. And the article was included in Youjifu Gongye in 2013.Quality Control of 1,1,1,3,3,3-Hexafluoroisopropylmethacrylate The following contents are mentioned in the article:

A review. Preparation of 1,1,1,3,3,3-hexafluoroisopropyl methacrylate was reviewed. Application of 1,1,1,3,3,3-hexafluoroisopropyl methacrylate was summarized. This study involved multiple reactions and reactants, such as 1,1,1,3,3,3-Hexafluoroisopropylmethacrylate (cas: 3063-94-3Quality Control of 1,1,1,3,3,3-Hexafluoroisopropylmethacrylate).

1,1,1,3,3,3-Hexafluoroisopropylmethacrylate (cas: 3063-94-3) belongs to esters. Esters are widespread in nature and are widely used in industry. In nature, fats are in general triesters derived from glycerol and fatty acids. Esters are responsible for the aroma of many fruits. Many esters have the potential for conformational isomerism, but they tend to adopt an s-cis (or Z) conformation rather than the s-trans (or E) alternative, due to a combination of hyperconjugation and dipole minimization effects. The preference for the Z conformation is influenced by the nature of the substituents and solvent, if present. Lactones with small rings are restricted to the s-trans (i.e. E) conformation due to their cyclic structure.Quality Control of 1,1,1,3,3,3-Hexafluoroisopropylmethacrylate

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

Hydrophobization of cellulose-containing materials with fluoroacrylic polymers and fatty carboxylic acids was written by Bryuzgin, E. V.;Klimov, V. V.;Dvoretskaya, O. V.;Man’, L. D.;Navrotskiy, A. V.;Novakov, I. A.. And the article was included in Russian Journal of Applied Chemistry in 2014.SDS of cas: 3063-94-3 The following contents are mentioned in the article:

The possibility of preparing highly hydrophobic and superhydrophobic coatings on the surface of cellulose-containing materials using fluorinated methacrylic polymers and fatty carboxylic acids was demonstrated. Contact angles of up to 156° and 158°, resp., were reached. This study involved multiple reactions and reactants, such as 1,1,1,3,3,3-Hexafluoroisopropylmethacrylate (cas: 3063-94-3SDS of cas: 3063-94-3).

1,1,1,3,3,3-Hexafluoroisopropylmethacrylate (cas: 3063-94-3) belongs to esters. Carboxylic acid esters of low molecular weight are colourless, volatile liquids with pleasant odours, slightly soluble in water. Many esters have the potential for conformational isomerism, but they tend to adopt an s-cis (or Z) conformation rather than the s-trans (or E) alternative, due to a combination of hyperconjugation and dipole minimization effects. The preference for the Z conformation is influenced by the nature of the substituents and solvent, if present. Lactones with small rings are restricted to the s-trans (i.e. E) conformation due to their cyclic structure.SDS of cas: 3063-94-3

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

Visible-Light-Induced Carbo-2-pyridylation of Electron-Deficient Alkenes with Pyridinium Salts was written by Hu, Rong-Bin;Sun, Shuai;Su, Yijin. And the article was included in Angewandte Chemie, International Edition in 2017.Computed Properties of C7H6F6O2 The following contents are mentioned in the article:

A simple and practical visible-light-induced carbo-2-pyridylation of electron-deficient alkenes with readily available N-benzoylmethylpyridinium bromides is reported. More than 40 examples are presented and proceed in greater than 80% yield (on average) with excellent regio- and diastereoselectivities. This study involved multiple reactions and reactants, such as 1,1,1,3,3,3-Hexafluoroisopropylmethacrylate (cas: 3063-94-3Computed Properties of C7H6F6O2).

1,1,1,3,3,3-Hexafluoroisopropylmethacrylate (cas: 3063-94-3) belongs to esters. Esters are widespread in nature and are widely used in industry. In nature, fats are in general triesters derived from glycerol and fatty acids. Esters are responsible for the aroma of many fruits. Esters contain a carbonyl center, which gives rise to 120° C–C–O and O–C–O angles. Unlike amides, esters are structurally flexible functional groups because rotation about the C–O–C bonds has a low barrier. Their flexibility and low polarity is manifested in their physical properties; they tend to be less rigid (lower melting point) and more volatile (lower boiling point) than the corresponding amides. Computed Properties of C7H6F6O2

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

2-Trifluoromethylated Indoles via Radical Trifluoromethylation of Isonitriles was written by Zhang, Bo;Studer, Armido. And the article was included in Organic Letters in 2014.Safety of 1,1,1,3,3,3-Hexafluoroisopropylmethacrylate The following contents are mentioned in the article:

Either two or three C-C bonds are formed in the synthesis of 2-trifluoromethylindoles starting with readily prepared isonitriles and the Togni reagent as CF₃ radical precursor. These transformations occur in the absence of transition metal, and products are obtained in moderate to good yields with excellent diastereoselectivity. This study involved multiple reactions and reactants, such as 1,1,1,3,3,3-Hexafluoroisopropylmethacrylate (cas: 3063-94-3Safety of 1,1,1,3,3,3-Hexafluoroisopropylmethacrylate).

1,1,1,3,3,3-Hexafluoroisopropylmethacrylate (cas: 3063-94-3) belongs to esters. Esters typically have a pleasant smell; those of low molecular weight are commonly used as fragrances and are found in essential oils and pheromones. Many esters have the potential for conformational isomerism, but they tend to adopt an s-cis (or Z) conformation rather than the s-trans (or E) alternative, due to a combination of hyperconjugation and dipole minimization effects. The preference for the Z conformation is influenced by the nature of the substituents and solvent, if present. Lactones with small rings are restricted to the s-trans (i.e. E) conformation due to their cyclic structure.Safety of 1,1,1,3,3,3-Hexafluoroisopropylmethacrylate

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

Polymerization of fluorine-containing vinyl monomers, 1. Monomer reactivity ratios and Q, e-values of fluoroalkyl acrylates and methacrylates was written by Narita, Tadashi;Hagiwara, Tokio;Hamana, Hiroshi. And the article was included in Makromolekulare Chemie, Rapid Communications in 1985.Name: 1,1,1,3,3,3-Hexafluoroisopropylmethacrylate The following contents are mentioned in the article:

The e values in the polymerization of 2,2,2-trifluoromethyl or 2,2,2-trifluoro-1-(trifluoromethyl)ethyl (meth)acrylates with styrene  [100-42-5] (calculated from reactivity ratios) and σ values (calculated using the relation between e and Hammett σ values) showed an electron-withdrawing inductive effect of fluoroalkyl ester groups. This study involved multiple reactions and reactants, such as 1,1,1,3,3,3-Hexafluoroisopropylmethacrylate (cas: 3063-94-3Name: 1,1,1,3,3,3-Hexafluoroisopropylmethacrylate).

1,1,1,3,3,3-Hexafluoroisopropylmethacrylate (cas: 3063-94-3) belongs to esters. Esters are also usually derived from carboxylic acids. It may also be obtained by reaction of acid anhydride or acid halides with alcohols or by the reaction of salts of carboxylic acids with alkyl halides. Esters are more polar than ethers but less polar than alcohols. They participate in hydrogen bonds as hydrogen-bond acceptors, but cannot act as hydrogen-bond donors, unlike their parent alcohols. This ability to participate in hydrogen bonding confers some water-solubility.Name: 1,1,1,3,3,3-Hexafluoroisopropylmethacrylate

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

Coherent Spin Precession and Lifetime-Limited Spin Dephasing in CsPbBr₃ Perovskite Nanocrystals was written by Crane, Matthew J.;Jacoby, Laura M.;Cohen, Theodore A.;Huang, Yunping;Luscombe, Christine K.;Gamelin, Daniel R.. And the article was included in Nano Letters in 2020.Product Details of 3063-94-3 The following contents are mentioned in the article:

Carrier spins in semiconductor nanocrystals are promising candidates for quantum information processing. Using a combination of time-resolved Faraday rotation and photoluminescence spectroscopies, we demonstrate optical spin polarization and coherent spin precession in colloidal CsPbBr₃ nanocrystals that persists up to room temperature By suppressing the influence of inhomogeneous hyperfine fields with a small applied magnetic field, we demonstrate inhomogeneous hole transverse spin-dephasing times (T₂^*) that approach the nanocrystal photoluminescence lifetime, such that nearly all emitted photons derive from coherent hole spins. Thermally activated LO phonons drive addnl. spin dephasing at elevated temperatures, but coherent spin precession is still observed at room temperature These data reveal several major distinctions between spins in nanocrystalline and bulk CsPbBr₃ and open the door for using metal-halide perovskite nanocrystals in spin-based quantum technologies. This study involved multiple reactions and reactants, such as 1,1,1,3,3,3-Hexafluoroisopropylmethacrylate (cas: 3063-94-3Product Details of 3063-94-3).

1,1,1,3,3,3-Hexafluoroisopropylmethacrylate (cas: 3063-94-3) belongs to esters. Esters are widespread in nature and are widely used in industry. In nature, fats are in general triesters derived from glycerol and fatty acids. Esters are responsible for the aroma of many fruits, including apples, durians, pears, bananas, pineapples, and strawberries. Liquid esters of low volatility serve as softening agents for resins and plastics. Esters also include many industrially important polymers. Polymethyl methacrylate is a glass substitute sold under the names Lucite and Plexiglas; polyethylene terephthalate is used as a film (Mylar) and as textile fibres sold as Terylene, Fortrel, and Dacron.Product Details of 3063-94-3

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

Tuning Surface Properties of Poly(methyl methacrylate) Film Using Poly(perfluoromethyl methacrylate)s with Short Perfluorinated Side Chains was written by Sohn, Eun-Ho;Ha, Jong-Wook;Lee, Soo-Bok;Park, In Jun. And the article was included in Langmuir in 2016.Name: 1,1,1,3,3,3-Hexafluoroisopropylmethacrylate The following contents are mentioned in the article:

To control the surface properties of a commonly used polymer, poly(Me methacrylate) (PMMA), poly(perfluoromethyl methacrylate)s (PFMMAs) with short perfluorinated side groups (i.e., -CF₃, -CF₂CF₃, -(CF₃)₂, -CF₂CF₂CF₃) were used as blend components because of their good solubility in organic solvents, low surface energies, and high optical transmittance. The surface energies of the blend films of PFMMA with the -CF₃ group and PMMA increased continuously with increasing PMMA contents from 17.58 to 25.97 mN/m, whereas those of the other polymer blend films remained at low levels (10.24-12.59 mN/m), similar to those of pure PFMMAs, even when the blends contained 90 weight% PMMA. Surface morphol. and composition measurements revealed that this result originated from the different blend structures, such as uniform distribution and vertical phase separation We expect that these PFMMAs will be useful in widening the applicable window of PMMA. This study involved multiple reactions and reactants, such as 1,1,1,3,3,3-Hexafluoroisopropylmethacrylate (cas: 3063-94-3Name: 1,1,1,3,3,3-Hexafluoroisopropylmethacrylate).

1,1,1,3,3,3-Hexafluoroisopropylmethacrylate (cas: 3063-94-3) belongs to esters. Esters perform as high-grade solvents for a broad array of plastics, plasticizers, resins, and lacquers, and are one of the largest classes of synthetic lubricants on the commercial market. Esters are more polar than ethers but less polar than alcohols. They participate in hydrogen bonds as hydrogen-bond acceptors, but cannot act as hydrogen-bond donors, unlike their parent alcohols. This ability to participate in hydrogen bonding confers some water-solubility.Name: 1,1,1,3,3,3-Hexafluoroisopropylmethacrylate

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

The formulation of polymers by polymerization-polycondensation processes: polyimide based systems was written by Vygodskii, Yakov S.;Sakharova, Antonina A.;Matieva, Aza M.. And the article was included in High Performance Polymers in 1999.Product Details of 3063-94-3 The following contents are mentioned in the article:

Radical chain (co)polymerization of a set of acrylates containing dissolved high performance polymers, namely fluoropolyimide, is performed. Based on the study of the structure and properties of the polymers (elemental composition, solubility, mol. weight parameters, etc.) it is proposed that the copolymer formation reaction takes place due to a transfer chain reaction on the polyimide. The influence of acrylates (ethyl-, n-butyl-, methyl-α-fluoro-, ethyl-α-fluoro-, Me glycidyl-, butyl-, hexafluoro-iso-propylmethacrylate) and polyimide content on the properties of the copolymers obtained is studied. Clear and opaque, hard and elastic materials are obtained. These polymers differ in their characteristics from the relevant polyacrylates and their blends with polyimide prepared by the usual method of mixing. One-step catalytic polycondensation of diamines and tetracarboxylic acid dianhydrides in a solution of preformed polyimide is studied. It is shown that such a procedure influences the structure and properties of polyimides formed in situ. This study involved multiple reactions and reactants, such as 1,1,1,3,3,3-Hexafluoroisopropylmethacrylate (cas: 3063-94-3Product Details of 3063-94-3).

1,1,1,3,3,3-Hexafluoroisopropylmethacrylate (cas: 3063-94-3) belongs to esters. Esters are widespread in nature and are widely used in industry. In nature, fats are in general triesters derived from glycerol and fatty acids. Esters are responsible for the aroma of many fruits, including apples, durians, pears, bananas, pineapples, and strawberries. Acyl chlorides and acid anhydrides alcoholysis is another way to produce esters. Acyl chlorides and acid anhydrides react with alcohols to produce esters. Anydrous conditions are recommended since both acyl chlorides and acid anhydrides react with water.Product Details of 3063-94-3

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

Novel main-chain-fluorinated polymers for 157-nm photoresists was written by Toriumi, Minoru;Koh, Meiten;Ishikawa, Takuji;Kodani, T.;Araki, Takayuki;Aoyama, Hirokazu;Yamashita, Tsuneo;Yamazaki, Tamio;Furukawa, Takamitsu;Itani, Toshiro. And the article was included in Proceedings of SPIE-The International Society for Optical Engineering in 2003.Formula: C7H6F6O2 The following contents are mentioned in the article:

Main-chain-fluorinated base-resins, including tetrafluoroethylene and norbornene derivatives, were synthesized and their fundamental properties, such as transparency at 157 nm and solubility in a standard alk. developer, were characterized. A high transparency, i.e., absorbance of less then 0.5 μm^-1, was achieved by optimizing the polymerization conditions with a variety of counter monomers. It was found that the polymerization conditions could also control the dissolution rates of the fluoropolymers and increased the dissolution rate of unprotected fluoropolymers by about three orders of magnitude, which was sufficient for the alk. developability. Pos.-working resists based on fluororesins were developed and showed good transparency of less than 1 μm^-1 at 157 nm, and good solubility in a standard alk. solution of 0.26-N tetramethylammonium (without any swelling behavior). And an acceptable etching rate as resistant as ArF resists was obtained and 65-nm dense lines could be delineated by the exposure at 157-nm wavelength. This study involved multiple reactions and reactants, such as 1,1,1,3,3,3-Hexafluoroisopropylmethacrylate (cas: 3063-94-3Formula: C7H6F6O2).

1,1,1,3,3,3-Hexafluoroisopropylmethacrylate (cas: 3063-94-3) belongs to esters. Esters typically have a pleasant smell; those of low molecular weight are commonly used as fragrances and are found in essential oils and pheromones. Liquid esters of low volatility serve as softening agents for resins and plastics. Esters also include many industrially important polymers. Polymethyl methacrylate is a glass substitute sold under the names Lucite and Plexiglas; polyethylene terephthalate is used as a film (Mylar) and as textile fibres sold as Terylene, Fortrel, and Dacron.Formula: C7H6F6O2

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

RAFT-polymerized poly(hexafluoroisopropyl methacrylate)s as precursors for functional water-soluble polymers was written by Nuhn, Lutz;Overhoff, Iris;Sperner, Marcel;Kaltenberg, Katrin;Zentel, Rudolf. And the article was included in Polymer Chemistry in 2014.Quality Control of 1,1,1,3,3,3-Hexafluoroisopropylmethacrylate The following contents are mentioned in the article:

Post-polymerization modification of well-defined precursor polymers is a versatile tool to obtain multifunctional water-soluble polymers that cannot be synthesized by common polymerization techniques. For the first time, 1,1,1,3,3,3-hexafluoroisopropyl methacrylate (HFIPMA) based homo and block copolymers were synthesized via RAFT polymerization to provide precise precursors for the post-polymerization modification of the 1,1,1,3,3,3-hexafluoroisopropyl ester side chains with water-soluble amines (methoxy tri(ethylene glycol)amine, 2-hydroxypropylamine and 3-(dimethylamino)-1-propylamine). Sequential aminolysis using Oregon Green cadaverine first, followed by 2-hydroxypropylamine enables access to dye-labeled poly(2-hydroxypropyl methacrylamide) and aminolysis with 3-(dimethylamino)-1-propylamine provides homo and block co-catiomers that complex pDNA in PBS. To this respect, poly(1,1,1,3,3,3-hexafluoroisopropyl methacrylate)s P(HFIPMA)s as precursor polymers may become an alternative route for the synthesis of multifunctional water-soluble polymers for advanced applications. This study involved multiple reactions and reactants, such as 1,1,1,3,3,3-Hexafluoroisopropylmethacrylate (cas: 3063-94-3Quality Control of 1,1,1,3,3,3-Hexafluoroisopropylmethacrylate).

1,1,1,3,3,3-Hexafluoroisopropylmethacrylate (cas: 3063-94-3) belongs to esters. Carboxylic acid esters of low molecular weight are colourless, volatile liquids with pleasant odours, slightly soluble in water. Esters contain a carbonyl center, which gives rise to 120° C–C–O and O–C–O angles. Unlike amides, esters are structurally flexible functional groups because rotation about the C–O–C bonds has a low barrier. Their flexibility and low polarity is manifested in their physical properties; they tend to be less rigid (lower melting point) and more volatile (lower boiling point) than the corresponding amides. Quality Control of 1,1,1,3,3,3-Hexafluoroisopropylmethacrylate

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics