Category: 3052-61-7

Hua, Daoben published the artcileDithiocarbamate mediated controlled/living free radical polymerization of methyl acrylate under ⁶⁰Co γ-ray irradiation: Conjugation effect of N-group, Synthetic Route of 3052-61-7, the publication is Journal of Polymer Science, Part A: Polymer Chemistry (2004), 42(22), 5670-5677, database is CAplus.

The free radical polymerizations of Me acrylate have been studied under γ-ray irradiation in the presence of the dithiocarbamates with different N-groups. The results indicate that the conjugation structure of the N-group of dithiocarbamate plays an important role in living free radical polymerization The polymerizations reveal good living characteristics in the presence of dithiocarbamates (benzyl 1H-imidazole-1-carbodithioate, benzyl 1H-pyrrole-1-carbodithioate, benzyl 1H-indole-1-carbodithioate, and benzyl 9H-carbazole-9-carbodithioate) with N-aryl group. In contrast, the polymerization with benzyl N,N-diethyldithiocarbamate cannot be controlled, and the obtained polymer has a broad mol. weight distribution or even crosslink occurs. Moreover, polymerization rate is influenced by the conjugation structure of the N-group of dithiocarbamate, and the aromatic polycyclic structure of the N-group leads to slow polymerization

Journal of Polymer Science, Part A: Polymer Chemistry published new progress about 3052-61-7. 3052-61-7 belongs to esters-buliding-blocks, auxiliary class Amine,Benzene,Amide, name is Benzyl diethylcarbamodithioate, and the molecular formula is C12H17NS2, Synthetic Route of 3052-61-7.

Referemce:
https://en.wikipedia.org/wiki/Ester,
Ester – an overview | ScienceDirect Topics

Azizi, Najmedin published the artcileStraightforward and Highly Efficient Catalyst-Free One-Pot Synthesis of Dithiocarbamates under Solvent-Free Conditions, HPLC of Formula: 3052-61-7, the publication is Organic Letters (2006), 8(23), 5275-5277, database is CAplus and MEDLINE.

A highly efficient and simple synthesis of dithiocarbamates, e.g. I, based on the one-pot reaction of amines, CS₂, and alkyl halides without using a catalyst under solvent-free conditions, is reported. The mild reaction conditions, high yields, and broad scope of the reaction illustrate the good synthetic utility of this method. The reaction is a highly atom-economic process for production of S-alkyl thiocarbamates and successfully can be used in high quantities in the pharmaceutical or agrochem. industries.

Organic Letters published new progress about 3052-61-7. 3052-61-7 belongs to esters-buliding-blocks, auxiliary class Amine,Benzene,Amide, name is Benzyl diethylcarbamodithioate, and the molecular formula is C12H17NS2, HPLC of Formula: 3052-61-7.

Referemce:
https://en.wikipedia.org/wiki/Ester,
Ester – an overview | ScienceDirect Topics

Azizi, Najmedin published the artcileVersatile and large-scale synthesis of functional dithiocarbamates in water, COA of Formula: C12H17NS2, the publication is Synthetic Communications (2011), 41(1), 94-99, database is CAplus.

Structural diversity is possible in direct access to functional dithiocarbamates based on a highly efficient and simple one-pot reaction of CS₂, amines, and alkyl halides in nearly quant. yields in water.

Synthetic Communications published new progress about 3052-61-7. 3052-61-7 belongs to esters-buliding-blocks, auxiliary class Amine,Benzene,Amide, name is Benzyl diethylcarbamodithioate, and the molecular formula is C12H17NS2, COA of Formula: C12H17NS2.

Referemce:
https://en.wikipedia.org/wiki/Ester,
Ester – an overview | ScienceDirect Topics

Lakshmi, Dhana published the artcileComputational Design and Preparation of MIPs for Atrazine Recognition on a Conjugated Polymer-Coated Microtiter Plate, Application In Synthesis of 3052-61-7, the publication is Industrial & Engineering Chemistry Research (2013), 52(39), 13910-13916, database is CAplus.

Herein, the authors present a technique for the coating of microplate wells with thin layers of cross-linked polymers, as demonstrated by the preparation of a small library of molecularly imprinted polymers (MIPs) imprinted with atrazine and the corresponding control polymers (NIPs). The composition of MIPs was based on the results of a computational screening using the SYBYL suite of mol. modeling software. The monomers giving the most favorable interaction energies in a virtual monomers screening were N,N’-methylene-bis-acrylamide, methacrylic acid, N-phenylethylene diamine methacrylamide (NPEDMA), and itaconic acid. The polymer library was prepared by surface grafting to a layer of poly-(NPEDMA), formed by oxidative polymerization in each of the microplate wells, after activation of the methacrylamide double bonds with a photochem. iniferter (benzyl N,N-diethyldithiocarbamate). MIPs and NIPs were prepared with each of the four functional monomers, cross-linked with ethylene glycol dimethacrylate, using template-monomer ratios of 1:1, 1:2, or 1:3. Binding of the template and its structural analogs (simizine and metribuzine) was assessed by LC-MS. The method is suitable for rapid screening and optimization of MIPs, is capable of automation, and uses a simple grafting protocol compatible with conventional MIP compositions The method not only can be used as a screening tool but could also form the basis of new MIP-based assays.

Industrial & Engineering Chemistry Research published new progress about 3052-61-7. 3052-61-7 belongs to esters-buliding-blocks, auxiliary class Amine,Benzene,Amide, name is Benzyl diethylcarbamodithioate, and the molecular formula is C12H17NS2, Application In Synthesis of 3052-61-7.

Referemce:
https://en.wikipedia.org/wiki/Ester,
Ester – an overview | ScienceDirect Topics

Piletska, Elena V. published the artcileMagnetic high throughput screening system for the development of nano-sized molecularly imprinted polymers for controlled delivery of curcumin, HPLC of Formula: 3052-61-7, the publication is Analyst (Cambridge, United Kingdom) (2015), 140(9), 3113-3120, database is CAplus and MEDLINE.

Curcumin is a versatile anti-inflammatory and anti-cancer agent known for its low bioavailability, which could be improved by developing materials capable of binding and releasing drug in a controlled fashion. The present study describes the preparation of magnetic nano-sized Molecularly Imprinted Polymers (nanoMIPs) for the controlled delivery of curcumin and their high throughput characterization using microtiter plates modified with magnetic inserts. NanoMIPs were synthesized using functional monomers chosen with the aid of mol. modeling. The rate of release of curcumin from five polymers was studied under aqueous conditions and was found to correlate well with the binding energies obtained computationally. The presence of specific monomers was shown to be significant in ensuring effective binding of curcumin and to the rate of release obtained. Characterization of the polymer particles was carried out using dynamic light scattering (DLS) technique and SEM in order to establish the relationship between irradiation time and particle size. The protocols optimized during this study could be used as a blueprint for the development of nanoMIPs capable of the controlled release of potentially any compound of interest.

Analyst (Cambridge, United Kingdom) published new progress about 3052-61-7. 3052-61-7 belongs to esters-buliding-blocks, auxiliary class Amine,Benzene,Amide, name is Benzyl diethylcarbamodithioate, and the molecular formula is C12H17NS2, HPLC of Formula: 3052-61-7.

Referemce:
https://en.wikipedia.org/wiki/Ester,
Ester – an overview | ScienceDirect Topics