Jung, Woo-Ok published the artcileRegio- and Enantioselective Iridium-Catalyzed Amination of Alkyl-Substituted Allylic Acetates with Secondary Amines, COA of Formula: C22H38N4O8, the publication is Organic Letters (2022), 24(1), 441-445, database is CAplus and MEDLINE.
Robust air-stable cyclometalated π-allyliridium C,O-benzoates modified by (S)-tol-BINAP catalyze the reaction of secondary aliphatic amines with racemic alkyl-substituted allylic acetates to furnish products of allylic amination with high levels of enantioselectivity. Complete branched regioselectivities were observed despite the formation of more highly substituted C-N bonds.
Organic Letters published new progress about 1523571-10-9. 1523571-10-9 belongs to esters-buliding-blocks, auxiliary class Azetidine,Salt,Spiro,Amide, name is tert-Butyl 1,6-diazaspiro[3.3]heptane-1-carboxylate oxalate(2:1), and the molecular formula is C22H38N4O8, COA of Formula: C22H38N4O8.
Referemce:
https://en.wikipedia.org/wiki/Ester,
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