Category: 135529-02-1

Huang, Pin-Chi published the artcileMorphology-Mediated Photoresponsive and Fluorescence Behaviors of Azobenzene-Containing Block Copolymers, Related Products of esters-buliding-blocks, the publication is Langmuir (2018), 34(25), 7416-7427, database is CAplus and MEDLINE.

We investigated the relationship between the self-assembled morphol. of poly(tert-Bu acrylate)-block-poly(6-[4-(4′-methoxyphenylazo)phenoxy]hexyl methacrylate) (PtBA-b-PAzoMA) block copolymers and their photoresponsive and fluorescence behaviors. The morphol. of PtBA-b-PAzoMA copolymers was manipulated by dissolving them in mixed DMF (DMF)/hexanol solvents. When PtBA-b-PAzoMA was dissolved in DMF-rich (neutral) solvents, a favorable interaction between the DMF mols. and both blocks resulted in a random-coiled conformation. The unconfined morphol. facilitated the formation of both nonassocd. and head-to-head organized azobenzene mesogens, which promoted fluorescence emission. When hexanol, a PtBA-selective solvent, was added to DMF, the solvency of PtBA-b-PAzoMA worsened, leading to its assembly into micelles, with PAzoMA in the micelle core. The confinement of azobenzene moieties in the micelle core hindered their trans-to-cis photoisomerization, thereby considerably decreasing the kinetics of photoisomerization and the population of cis isomers. Addnl., a nanoconfined geometry resulted in compactly packed chromophores, causing fluorescence loss. When PtBA-b-PAzoMA was exposed to UV light, the increased number of cis isomers hampered the closely packed mesogens, resulting in a substantial enhancement of fluorescence emission. When the mole fraction of the PAzoMA block was increased, PtBA-b-PAzoMA formed clusters, causing the slow kinetics of photoisomerization and fluorescence quenching.

Langmuir published new progress about 135529-02-1. 135529-02-1 belongs to esters-buliding-blocks, auxiliary class azo,Alkenyl,Benzene,Ester,Ether, name is 6-(4-((4-Methoxyphenyl)diazenyl)phenoxy)hexyl methacrylate, and the molecular formula is C23H28N2O4, Related Products of esters-buliding-blocks.

Referemce:
https://en.wikipedia.org/wiki/Ester,
Ester – an overview | ScienceDirect Topics

Pathiranage, Taniya M. S. K. published the artcileSynthesis and characterization of side-chain thermotropic liquid crystalline copolymers containing regioregular poly(3-hexylthiophene), Recommanded Product: 6-(4-((4-Methoxyphenyl)diazenyl)phenoxy)hexyl methacrylate, the publication is Polymer (2015), 317-326, database is CAplus.

An azobenzene liquid crystalline mesogen, 6-(4-((4-methoxyphenyl)diazenyl)phenoxy)hexyl methacrylate (MMAZO) was incorporated into a block copolymer with regioregular poly(3-hexylthiophene) (P3HT). The synthesis was performed by a combination of Grignard metathesis (GRIM) and atom transfer radical polymerization (ATRP) techniques. The composition of synthesized copolymers was determined from ¹HNMR anal. The P3HT block/random copolymers containing thermotropic liquid crystalline segments were expected to bring unique self-assembly and opto-electronic properties. The field-effect mobility of the P3HT copolymers was measured in organic thin film transistors (OTFT). The surface morphol. of the P3HT copolymer films upon annealing was investigated by tapping mode at. force microscopy (TMAFM). Finally, the transition of liquid crystalline mesophase in response to the temperature in the P3HT copolymers was investigated by differential scanning calorimetry (DSC) and polarizing optical microscopy (POM).

Polymer published new progress about 135529-02-1. 135529-02-1 belongs to esters-buliding-blocks, auxiliary class azo,Alkenyl,Benzene,Ester,Ether, name is 6-(4-((4-Methoxyphenyl)diazenyl)phenoxy)hexyl methacrylate, and the molecular formula is C23H28N2O4, Recommanded Product: 6-(4-((4-Methoxyphenyl)diazenyl)phenoxy)hexyl methacrylate.

Referemce:
https://en.wikipedia.org/wiki/Ester,
Ester – an overview | ScienceDirect Topics

Wu, Yu-Shen published the artcileManipulating the structures and photoresponsive properties of an azobenzene-containing triblock copolymer by changing solvency and adding salts, Computed Properties of 135529-02-1, the publication is Journal of Molecular Liquids (2022), 118013, database is CAplus.

We examined the structure-property relationship of a triblock copolymer comprising azobenzene sequences, namely, poly(6-[4-(4′-ethoxyphenylazo)phenoxy]hexyl methacrylate)-block-poly(ethylene glycol)-block-poly(6-[4-(4′-ethoxyphenylazo)phenoxy]hexyl methacrylate) (PMMAzo-b-PEG-b-PMMAzo), in mixed DMF (DMF)/H2O solvents, with the effects of solvency and salts being the main focus. When H2O (a PEG-selective solvent) was added to DMF (a neutral solvent), the poor compatibility between H2O and PMMAzo mols. led to the formation of micelles comprising PMMAzo and PEG in the core and corona, resp. Increases in the H2O content in the mixed solvent decreased the solvency, which caused increases in the micelle association number and hydrophobic core radius. The azobenzene moieties confined in the micellar core inhibited their photoisomerization, which caused decreases in the photoisomerization kinetics and cis isomer content. The addition of KCl to the PMMAzo-b-PEG-b-PMMAzo solution increased the hydrophobicity of PEG chains and the core radius and decreased the corona thickness. Moreover, the KSCN addition to the aforementioned solution increased the hydrophilicity of PMMAzo segments, which caused the core radius and corona thickness of micelles. Salt addition disturbed the compact packing of mesogens and reduced the mesogen association Consequently, with an increase in the salt concentration, the content of H-type mesogen aggregates increased, whereas that of nonassocd. mesogens decreased.

Journal of Molecular Liquids published new progress about 135529-02-1. 135529-02-1 belongs to esters-buliding-blocks, auxiliary class azo,Alkenyl,Benzene,Ester,Ether, name is 6-(4-((4-Methoxyphenyl)diazenyl)phenoxy)hexyl methacrylate, and the molecular formula is C12H17BO5, Computed Properties of 135529-02-1.

Referemce:
https://en.wikipedia.org/wiki/Ester,
Ester – an overview | ScienceDirect Topics

Li, Najun published the artcileSynthesis and third-order NLO properties of polymethacrylates containing pendent azobenzene groups, Product Details of C23H28N2O4, the publication is High Performance Polymers (2007), 19(3), 356-367, database is CAplus.

Six azobenzene monomers containing methacrylate groups were prepared and characterized. The monomers varied by having alkyl spacers of varying lengths and either nitro or methoxy substituents in conjugation with the azo groups. The monomers were polymerized via atom transfer radical polymerization (ATRP) to give polymethyacrylates with pendent azobenzene groups. The pendent azobenzene groups were separated from the polymer backbone by alkyl spacing groups of varying lengths. The side-chain nonlinear optical (NLO) polymers with variable and controllable mol. weight and low polydispersity (1.2-1.4) were obtained. The kinetics of ATRP for each azo monomer was also studied. The third-order NLO property of azo monomers and their polymers were measured using the degenerated four wave mixing technique. Each of the polymers exhibited relatively high χ⁽³⁾ value and rapid response times. The effects of the substituent and spacer length on the ATRP of the methacrylate monomers and the effect of mol. weight on the third-order NLO property of polymers were investigated.

High Performance Polymers published new progress about 135529-02-1. 135529-02-1 belongs to esters-buliding-blocks, auxiliary class azo,Alkenyl,Benzene,Ester,Ether, name is 6-(4-((4-Methoxyphenyl)diazenyl)phenoxy)hexyl methacrylate, and the molecular formula is C23H28N2O4, Product Details of C23H28N2O4.

Referemce:
https://en.wikipedia.org/wiki/Ester,
Ester – an overview | ScienceDirect Topics

Lee, Ting-Lei published the artcilePhotoresponsive and fluorescence behaviors of azobenzene-containing amphiphilic block copolymers, Product Details of C23H28N2O4, the publication is Journal of Polymer Science, Part B: Polymer Physics (2017), 55(10), 793-803, database is CAplus.

The effects of solvency and mole fraction of azobenzene moieties (f_PAzoMA) on the photoresponsive and fluorescence behaviors of poly(acrylic acid)-block-poly(6-[4-(4′-methoxyphenylazo)phenoxy]hexyl methacrylate) (PAA-PAzoMA) amphiphilic diblock copolymers were investigated using UV-vis spectroscopy and fluorescence spectroscopy. The photoresponsive behavior depended strongly on the solvency and f_PAzoMA. When dissolved in a PAA-selective solvent, PAA-PAzoMA formed micelles with PAzoMA in the micelle core. The confinement of azobenzene moieties caused a steric hindrance, thereby markedly reducing the kinetics of photoisomerization compared with that of the unconfined PAA-PAzoMA in a nonselective solvent. Addnl., PAA-PAzoMA dissolved in the PAA-selective solvent caused a blue shift of the maximum absorbance, suggesting the formation of H-aggregates of azobenzene mesogens. The high H-aggregate content substantially reduced the fluorescence emission. Consequently, the fluorescence emission of PAA-PAzoMA in the nonselective solvent was more intense than that in the PAA-selective solvent. Upon UV irradiation, the enhanced bent-shaped cis isomers disturbed the compact packing of azobenzene mesogens, which substantially enhanced the fluorescence emission. Both the photoisomerization rate and fluorescence emission decreased with an increase in f_PAzoMA. © 2017 Wiley Periodicals, Inc. J. Polym. Sci., Part B: Polym. Phys. 2017.

Journal of Polymer Science, Part B: Polymer Physics published new progress about 135529-02-1. 135529-02-1 belongs to esters-buliding-blocks, auxiliary class azo,Alkenyl,Benzene,Ester,Ether, name is 6-(4-((4-Methoxyphenyl)diazenyl)phenoxy)hexyl methacrylate, and the molecular formula is C23H28N2O4, Product Details of C23H28N2O4.

Referemce:
https://en.wikipedia.org/wiki/Ester,
Ester – an overview | ScienceDirect Topics

Yin, Lu published the artcileSupramolecular chirality induced by chiral solvation in achiral cyclic Azo-containing polymers: topological effects on chiral aggregation, HPLC of Formula: 135529-02-1, the publication is Polymer Chemistry (2018), 9(6), 769-776, database is CAplus.

Herein, a series of azobenzene (Azo)-containing side-chain cyclic polymers were successfully synthesized by combining atom transfer radical polymerization (ATRP) and Cu(I)-catalyzed azide/alkyne cycloaddition (CuAAc) “click” reaction. The aggregates of linear and cyclic Azo polymers in a dichloroethane/limonene mixed solvent were characterized by CD (CD) and UV-visible spectroscopy, demonstrating that the topol. structural constraint and mol. mass of cyclic polymers have clear effects on the supramol. chirality driven by a chiral solvent. The difference between linear and cyclic Azo aggregates in supramol. chirality became less distinct with increasing mol. mass of Azo polymers. The chiroptical switch of cyclic Azo polymers was firstly constructed by trans-cis photoisomerization and cis-trans heating-assisted reorganization processes. These interesting findings suggest that the cyclic topol. has a clear influence on the behavior of supramol. chirality induced by chiral limonene.

Polymer Chemistry published new progress about 135529-02-1. 135529-02-1 belongs to esters-buliding-blocks, auxiliary class azo,Alkenyl,Benzene,Ester,Ether, name is 6-(4-((4-Methoxyphenyl)diazenyl)phenoxy)hexyl methacrylate, and the molecular formula is C8H7ClO3, HPLC of Formula: 135529-02-1.

Referemce:
https://en.wikipedia.org/wiki/Ester,
Ester – an overview | ScienceDirect Topics

Yin, Lu published the artcileInduction and modulation of supramolecular chirality in side-chain azobenzene polymers through the covalent chiral domino effect, Product Details of C23H28N2O4, the publication is Science China: Chemistry (2021), 64(12), 2105-2110, database is CAplus.

Induction, transfer, and modulation of intriguing supramol. chirality were achieved in a chiral domino-type polymer system using a chiral α-end azobenzene (Azo) moiety as one chiral terminus and achiral Azo repeating units as building blocks. The Azo polymers prepared by atom transfer radical polymerization were imparted with well-controlled chain lengths and a chiral moiety at a well-defined position. One chiral terminus can effectively dictate the helical orientation of the achiral Azo stacks in the aggregation state. The spacer length between the chiral residue and the achiral repeating units dominates the preferred handedness of the side-chain Azo stacks. For instance, the R-configuration moiety with a short alkyl chain (with 0, 2, and 3 carbons) induces right-handed supramol. chirality, whereas those with long alkyl chains (with 4, 5, and 6 carbons) induce the opposite helical orientation of the Azo units. Moreover, the chiral regulation of polymer aggregates is successfully achieved using the unique photoisomerization transition of the Azo chromophore and the heat-assisted reassembly approach. Chiral induction and chiral-to-achiral communication are further verified via theor. simulations.

Science China: Chemistry published new progress about 135529-02-1. 135529-02-1 belongs to esters-buliding-blocks, auxiliary class azo,Alkenyl,Benzene,Ester,Ether, name is 6-(4-((4-Methoxyphenyl)diazenyl)phenoxy)hexyl methacrylate, and the molecular formula is C18H17NO8, Product Details of C23H28N2O4.

Referemce:
https://en.wikipedia.org/wiki/Ester,
Ester – an overview | ScienceDirect Topics

Yin, Lu published the artcileSupramolecular chirality induced by chiral solvation in achiral cyclic Azo-containing polymers: topological effects on chiral aggregation, HPLC of Formula: 135529-02-1, the publication is Polymer Chemistry (2018), 9(6), 769-776, database is CAplus.

Herein, a series of azobenzene (Azo)-containing side-chain cyclic polymers were successfully synthesized by combining atom transfer radical polymerization (ATRP) and Cu(I)-catalyzed azide/alkyne cycloaddition (CuAAc) “click” reaction. The aggregates of linear and cyclic Azo polymers in a dichloroethane/limonene mixed solvent were characterized by CD (CD) and UV-visible spectroscopy, demonstrating that the topol. structural constraint and mol. mass of cyclic polymers have clear effects on the supramol. chirality driven by a chiral solvent. The difference between linear and cyclic Azo aggregates in supramol. chirality became less distinct with increasing mol. mass of Azo polymers. The chiroptical switch of cyclic Azo polymers was firstly constructed by trans-cis photoisomerization and cis-trans heating-assisted reorganization processes. These interesting findings suggest that the cyclic topol. has a clear influence on the behavior of supramol. chirality induced by chiral limonene.

Polymer Chemistry published new progress about 135529-02-1. 135529-02-1 belongs to esters-buliding-blocks, auxiliary class azo,Alkenyl,Benzene,Ester,Ether, name is 6-(4-((4-Methoxyphenyl)diazenyl)phenoxy)hexyl methacrylate, and the molecular formula is C8H7ClO3, HPLC of Formula: 135529-02-1.

Referemce:
https://en.wikipedia.org/wiki/Ester,
Ester – an overview | ScienceDirect Topics

Yin, Lu published the artcileInduction and modulation of supramolecular chirality in side-chain azobenzene polymers through the covalent chiral domino effect, Product Details of C23H28N2O4, the publication is Science China: Chemistry (2021), 64(12), 2105-2110, database is CAplus.

Induction, transfer, and modulation of intriguing supramol. chirality were achieved in a chiral domino-type polymer system using a chiral α-end azobenzene (Azo) moiety as one chiral terminus and achiral Azo repeating units as building blocks. The Azo polymers prepared by atom transfer radical polymerization were imparted with well-controlled chain lengths and a chiral moiety at a well-defined position. One chiral terminus can effectively dictate the helical orientation of the achiral Azo stacks in the aggregation state. The spacer length between the chiral residue and the achiral repeating units dominates the preferred handedness of the side-chain Azo stacks. For instance, the R-configuration moiety with a short alkyl chain (with 0, 2, and 3 carbons) induces right-handed supramol. chirality, whereas those with long alkyl chains (with 4, 5, and 6 carbons) induce the opposite helical orientation of the Azo units. Moreover, the chiral regulation of polymer aggregates is successfully achieved using the unique photoisomerization transition of the Azo chromophore and the heat-assisted reassembly approach. Chiral induction and chiral-to-achiral communication are further verified via theor. simulations.

Science China: Chemistry published new progress about 135529-02-1. 135529-02-1 belongs to esters-buliding-blocks, auxiliary class azo,Alkenyl,Benzene,Ester,Ether, name is 6-(4-((4-Methoxyphenyl)diazenyl)phenoxy)hexyl methacrylate, and the molecular formula is C18H17NO8, Product Details of C23H28N2O4.

Referemce:
https://en.wikipedia.org/wiki/Ester,
Ester – an overview | ScienceDirect Topics

Yin, Lu published the artcileSupramolecular chirality induced by chiral solvation in achiral cyclic Azo-containing polymers: topological effects on chiral aggregation, HPLC of Formula: 135529-02-1, the publication is Polymer Chemistry (2018), 9(6), 769-776, database is CAplus.

Herein, a series of azobenzene (Azo)-containing side-chain cyclic polymers were successfully synthesized by combining atom transfer radical polymerization (ATRP) and Cu(I)-catalyzed azide/alkyne cycloaddition (CuAAc) “click” reaction. The aggregates of linear and cyclic Azo polymers in a dichloroethane/limonene mixed solvent were characterized by CD (CD) and UV-visible spectroscopy, demonstrating that the topol. structural constraint and mol. mass of cyclic polymers have clear effects on the supramol. chirality driven by a chiral solvent. The difference between linear and cyclic Azo aggregates in supramol. chirality became less distinct with increasing mol. mass of Azo polymers. The chiroptical switch of cyclic Azo polymers was firstly constructed by trans-cis photoisomerization and cis-trans heating-assisted reorganization processes. These interesting findings suggest that the cyclic topol. has a clear influence on the behavior of supramol. chirality induced by chiral limonene.

Polymer Chemistry published new progress about 135529-02-1. 135529-02-1 belongs to esters-buliding-blocks, auxiliary class azo,Alkenyl,Benzene,Ester,Ether, name is 6-(4-((4-Methoxyphenyl)diazenyl)phenoxy)hexyl methacrylate, and the molecular formula is C8H7ClO3, HPLC of Formula: 135529-02-1.

Referemce:
https://en.wikipedia.org/wiki/Ester,
Ester – an overview | ScienceDirect Topics