Category: 15625-89-5

Borjigin, Timur published the artcileThe new LED-Sensitive photoinitiators of Polymerization: Copper complexes in free radical and cationic photoinitiating systems and application in 3D printing, Recommanded Product: Trimethylolpropane triacrylate, the publication is European Polymer Journal (2022), 110885, database is CAplus.

A ligand (A1) and four copper complexes (Cu1, Cu2, Cu3 and Cu4) were examined as photosensitizers in various photoinitiating systems (PISs). Interestingly, excellent photochem. reactivities were determined with the different compounds Especially, notable photoinitiation abilities were determined upon exposure to LED@405 nm during the free radical polymerization of acrylates and the cationic polymerization of epoxides when combined with an iodonium salt and an amine. With regards to their remarkable reactivities, the different photoinitiating systems were applied to 3D printing experiments By combining steady state photolysis and ESR spin trapping, the chem. mechanism supporting the polymerization processes could be fully detailed and proved. Among all PISs studied, the three-component PISs furnished the best monomer conversions during the free radical polymerization of trimethylolpropane triacrylate (TMPTA) and the cationic polymerization of (3,4-epoxycyclohexane)methyl 3,4-epoxycyclohexylcarboxylate (EPOX) monomers. The conversion process was monitored by real-time Fourier transform IR spectroscopy (RT-FTIR). Three-component PISs based on A1, Cu1 and Cu2 showed better performances than those based on Cu3, Cu4 and the different two-component PIS (comprising only the iodonium salt or the amine) in FRP experiments Based on the outstanding photoinitiation abilities of A1 and Cu1 with both TMPTA and EPOX, smooth and regular 3D patterns could be obtained by direct laser write experiments by generating interpenetrating polymer networks (IPN) with the blend of these two monomers.

European Polymer Journal published new progress about 15625-89-5. 15625-89-5 belongs to esters-buliding-blocks, auxiliary class Polymerization Reagents,Crosslinkers, name is Trimethylolpropane triacrylate, and the molecular formula is C15H20O6, Recommanded Product: Trimethylolpropane triacrylate.

Referemce:
https://en.wikipedia.org/wiki/Ester,
Ester – an overview | ScienceDirect Topics

Gary, Daniel P. published the artcileCharge transfer complexes as dual thermal/photo initiators for free-radical frontal polymerization, SDS of cas: 15625-89-5, the publication is Journal of Polymer Science (Hoboken, NJ, United States) (2022), 60(10), 1624-1630, database is CAplus.

Frontal polymerization is a process in which a localized reaction zone propagates from the coupling of thermal transport and the Arrhenius rate dependence of an exothermic polymerization; monomer is converted into polymer as the front passes through an unstirred medium. Herein we report the first study of charge transfer complexes (CTCs) as photo/thermal initiators for free-radical frontal polymerization Front velocity was studied as a function of mole ratio between an aromatic amine, such as dimethyl-p-toluidine or dimethylaniline, and an iodonium salt. It was found that the front velocity reached a maximum at a certain mole ratio of amine to iodonium salt. The velocity remained constant upon increasing the ratio of amine to iodonium salt past this critical ratio. Fronts were also studied using N-Ph glycine as an electron donor, but its utility was limited by low solubility Lastly, the steric and electronic effects of the iodonium salt and counter anion were explored. It was found that CTCs using iodonium salts with less nucleophilic anions gave higher front velocities. In terms of intrinsic reactivity, the CTC composed of N,N-dimethyl-p-toluidine and bis[4-(tert-butyl)phenyl]iodonium tetra(nonafluoro-tert-butoxy)aluminate gave the highest front velocity per m of iodonium salt.

Journal of Polymer Science (Hoboken, NJ, United States) published new progress about 15625-89-5. 15625-89-5 belongs to esters-buliding-blocks, auxiliary class Polymerization Reagents,Crosslinkers, name is Trimethylolpropane triacrylate, and the molecular formula is C15H20O6, SDS of cas: 15625-89-5.

Referemce:
https://en.wikipedia.org/wiki/Ester,
Ester – an overview | ScienceDirect Topics

Mustapha, Siti Noor Hidayah published the artcileSynthesis and characterization of hydrophobic properties of silicon dioxide in palm oil based bio-coating, Name: Trimethylolpropane triacrylate, the publication is Materials Today: Proceedings (2022), 51(Part_2), 1415-1419, database is CAplus.

This research aims to synthesize a biobased polyurethane coating from epoxidized palm oil (EPO) and determine the effect of different silicon dioxide (SiO₂) loadings on the hydrophobicity performance of the coating. In this work, EPO was firstly undergoing an acrylation reaction and followed by the addition of isophorone diisocyanate (IPDI) to form Polyurethane (PU). Improvement was made by adding SiO₂ at different loadings into the palm oil-based PU to provide hydrophobic properties to the coating materials. The sample was characterized using Fourier Transform IR Spectroscopy (FTIR), water sliding angle test, and water absorption test. Based on the FTIR results, PU was successfully synthesized from EPO with SiO₂ addition The results also proved that the addition of SiO₂ successfully improved the hydrophobicity of the coating. The higher the SiO₂ content in palm oil PU, the shorter the time taken for the water to slide down the 25° angle coated glass and lower the water absorption percentage of the coating material. Based on the anal., 3 phr SiO₂ content showed the highest hydrophobicity performance, which could be applied in further research.

Materials Today: Proceedings published new progress about 15625-89-5. 15625-89-5 belongs to esters-buliding-blocks, auxiliary class Polymerization Reagents,Crosslinkers, name is Trimethylolpropane triacrylate, and the molecular formula is C15H20O6, Name: Trimethylolpropane triacrylate.

Referemce:
https://en.wikipedia.org/wiki/Ester,
Ester – an overview | ScienceDirect Topics

D. Desai, Prashil published the artcileSynthesis of ultraviolet curable bisphenol-based epoxy acrylates and comparative study on its physico-chemical properties, Product Details of C15H20O6, the publication is Journal of Applied Polymer Science (2022), 139(17), 52022, database is CAplus.

Photocuring resins have emerged as cutting-edge technol. in coatings, adhesives, composites, additive manufacturing, and so forth. In the present work, different bisphenol, namely A, F, and S, were used to synthesize low mol. weight epoxy resin, which was further reacted with acrylic acid monomer to form bisphenol-based epoxy acrylate (BEA). The BEA resins were formulated using reactive diluents, trimethylolpropane triacrylate, and hexanediol diacrylate in the ratio of 0-40 wt% at the increment of 10 wt% alongside a fixed quantity photoinitiator. These resins were then cast into dumbbell-shaped specimens by irradiating them under UV light. The structural elucidation of BEA resins was performed using Fourier transform IR, NMR, and UV-Vis spectroscopy. The formulated resins were also studied for their rheol. properties. Further, the UV cured specimens were evaluated for mech., thermal, contact angle, and extent of curing. These outcomes were utilized for establishing the structure-property relationship based on the functionality, reactivity, and mol. structure of synthesized BEA resins, which controllers the design architecture and crosslinking d. of UV-cured specimens.

Journal of Applied Polymer Science published new progress about 15625-89-5. 15625-89-5 belongs to esters-buliding-blocks, auxiliary class Polymerization Reagents,Crosslinkers, name is Trimethylolpropane triacrylate, and the molecular formula is C15H20O6, Product Details of C15H20O6.

Referemce:
https://en.wikipedia.org/wiki/Ester,
Ester – an overview | ScienceDirect Topics

Amoozadeh, Pegah published the artcileUV-curable hybrid hydrogels of carbon quantum dots: synthesis, characterizations and investigation of properties and rheological behavior, Related Products of esters-buliding-blocks, the publication is Polymer-Plastics Technology and Materials, database is CAplus.

In this study, we are going to produce UV-curable hydrogel hybrids with carbon quantum dots. For this purpose, after synthesizing CQDs, they were reacted with acrylic acid to establish covalent bonds and create a C = C bond on the surface of CQDs. Then acrylamide hydrogel was synthesized. In the next step, 1, 3 and 5% UV-curable hydrogel hybrids were prepared The exptl. results displayed that increasing the amount of CQDs in the hydrogel increased photoluminescence intensity and water adsorption while boosting the hydrogel′s thermal stability. Besides, increasing the CQDs amount reduces the hydrogel elasticity.

Polymer-Plastics Technology and Materials published new progress about 15625-89-5. 15625-89-5 belongs to esters-buliding-blocks, auxiliary class Polymerization Reagents,Crosslinkers, name is Trimethylolpropane triacrylate, and the molecular formula is C15H20O6, Related Products of esters-buliding-blocks.

Referemce:
https://en.wikipedia.org/wiki/Ester,
Ester – an overview | ScienceDirect Topics

Mohd Yunus, Nor Yuziah published the artcileTensile performances of radiation triggered wood-plastic composite and trimethylolpropane triacrylate (TMPTA) as additive at different treatments, Application In Synthesis of 15625-89-5, the publication is Materials Today: Proceedings (2022), 51(Part_2), 1293-1297, database is CAplus.

The blending of wood fibers with polypropylene has been widely reported. The behavior for radiation triggered wood-plastic composite (WPC) may differ for different treatment protocol. This study looks at the effect of combination style of rubberwood fiber, polypropylenes and additive (trimethylolpropane triacrylate, TMPTA) radiation treatment. The effect is measured through the tensile and flexural properties of the resultant WPC. The combination of sep. radiation of fiber, polypropylene combine with TMPTA, showed the best performance for tensile at 48.2 MPa at initial stage and second best reading after 24 mo. Interestingly the combination with only polypropylene irradiated gave lowest initial tensile but developed the highest strength value after 24 mo storage. The dynamic mech. test for the WPC showed the presence of trapped radicals in the completed WPC. The change in strength showed a different ageing effect in radiated sample which need to be studied further prior to usage.

Materials Today: Proceedings published new progress about 15625-89-5. 15625-89-5 belongs to esters-buliding-blocks, auxiliary class Polymerization Reagents,Crosslinkers, name is Trimethylolpropane triacrylate, and the molecular formula is C15H20O6, Application In Synthesis of 15625-89-5.

Referemce:
https://en.wikipedia.org/wiki/Ester,
Ester – an overview | ScienceDirect Topics

El-Zayat, Mai M. published the artcileEnhancing the physico-mechanical properties of ethylene propylene diene monomer rubber via ?-radiation in the presence of bi-functional and tri-functional monomers, SDS of cas: 15625-89-5, the publication is Radiochimica Acta (2022), 110(2), 145-156, database is CAplus.

This study, uses two polyfunctional monomers (PFMs) namely ethylene glycol dimethacrylate (EGDMA) as a bifunctional monomer and trimethylolpropane triacrylate (TMPTA) as a trifunctional monomer were used as co-agents in irradiation crosslinking of Ethylene Propylene Diene Monomer Rubber (EPDM). The effect of concentration of each PFM and irradiation dose on the crosslinking d., gel content, swelling behavior in motor and brake oils, in addition to the mech. and thermal stability properties of EPDM was investigated in detailed. The results showed a remarkable increase in the gel content, crosslinking d. and mech. properties as the concentration of PFMs increased from 1 to 5 phr (parts per hundred parts of rubber). The various blends of EPDM with the trifunctional monomer express the highest gel content and crosslinking d. than those with the bifunctional monomer. The addition of 5 phr of TMPTA to EPDM causes a dramatic improvement in tensile strength (TS) of the prepared blend reached to 188% compared to neat EPDM at 50 kGy. At the same time, the maximum TS of the blend containing 5 phr of EGDMA achieved only 41% compared to neat EPDM at an irradiation dose of 100 kGy. The swelling of irradiated samples in brake oil revealed a stronger oil resistance than motor oil. For all irradiated samples, the oil uptake decreased with the irradiation dose up to 100 kGy. The EPDM samples containing 5 phr of TMPTA recorded the highest oil resistance at 100 kGy. The results also showed that the addition of PFMs and irradiation treatment of the various prepared blends improved the thermal stability of EPDM. Finally, neat EPDM and the blends containing 1 and 3 phr of EGDMA can be used as radiation dosimeters in the very high dose range (50-200 kGy).

Radiochimica Acta published new progress about 15625-89-5. 15625-89-5 belongs to esters-buliding-blocks, auxiliary class Polymerization Reagents,Crosslinkers, name is Trimethylolpropane triacrylate, and the molecular formula is C15H20O6, SDS of cas: 15625-89-5.

Referemce:
https://en.wikipedia.org/wiki/Ester,
Ester – an overview | ScienceDirect Topics

Dakova, Ivanka published the artcileFe(II) ion-imprinted copolymer gels – smart materials for Fe(II)/Fe(III) speciation in surface waters, Computed Properties of 15625-89-5, the publication is Polymer International (2022), 71(6), 706-714, database is CAplus.

The effect of template species – Fe(II) complexes with 4-(2-pyridylazo)resorcinol or 2,2′-bipyridine as well as the functional monomers: acidic (methacrylic acid) and neutral (hydroxyethyl methacrylate) on the extraction efficiency and applicability of Fe(II) ion-imprinted polymers for iron speciation in surface waters is presented in this study. The polymers were synthesized by precipitation copolymerization of functional monomer, trimethylolpropane trimethacrylate (crosslinking agent) and 2,2′-azo-bis-isobutyronitrile (initiator) in the presence of template and characterized by elemental microanal., SEM and Brunauer-Emmett-Teller analyses. Extraction efficiency was examined by batch solid-phase extraction The equilibrium exptl. data of adsorption processes with different synthesized sorbents were fitted by both Langmuir and Freundlich isotherms and are discussed from the viewpoint of possible bond formation between monomer and template species and the stability of the prepolymerization complex. Pseudo-first-order and pseudo-second-order kinetic models were tested to elucidate the possible controlling mechanism of the sorption process for different sorbents. Under the optimum conditions p^H 7 and equilibrium time of 30 min the highest extraction efficiency and selectivity toward Fe(II) was achieved for Fe(II) ion-imprinted polymer containing methacrylic acid and Fe(II)-4-(2-pyridylazo)resorcinol complex as a template. The anal. procedure for Fe speciation was developed and validated with this sorbent. 2021 Society of Industrial Chem.

Polymer International published new progress about 15625-89-5. 15625-89-5 belongs to esters-buliding-blocks, auxiliary class Polymerization Reagents,Crosslinkers, name is Trimethylolpropane triacrylate, and the molecular formula is C15H20O6, Computed Properties of 15625-89-5.

Referemce:
https://en.wikipedia.org/wiki/Ester,
Ester – an overview | ScienceDirect Topics

Madhesan, Thirumalai published the artcileProbe anchored porous organic polymer monolithic architectures as optical sensor for ultra-trace analysis of Hg²⁺ in water samples, Computed Properties of 15625-89-5, the publication is Microporous and Mesoporous Materials (2022), 111724, database is CAplus.

In this article, we have demonstrated an effective strategy to detect and remove the toxic Hg²⁺ by an ion-selective optical sensor using chromoionophoric receptor that is homogenously dispersed onto the surface of porous organic polymer (POP) template. Herein, we present a detailed summation of the synthesis of different POPs by employing various kinds of monomers and crosslinkers to discover excellent structural property materials that could cater to the needs of an optical sensor. The resultant POP from the bulk polymerization of N,N-di-Me allylamine (DMA), and trimethylolpropane triacrylate (TMPTA), i.e., poly(DMA-co-TMPTA), manifested a higher surface area with pore size, thus has been utilized as the substrate material for the fabrication of the sensor. Further, the chromoionophoric coordinating ligand, i.e., 7-4(diethylamino)phenyldiazenyl quinolin-8-ol (DPDQ), is immobilized as receptor mols. onto the POP template for ultra-trace detection of Hg²⁺. The surface dispersed receptor forms stable 1:1 charge-transfer complexes [Hg²⁺-DPDQ] with a striking naked-eye color transition from pale orange to bright reddish-brown. The developed optical sensor offers an ultra-fast, selective response for Hg²⁺ with a lower detection limit of 0.1 μg/L (ppb) in the linear range of 0-100 μg/L. The regeneration of the sensor is envisaged with 0.02 M HCl and can be reused for up to six sensing cycles. Actual water samples from different geog. locations of India are tested using the developed sensor, and the method proved effective for real-time monitoring of Hg²⁺.

Microporous and Mesoporous Materials published new progress about 15625-89-5. 15625-89-5 belongs to esters-buliding-blocks, auxiliary class Polymerization Reagents,Crosslinkers, name is Trimethylolpropane triacrylate, and the molecular formula is C15H20O6, Computed Properties of 15625-89-5.

Referemce:
https://en.wikipedia.org/wiki/Ester,
Ester – an overview | ScienceDirect Topics

Liu, Qiaoyang published the artcilePreparation and UV -curing properties of oxazolidine-2-one based acrylates, Formula: C15H20O6, the publication is Polymers for Advanced Technologies (2022), 33(8), 2416-2424, database is CAplus.

Three oxazolidine-2-one based acrylates monomers were synthesized by the reaction of oxazolidine-2-one with 1,6-hexanediol diacrylate (HDDA), neopentyl glycol diacrylate (NPGDA) and trimethylolpropane triacrylate (TMPTA). The mol. structures of the products were characterized by FT-IR, ¹H NMR and electrospray ionization high resolution mass spectrometry (ESI-HRMS). The photo-polymerization kinetics of the synthesized oxazolidine-2-one based acrylates were investigated by real-time IR spectroscopy. The results showed that the oxazolidine-2-one based acrylates with 1 weight% 2-isopropylthioxanthone (ITX) could be cured to form a transparent film under UV irradiation The UV curing speed of oxazolidine-2-one based acrylates with 1 weight% ITX was better than that of TMPTA with 1 weight% ITX and 3 weight% Et 4-(dimethylamino) benzoate (EDB) as co-initiator. Based on the HRMS anal. of oligomers extracted from the UV-cured film, the plausible photopolymerization mechanism was proposed. The synthesized monomer formula with CN996 resin can be 3D printed forming various models with smooth surface, good accuracy, excellent thermal stability and 99.4% gel content.

Polymers for Advanced Technologies published new progress about 15625-89-5. 15625-89-5 belongs to esters-buliding-blocks, auxiliary class Polymerization Reagents,Crosslinkers, name is Trimethylolpropane triacrylate, and the molecular formula is C15H20O6, Formula: C15H20O6.

Referemce:
https://en.wikipedia.org/wiki/Ester,
Ester – an overview | ScienceDirect Topics