Category: 3052-61-7

Konecny, V. published the artcileSynthesis and biological properties of dithiocarbamic acid derivatives. IV. Herbicidal activity of some esters of N, N-diethyldithiocarbamic acid, Category: esters-buliding-blocks, the publication is Acta Facultatis Rerum Naturalium Universitatis Comenianae, Chimia (1971), 47-57, database is CAplus.

The herbicidal effectiveness of N,N-diethyldithiocarbamic acid esters [(Et)2NC(:S)SR] or [(Et)2NC(:S)SCH2C(O)R] as foliar sprays or as preplant treatments in agricultural crops was most promising with N,N-diethyl-S-(2-chloroallyl)dithiocarbamidate (Vegadex) [95-06-7]. Similar herbicidal effects could be demonstrated with preplant or foliar applications of N,N-diethyl-S-propyldithiocarbamidate [19047-77-9] or with preplant applications of N,N-diethyl-S-(N’,N’-dimethylcarbamidomethyl)dithiocarbamidate [23257-85-4]. The synthesis of the title compounds was reported in an earlier paper.

Acta Facultatis Rerum Naturalium Universitatis Comenianae, Chimia published new progress about 3052-61-7. 3052-61-7 belongs to esters-buliding-blocks, auxiliary class Amine,Benzene,Amide, name is Benzyl diethylcarbamodithioate, and the molecular formula is C12H17NS2, Category: esters-buliding-blocks.

Referemce:
https://en.wikipedia.org/wiki/Ester,
Ester – an overview | ScienceDirect Topics

Garcia Lopez, J. published the artcileApplication of molecularly imprinted polymer nanoparticles for degradation of the bacterial autoinducer N-hexanoyl homoserine lactone, Recommanded Product: Benzyl diethylcarbamodithioate, the publication is Chemical Communications (Cambridge, United Kingdom) (2019), 55(18), 2664-2667, database is CAplus and MEDLINE.

A novel bacterial quorum quenching system is presented. For the first time the degradation of N-L-hexanoyl homoserine lactone (C6-AHL), a Gram-neg. quorum sensing autoinducer, has been enhanced using molecularly imprinted nanoparticles (MIP NPs) which were prepared using transition state analog of the γ-lactone ring hydrolysis as template.

Chemical Communications (Cambridge, United Kingdom) published new progress about 3052-61-7. 3052-61-7 belongs to esters-buliding-blocks, auxiliary class Amine,Benzene,Amide, name is Benzyl diethylcarbamodithioate, and the molecular formula is C12H17NS2, Recommanded Product: Benzyl diethylcarbamodithioate.

Referemce:
https://en.wikipedia.org/wiki/Ester,
Ester – an overview | ScienceDirect Topics

Kuriyama, Akira published the artcileLiving radical polymerization of methyl methacrylate with a tetrafunctional photoiniferter: synthesis of a star polymer, Related Products of esters-buliding-blocks, the publication is Polymer Journal (Tokyo, Japan) (1984), 16(6), 511-14, database is CAplus.

The radical polymerization of Me methacrylate is described using 1,2,4,5-tetrakis(N,N-diethyldithiocarbamylmethyl)benzene  [92687-20-2] as a tetrafunctional photoiniferter and compared with that using benzyl N,N-diethyldithiocarbamate  [3052-61-7] and p-xylylene bis(N,N-diethyldithiocarbamate) [89964-93-2]. Fractionation results confirmed the formation of star polymers.

Polymer Journal (Tokyo, Japan) published new progress about 3052-61-7. 3052-61-7 belongs to esters-buliding-blocks, auxiliary class Amine,Benzene,Amide, name is Benzyl diethylcarbamodithioate, and the molecular formula is C12H17NS2, Related Products of esters-buliding-blocks.

Referemce:
https://en.wikipedia.org/wiki/Ester,
Ester – an overview | ScienceDirect Topics

Otsu, Takayuki published the artcileSolid-phase block copolymer synthesis by the iniferter technique, Application of Benzyl diethylcarbamodithioate, the publication is Macromolecules (1986), 19(7), 2087-9, database is CAplus.

The synthesis of pure block copolymers free from homopolymer was attempted by using diethyldithiocarbamate derivatives attached to a dense polystyrene  [9003-53-6]el through a hydrolyzable ester spacer as a solid photoiniferter. The photopolymerization of styrene proceeded via a living radical mechanism, i.e., both yield and mol. weight of the polystyrene isolated by hydrolysis increased with increased reaction time. Repeated photopolymerization of vinyl monomers and solvent-extraction of the homopolymers produced, followed by hydrolysis, gave the pure triblock copolymers.

Macromolecules published new progress about 3052-61-7. 3052-61-7 belongs to esters-buliding-blocks, auxiliary class Amine,Benzene,Amide, name is Benzyl diethylcarbamodithioate, and the molecular formula is C12H17NS2, Application of Benzyl diethylcarbamodithioate.

Referemce:
https://en.wikipedia.org/wiki/Ester,
Ester – an overview | ScienceDirect Topics

Ishizu, Koji published the artcileDegree of branching of hyperbranched polystyrenes via a controlled radical mechanism of an inimer: Determination by a kinetic approach, Computed Properties of 3052-61-7, the publication is Journal of Applied Polymer Science (2005), 96(5), 1810-1815, database is CAplus.

We studied, with a kinetic approach, the living nature and degree of branching (DB) of the formation of hyperbranched polystyrene by the free-radical photopolymerization of 2-(N,N-diethyldithiocarbamyl)methylstyrene in benzene. The free-radical polymerization proceeded with a living radical mechanism. Subsequently, we treated the kinetics of the initiation and propagation steps of the active A* and B* (side-group) sites with model compounds The degradation rates of two types of dithiocarbamate groups at the A and B sites agreed well with theor. trends for C-S bond dissociation energies predicted by the d. functional theory for model compounds The reactivity of the initiating B* groups was greater than that of the propagating A* groups. DB of the hyperbranched polymers was estimated to be 0.31 with both reaction rates in terms of Mueller’s equation. This result supported the DB value (0.39) estimated from NMR data. The hyperbranched mols. obtained in this work were not perfectly dendritic but had somewhat defective structures.

Journal of Applied Polymer Science published new progress about 3052-61-7. 3052-61-7 belongs to esters-buliding-blocks, auxiliary class Amine,Benzene,Amide, name is Benzyl diethylcarbamodithioate, and the molecular formula is C12H17NS2, Computed Properties of 3052-61-7.

Referemce:
https://en.wikipedia.org/wiki/Ester,
Ester – an overview | ScienceDirect Topics

Ishizu, Koji published the artcileKinetics of Hyperbranched Polystyrenes by Free Radical Polymerization of Photofunctional Inimer, Application In Synthesis of 3052-61-7, the publication is Macromolecules (2002), 35(9), 3781-3784, database is CAplus.

Kinetics of hyperbranched polystyrene was studied by free radical polymerization of photofunctional inimer CH₂=CH-p-C₆H₄-CH₂SC(S)N(Et)₂. The degree of branching was also studied. Results demonstrated that d. functional theory calculations provide a reliable and quant. prediction of exptl. observed trends in C-S bond dissociation energies for several model compounds

Macromolecules published new progress about 3052-61-7. 3052-61-7 belongs to esters-buliding-blocks, auxiliary class Amine,Benzene,Amide, name is Benzyl diethylcarbamodithioate, and the molecular formula is C12H17NS2, Application In Synthesis of 3052-61-7.

Referemce:
https://en.wikipedia.org/wiki/Ester,
Ester – an overview | ScienceDirect Topics

Yoshimi, Yasuo published the artcileSize of heparin-imprinted nanoparticles reflects the matched interactions with the target molecule, Name: Benzyl diethylcarbamodithioate, the publication is Sensors (2019), 19(10), 2415, database is CAplus and MEDLINE.

It has been shown that the faradic current at an electrode grafted with molecularly imprinted polymer (MIP) is sensitive to the specific target mol. used as the template. This phenomenon is applicable to sensors with very high selectivity, but the sensing mechanism is still a black box. We investigated the size sensitivity of nanoparticles of molecularly imprinted polymers (MIP-NPs) to a specific interaction for determination of the mechanism of the gate effect and its feasibility for new applications. Nanoparticles of poly(methacryloxy Et trimethylammonium chloride-co-acrylamide-co-methylenebisacrylamide) imprinted with heparin immobilized on glass beads were synthesized. The diameter of the MIP-NPs of heparin was increased by the presence of the heparin template but was insensitive to chondroitin sulfate C (CSC), the analog of heparin. The high selectivity of the MIP-NPs was consistent with the selectivity of electrodes grafted with a heparin-imprinted polymer in our previous studies. The quartz crystal microbalance probes immobilizing heparin or CSC were sensitive to MIP-NPs, which indicates that the binding ability of MIP-NP does not discriminate between the template and other glycosaminoglycans. These results indicate that the size of the MIP-NP is sensitive to the matched binding with the template through the imprinted cavity.

Sensors published new progress about 3052-61-7. 3052-61-7 belongs to esters-buliding-blocks, auxiliary class Amine,Benzene,Amide, name is Benzyl diethylcarbamodithioate, and the molecular formula is C4Br2N2O4S, Name: Benzyl diethylcarbamodithioate.

Referemce:
https://en.wikipedia.org/wiki/Ester,
Ester – an overview | ScienceDirect Topics

Oki, Yoshitaka published the artcileSynthesis of AB and ABA type block copolymers of vinyl chloride using iniferter technique, Formula: C12H17NS2, the publication is Polymer Journal (Tokyo, Japan) (2002), 34(10), 736-741, database is CAplus.

The photopolymerization of vinyl chloride (VC) with benzyl N,N-diethyldithiocarbamate (BDC) or p-xylylene bis(N,N-diethyldithiocarbamate) (XDC) was carried out in 1,2-dichloroethane at 30°C. From the ¹H NMR spectra, these poly(vinyl chloride)s (PVC) were found to contain mono- or di-functional polymers which can be used for synthesizing the AB type or ABA type block copolymers, resp. The photocopolymn. of the mono-functional PVC with styrene (St) or vinyl acetate (VAc) was carried out in cyclohexanone at 30°C. The obtained copolymers were the AB type block copolymers of VC with St or VAc. The photocopolymn. of the di-functional PVC with St in cyclohexanone at 30°C gave an ABA type block copolymer of VC and St.

Polymer Journal (Tokyo, Japan) published new progress about 3052-61-7. 3052-61-7 belongs to esters-buliding-blocks, auxiliary class Amine,Benzene,Amide, name is Benzyl diethylcarbamodithioate, and the molecular formula is C12H17NS2, Formula: C12H17NS2.

Referemce:
https://en.wikipedia.org/wiki/Ester,
Ester – an overview | ScienceDirect Topics

Nghiem, Quoc Dat published the artcileControlled/living radical polymerization of vinylcyclicsilazane by RAFT process and their block copolymers, Computed Properties of 3052-61-7, the publication is Journal of Polymer Science, Part A: Polymer Chemistry (2008), 46(13), 4594-4601, database is CAplus.

High mol. weight poly(vinyl)silazane were synthesized successfully by reversible addition fragmentation chain transfer (RAFT) polymerization in toluene at 120 °C, using dithiocarbamate derivatives and 2,2′-azobis-isobutyrylnitrile (AIBN) as the RAFT agents and thermal initiator, resp. The polymerization of a vinylcyclicsilazane oligomer with 82.5% conversion was readily controlled to increase the mol. weight from 1000 to 12,000 g/mol with a narrow polydispersity <1.5. The resulting polymer showed a high ceramic yield of 70 wt % at 1000 °C. Moreover, the approach was extended successfully to the synthesis of poly(vinyl)silazane-block-polystyrene as an inorganic-organic diblock copolymer.

Journal of Polymer Science, Part A: Polymer Chemistry published new progress about 3052-61-7. 3052-61-7 belongs to esters-buliding-blocks, auxiliary class Amine,Benzene,Amide, name is Benzyl diethylcarbamodithioate, and the molecular formula is C12H17NS2, Computed Properties of 3052-61-7.

Referemce:
https://en.wikipedia.org/wiki/Ester,
Ester – an overview | ScienceDirect Topics

Johnson, Carl R. published the artcileSyntheses of thiiranes from aldehydes or ketones and sulfur-stabilized carbanions, HPLC of Formula: 3052-61-7, the publication is Tetrahedron Letters (1975), 2865-8, database is CAplus.

S-stabilized carbanionic compounds with alkyllithium and aldehydes gave homologated derivatives which with alkali or on heating decomposed to thiiranes. E.g., the thiazoline I (R = H) and the pyridine II (R = H) with BuLi and PhCHO gave homologs I and II [R = CH(OH)Ph] which with base gave thiiranes III (R = H, Ph, resp.). Similarly, Et2NCS2CH2Ph with LiN(CHMe2)2 and EtCHO gave, after treatment with NaH, III (R = Et).

Tetrahedron Letters published new progress about 3052-61-7. 3052-61-7 belongs to esters-buliding-blocks, auxiliary class Amine,Benzene,Amide, name is Benzyl diethylcarbamodithioate, and the molecular formula is C12H17NS2, HPLC of Formula: 3052-61-7.

Referemce:
https://en.wikipedia.org/wiki/Ester,
Ester – an overview | ScienceDirect Topics