Category: 3052-61-7

Yamashita, Keiji published the artcilePreparation of photoresist polymer by a photoreactive monomer containing N,N-diethyldithiocarbamate group, Application of Benzyl diethylcarbamodithioate, the publication is Journal of Applied Polymer Science (1988), 35(2), 465-73, database is CAplus.

p-Et₂NCS₂CH₂C₆H₄CH:CH₂ (I) was synthesized and copolymerized with styrene, Me methacrylate, acrylonitrile, and vinyl acetate by AIBN initiation. The copolymers obtained had efficient photocrosslinking abilities, and were thermally stable. Therefore, there was no loss of dithiocarbamoyl group during radical polymerization, and the polymerization proceeded through vinyl groups. The degree of UV photocrosslinking was proportional to the concentration of the photosensitive group, but photosensitivity of the polymer was not. Water-soluble photoreactive copolymers of I with acrylamide (II) and methacrylic acid were also prepared I–II copolymer had good photosensitivity at only 3 mol% I incorporation. Photocrosslinking yields of these polymers depends on the viscosity of the original polymers except in the case of low concentration of I. The relation between copolymer composition and glass transition temperature (T_g) was also investigated. Investigation of T_g, showed that the copolymer structure largely affected the ΔT_g. The mechanism of photocrosslinking was studied by photodecomposition of benzyl N,N-diethyldithiocarbamate, and the decreases of sulfur content was clearly related to photocrosslinking points.

Journal of Applied Polymer Science published new progress about 3052-61-7. 3052-61-7 belongs to esters-buliding-blocks, auxiliary class Amine,Benzene,Amide, name is Benzyl diethylcarbamodithioate, and the molecular formula is C8H10BNO3, Application of Benzyl diethylcarbamodithioate.

Referemce:
https://en.wikipedia.org/wiki/Ester,
Ester – an overview | ScienceDirect Topics

Yamashita, Keiji published the artcilePreparation of photoresist polymer by a photoreactive monomer containing N,N-diethyldithiocarbamate group, Computed Properties of 3052-61-7, the publication is Journal of Applied Polymer Science (1988), 35(2), 465-73, database is CAplus.

The title monomer, 4-vinylbenzyl diethyldithiocarbamate (I), was synthesized and copolymerized with some vinyl monomers by AIBN. The copolymers obtained had efficient photocrosslinking abilities, and were thermally stable. There was no loss of the dithiocarbamoyl group during radical polymerization, and the polymerization proceeded through the vinyl group. The degree of photocrosslinking was proportional to the concentration of the photosensitive group, but the photosensitivity of the polymer was not. Water-soluble photoreactive copolymers, of I with acrylamide (II) or methacrylic acid were also prepared The I–II copolymer had good photosensitivity at 3% I incorporation. Photocrosslinking yields of these polymers depended on the viscosity of the original polymers except for low I amounts The relation between copolymer composition and glass transition temperature (T_g) indicated that the copolymer structure largely depended on ΔT_g. The mechanism of photocrosslinking was studied by photodecomposition of benzyl diethyldithiocarbamate, showing that decreases of S content were clearly related to the photocrosslinking points.

Journal of Applied Polymer Science published new progress about 3052-61-7. 3052-61-7 belongs to esters-buliding-blocks, auxiliary class Amine,Benzene,Amide, name is Benzyl diethylcarbamodithioate, and the molecular formula is C7H3BrF3I, Computed Properties of 3052-61-7.

Referemce:
https://en.wikipedia.org/wiki/Ester,
Ester – an overview | ScienceDirect Topics

Jovanovic, Slobodan M. published the artcileInitiation of polymerization of methyl methacrylate by dithiocarbomate-based iniferters, Application of Benzyl diethylcarbamodithioate, the publication is Hemijska Industrija (2005), 59(11-12), 311-316, database is CAplus.

Twelve modified dithiocarbamates and a thiuram disulfide used for the initiation of Me methacrylate (MMA) polymerization were synthesized in this study. The polymerization of MMA was followed by determine the yield and molar mass of the obtained PMMA as a function of polymerization time. Four of the synthesized dithiocarbamates: S-benzyl-N,N-dibenzyldithiocarbamate, S-allyl-N,N-dibenzyldithiocarbamate, S-benzyl-N,N-diisobutyldithiocarbamate and S-benzoyl-N,N-diisobutyldithiocarbamate, as well as N,N,N’,N’-tetrabenzylthiuramdisulfide acted as iniferters. They were active as the initiators of the photo and/or thermally initiated radical polymerization of MMA in bulk and inert solvents (benzene and toluene). S-Benzyl-N,N-dibenzyldithiocarbamate can be successfully used for the initiation of MMA polymerization in a polar solvent such as dimethylacetamide.

Hemijska Industrija published new progress about 3052-61-7. 3052-61-7 belongs to esters-buliding-blocks, auxiliary class Amine,Benzene,Amide, name is Benzyl diethylcarbamodithioate, and the molecular formula is C12H17NS2, Application of Benzyl diethylcarbamodithioate.

Referemce:
https://en.wikipedia.org/wiki/Ester,
Ester – an overview | ScienceDirect Topics

Gorshkov, N. I. published the artcileMixed-Ligand Gallium Complexes with N-Vinylpyrrolidone-N-Vinylformamide-N-Vinyliminodiacetic Acid Terpolymers Containing Dithiocarbamates as a Coligand, Formula: C12H17NS2, the publication is Doklady Chemistry (2019), 485(2), 105-108, database is CAplus.

Terpolymers with a mol. weight of 65 and 13 kDa containing 90 mol % of N-vinylpyrrolidone, 7 mol % of N-vinylformamide, and 3 mol % of N-vinyliminodiacetic acid units have been synthesized. Diethyldithiocarbamate and benzyldithiocarbamate have been used as coligands. The mixed-ligand complexation with Ga³⁺ ion has been studied by HPLC. The composition and structure of the resulting metal-polymer complexes have been determined by exclusion chromatog. and spectral (IR, ¹H NMR) data.

Doklady Chemistry published new progress about 3052-61-7. 3052-61-7 belongs to esters-buliding-blocks, auxiliary class Amine,Benzene,Amide, name is Benzyl diethylcarbamodithioate, and the molecular formula is C12H17NS2, Formula: C12H17NS2.

Referemce:
https://en.wikipedia.org/wiki/Ester,
Ester – an overview | ScienceDirect Topics

Arnold, Michelle E. published the artcileMicrophase-Separated Block Copolymers Comprising Low Surface Energy Fluorinated Blocks and Hydrophilic Blocks: Synthesis and Characterization, Category: esters-buliding-blocks, the publication is Macromolecules (2002), 35(9), 3697-3707, database is CAplus.

The synthesis and characterization of diblock and triblock copolymers produced by a two-component iniferter system is reported. These materials, designed for possible water treatment applications, consist of a hydrophilic poly(2-dimethylaminoethyl methacrylate) (PDMAEMA) block and a very low surface energy poly(1,1′-dihydroperfluorooctyl methacrylate) (PFOMA) or poly(1,1,2,2-tetrahydroperfluorooctyl acrylate) (PTAN) block. Angle-dependent X-ray spectroscopy results and water contact angle measurements indicate that the surfaces of PDMAEMA-b-PFOMA diblock copolymers consist primarily of PFOMA. Transmission electron microscopy reveals that the block copolymers are microphase-separated, exhibiting either cylindrical or layered morphologies that do not change appreciably upon exposure to water. Both water uptake and water flux increase with increasing PDMAEMA content.

Macromolecules published new progress about 3052-61-7. 3052-61-7 belongs to esters-buliding-blocks, auxiliary class Amine,Benzene,Amide, name is Benzyl diethylcarbamodithioate, and the molecular formula is C12H17NS2, Category: esters-buliding-blocks.

Referemce:
https://en.wikipedia.org/wiki/Ester,
Ester – an overview | ScienceDirect Topics

Mouri, Emiko published the artcileAssociation behaviors of poly(N-vinylpyrrolidone)-grafted fullerenes in aqueous solution, Application In Synthesis of 3052-61-7, the publication is Journal of Polymer Research (2018), 25(10), 1-10, database is CAplus.

Poly(N-vinylpyrrolidone) (PVP)-grafted fullerenes (PVP-C₆₀ and PVP-C₇₀) were synthesized by iniferter polymerization in order to fabricate water-soluble fullerene containing micelles. PVP-C₆₀ formed micelles with hydrodynamic diameters ranging from 15 to 33 nm. The solubilization of fullerene mols. into the core of the PVP-C₆₀ micelles was also found to control the size of the micelles. By increasing the amount of added fullerene, we gradually increased the micelle size before drastically increasing it to that of 200 nm in hydrodynamic diameter The drastic change occurred at a critical value of the added C₆₀/PVP monomer ratio, almost independently of the mol. weight of PVP.

Journal of Polymer Research published new progress about 3052-61-7. 3052-61-7 belongs to esters-buliding-blocks, auxiliary class Amine,Benzene,Amide, name is Benzyl diethylcarbamodithioate, and the molecular formula is C12H17NS2, Application In Synthesis of 3052-61-7.

Referemce:
https://en.wikipedia.org/wiki/Ester,
Ester – an overview | ScienceDirect Topics

Maruyama, Taiki published the artcileMultifunctional 3D Printing of Heterogeneous Polymer Structures by Laser-Scanning Micro-Stereolithography Using Reversible Addition-Fragmentation Chain-Transfer Polymerization, HPLC of Formula: 3052-61-7, the publication is ACS Applied Polymer Materials (2022), 4(8), 5514-5522, database is CAplus.

Stereolithog. is the most precise three-dimensional (3D) printing technol. and has been applied to various applications with various photocurable materials. However, most 3D-printed objects produced using conventional methods are made of uniform materials, limiting their functions. In this study, to produce heterogeneous 3D-printed objects, microphase-separated structures were controlled by the copolymerization of a photoinduced macro-reversible addition-fragmentation chain-transfer (macro-RAFT) agent and a monomer at different scanning speeds of an UV laser beam using a laboratory-constructed laser-scanning micro-stereolithog. system based on a bottom-up configuration in a fully open-to-air system. First, we demonstrated 3D printing using a RAFT agent by fabricating a pyramidal structure using a 375 nm laser. Copolymerization with styrene was performed to confirm that the synthesized poly(Bu acrylate) with dormant species at the end (DTC-PBA) formed block polymers upon photoirradiation NMR and gel permeation chromatog. (GPC) results indicated the formation of a block polymer. A homogeneous photocurable resin was prepared by mixing the synthesized DTC-PBA with multi-functional monomers, and 3D printing was performed using the prepared photocurable resin at different scanning speeds. As the scanning speed increased, the transparency of the 3D-printed model increased, whereas the mech. strength decreased. It was suggested from scanning probe microscopy (SPM) observations that these differences were due to differences in the microphase-separation structure. As a result, it was demonstrated that heterogeneous 3D structures with sites have different mech. and optical properties from those of a single material. Controlling the phys. properties of 3D-printed parts by controlling the laser irradiation conditions is useful for functionalizing 3D-printed microdevices.

ACS Applied Polymer Materials published new progress about 3052-61-7. 3052-61-7 belongs to esters-buliding-blocks, auxiliary class Amine,Benzene,Amide, name is Benzyl diethylcarbamodithioate, and the molecular formula is C12H17NS2, HPLC of Formula: 3052-61-7.

Referemce:
https://en.wikipedia.org/wiki/Ester,
Ester – an overview | ScienceDirect Topics

Chevrie, David published the artcileOxidation of dithiocarbamates and synthesis of a stable sulfine, Quality Control of 3052-61-7, the publication is Tetrahedron Letters (1998), 39(49), 8983-8986, database is CAplus.

Investigation of the oxidation reaction of various dithiocarbamates demonstrated that the corresponding sulfines (S-oxides) are formed. Though their stabilities are very moderate, a number of sulfines could be isolated and characterized. When left at ambient temperature they decomposed to thiolocarbamates and dithiocarbamates. The sulfines from secondary dithiocarbamates led to disulfides. With a sterically hindered aryl group present on the sulfur atom, a stable sulfine was prepared and its crystal structure was analyzed.

Tetrahedron Letters published new progress about 3052-61-7. 3052-61-7 belongs to esters-buliding-blocks, auxiliary class Amine,Benzene,Amide, name is Benzyl diethylcarbamodithioate, and the molecular formula is C12H17NS2, Quality Control of 3052-61-7.

Referemce:
https://en.wikipedia.org/wiki/Ester,
Ester – an overview | ScienceDirect Topics

Nakayama, Yasuhide published the artcileHigh performance gene delivery polymeric vector: Nano-structured cationic star polymers (star vectors), Recommanded Product: Benzyl diethylcarbamodithioate, the publication is Current Drug Delivery (2005), 2(1), 53-57, database is CAplus and MEDLINE.

Nano-structured hyperbranched cationic star polymers, called star vectors, were molecularly designed for a novel gene delivery non-viral vector. The linear and 3, 4 or 6 branched water-soluble cationic polymers, which had same mol. weight of ∼18,000, were synthesized by iniferter (initiator-transfer agent-terminator)-based photo-living-radical polymerization of 3-(N,N-dimethylamino)propyl acrylamide, initiated from resp. multi-dithiocarbamate-derivatized benzenes as an iniferter. All polymers produced polyion complexes ‘polyplexes’ by mixing with pDNA (pGL3-control plasmid), in which the particle size was ∼250 nm in diameter [the charge ratio < 2/1 (vector/pDNA)] and ∼150 nm (the charge ratio > 2.5/1), and the ζ-potential was ∼+10 mV (the charge ratio > 1/1). When COS-1 cells were incubated with the polyplexes 12h after preparation under the charge ratio of 5/1, higher gene expression was obtained as an increase in branching, with a little cytotoxicity. The relative gene expression to the linear polymer was about 2, 5, and 10 times in 3-, 4-, and 6-branched polymers, resp. The precise change in branching of polymers enabled the control of the gene transfer activity.

Current Drug Delivery published new progress about 3052-61-7. 3052-61-7 belongs to esters-buliding-blocks, auxiliary class Amine,Benzene,Amide, name is Benzyl diethylcarbamodithioate, and the molecular formula is C12H17NS2, Recommanded Product: Benzyl diethylcarbamodithioate.

Referemce:
https://en.wikipedia.org/wiki/Ester,
Ester – an overview | ScienceDirect Topics

Lee, Heung Jae published the artcileSurface photograft polymerization on segmented polyurethane using the iniferter technique, Product Details of C12H17NS2, the publication is Journal of Biomedical Materials Research (1999), 47(4), 564-567, database is CAplus and MEDLINE.

A segmented polyurethane (SPU) film was chloromethylated and subsequently dithiocarbamated. The treated films were immersed in solutions containing poly(ethylene glycol) methacrylate (PEGMA) or N,N-dimethylacryl amide (DMAAm) and irradiated with UV light. The resultant surfaces were highly wettable with water. The surface chem. compositions, as determined by XPS, indicated that surface graft polymerization, initiated from surface-derivatized dithiocarbamate, had occurred and had altered the surface properties and the composition of SPU. The platelet adhesion test using platelet-rich plasma showed minimal adhesion for the poly(PEGMA)-grafted surface, followed by the poly(DMAAm)-grafted surface.

Journal of Biomedical Materials Research published new progress about 3052-61-7. 3052-61-7 belongs to esters-buliding-blocks, auxiliary class Amine,Benzene,Amide, name is Benzyl diethylcarbamodithioate, and the molecular formula is C12H17NS2, Product Details of C12H17NS2.

Referemce:
https://en.wikipedia.org/wiki/Ester,
Ester – an overview | ScienceDirect Topics