Yang, Jun; Zhu, Shengqing; Wang, Fang; Qing, Feng-Ling; Chu, Lingling published the artcile< Silver-Enabled General Radical Difluoromethylation Reaction with TMSCF2H>, Computed Properties of 151259-38-0, the main research area is silver mediated oxidative difluoromethylation styrene vinyl trifluoroborate TMSCF2H; regioselective synthesis; alkenes; difluoromethylation; heteroarenes; radical fluoroalkylation; silver.
A silver-mediated oxidative difluoromethylation of styrenes and vinyl trifluoroborates with TMSCF2H is reported for the first time. This method enables direct and facile access to CF2H-alkenes from abundant alkenes with excellent functional-group compatibility. Moreover, this Ag/TMSCF2H protocol could further enable a series of radical difluoromethylation reactions of a wide array of substrates, offering a generic and complementary platform for the construction of diversified C-CF2H bonds.
Angewandte Chemie, International Edition published new progress about Alkenes Role: RCT (Reactant), SPN (Synthetic Preparation), RACT (Reactant or Reagent), PREP (Preparation). 151259-38-0 belongs to class esters-buliding-blocks, and the molecular formula is C11H19NO2, Computed Properties of 151259-38-0.
Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics