Category: 118-55-8

Liu, Tao; Yuan, Xiaoxue; Zhang, Gang; Zeng, Yi; Chen, Tong; Wang, Gongying published an article in 2019, the title of the article was Influence of coordinating groups of organotin compounds on the Fries rearrangement of diphenyl carbonate.Reference of Phenyl Salicylate And the article contains the following content:

In this paper, the Fries rearrangement of di-Ph carbonate (DPC) catalyzed by organotin compounds with different coordination groups was studied for the first time. The electronic effect and steric hindrance of the coordinating groups were discussed with respect to the reactivity of DPC rearrangement. The results showed that both the electronic effect and steric hindrance of the coordinating groups influenced the acidity of the active tin centers and then affected the catalytic performance of organotin as a Lewis acid for the rearrangement of DPC, and the influence of the electronic effect is greater than that of steric hindrance. The catalytic activity is in the order of BuSnO(OH) > Bu2SnO > Bu2Sn(OCOC11H23)2 > BuSnCl3 > Bu3SnOSnBu3 > Bu3SnCl, and Bu2SnO showed the best catalytic activity due to its strong electron absorption effect, small steric hindrance, and good stability. Under the optimum reaction conditions, the conversion of DPC was up to 93%, and the yields of Ph salicylate (PS) and xanthone (XA) were 62% and 28%, resp. In addition, a reaction mechanism of DPC rearrangement catalyzed by the organotin compounds was speculated. This research can provide vigorous theor. data support to control the byproducts produced by DPC rearrangement in the process of DPC synthesis. It also provides a new route for the preparation of PS and XA. The experimental process involved the reaction of Phenyl Salicylate(cas: 118-55-8).Reference of Phenyl Salicylate

The Article related to diphenyl carbonate organotin catalyst fries rearrangement mechanism, Physical Organic Chemistry: Rearrangements, Including Isomerization and Tautomerization and other aspects.Reference of Phenyl Salicylate

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On December 31, 2022, Yashima, Takumi; Tani, Marie; Kurita, Rei published an article.HPLC of Formula: 118-55-8 The title of the article was Filamentous crystal growth in organic liquids and selection of crystal morphology. And the article contained the following:

Filamentous crystals such as whisker crystals are often seen not only in metallic liquids, but also in organic liquids and solutions They are interesting as reinforce materials. However, it remains challenging to induce filamentous crystals due to an incomplete understanding of the mechanisms behind their formation. In this paper, we investigate filamentous crystal growth in viscous organic liquids It is found that filamentous crystals grow via an extraordinary dynamical path, where the mols. locally evaporate to bubbles and then redeposite to the tip of growing crystalline filaments. We also succeeded in controlling whether filamentous or faceted crystal growth is selected by inducing or suppressing the bubbles. The experimental process involved the reaction of Phenyl Salicylate(cas: 118-55-8).HPLC of Formula: 118-55-8

The Article related to filamentous crystal growth organic liquid morphol, Crystallography and Liquid Crystals: Crystal Morphology (Habit), Orientation, Crystallinity and other aspects.HPLC of Formula: 118-55-8

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On January 19, 2022, Xie, Huilin; Lin, Chuankai; Wang, Ruixiang; Liu, Jin-Biao published an article.Electric Literature of 118-55-8 The title of the article was Synthesis of salicylates from anionically activated aromatic trifluoromethyl group. And the article contained the following:

An efficient approach to salicylates via a novel transformation of anionically activated aromatic trifluoromethyl group is described. 2-(Trifluoromethyl)phenol reacts with phenols/alcs. under alk. conditions to afford the corresponding aryl/alkyl salicylates in high yields. Mechanism studies indicated that the carbonyl oxygen atom of ester is from the H2O in the solvent. The experimental process involved the reaction of Phenyl Salicylate(cas: 118-55-8).Electric Literature of 118-55-8

The Article related to phenol trifluoromethyl hydrolysis nucleophilic substitution alc, benzoate hydroxy preparation, Benzene, Its Derivatives, and Condensed Benzenoid Compounds: Esters, Acyl Peroxides, Acyl Halides and other aspects.Electric Literature of 118-55-8

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On September 26, 2022, Wang, Songlin; Jiang, Nan; Peng, Jiali; Yang, Peng; Cui, Chengxing; Niu, Hongying; Zhang, Qiying; Wang, Jianji published an article.Reference of Phenyl Salicylate The title of the article was Efficient Synthesis of Diphenyl Carbonate from CO2, Phenol, and Carbon Tetrachloride under Mild Conditions. And the article contained the following:

Herein, an efficient catalytic system for the direct synthesis of DPC from CO2, phenol, and carbon tetrachloride was developed by using a ZnCl2/copper triflate (Cu(OTf)2) composite catalyst. For the first time, high yield and high selectivity were achieved for DPC synthesis under mild conditions, even at atm. pressure. Carefully designed control experiments and DFT studies indicated that the synergistic activation of Cu(OTf)2 and its anion complex with ZnCl2 for phenol and CO2 led to a remarkably improved catalytic activity through a Lewis acid-assisted catalysis. This study not only provides a new strategy for efficient preparation of DPC but also offers an effective pathway for better CO2 utilization. The experimental process involved the reaction of Phenyl Salicylate(cas: 118-55-8).Reference of Phenyl Salicylate

The Article related to phenol carbon dioxide zinc chloride copper triflate carbonylation, diphenyl carbonate preparation, Benzene, Its Derivatives, and Condensed Benzenoid Compounds: Esters, Acyl Peroxides, Acyl Halides and other aspects.Reference of Phenyl Salicylate

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Tripathy, Alisha Rani; Yedase, Girish Suresh; Yatham, Veera Reddy published an article in 2021, the title of the article was Cerium photocatalyzed radical Smiles rearrangement of 2-aryloxybenzoic acids.Safety of Phenyl Salicylate And the article contains the following content:

A cerium photocatalyzed aryl migration from an aryl ether to a carboxylic acid group through radical-Smiles rearrangement was reported. This operationally simple protocol utilized inexpensive CeCl3 as a photocatalyst and converted a variety of 2-aryloxybenzoic acids into aryl-2-hydroxybenzoates in good yields. The experimental process involved the reaction of Phenyl Salicylate(cas: 118-55-8).Safety of Phenyl Salicylate

The Article related to aryloxybenzoic acid cerium catalyst photochem radical smiles rearrangement, aryl hydroxybenzoate preparation, Benzene, Its Derivatives, and Condensed Benzenoid Compounds: Esters, Acyl Peroxides, Acyl Halides and other aspects.Safety of Phenyl Salicylate

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Yao, Shu-Feng; Cai, Zhao-Sheng; Huang, Xu-Juan; Song, Lan-Xuan published an article in 2020, the title of the article was Preparation of salicylic nitrile through direct catalytic dehydration of salicylamide with immobilized phosphoric acid as catalyst.Formula: C13H10O3 And the article contains the following content:

Salicylic nitrile was prepared through direct catalytic dehydration of salicylamide under high temperature using immobilized phosphoric acid as catalyst. The catalytic performances of different catalysts were evaluated according to the analytic results of GC-MS, and the feasibility about the preparation of salicylic nitrile by direct catalytic dehydration of salicylamide was investigated according to the composition of product determinated by GC anal. (area nomalization). Exptl. results indicated the comprehensive property of silica gel supported phosphoric acid was the best one among all of the catalysts utilized in this study. When the temperature of catalyst bed was 480 ± 10° and silica gel supported phosphoric acid was utilized as catalyst, the conversion ratio of salicylamide was 88.79%, the selectivity to salicylic nitrile was 97.97% and the yields of salicylic nitrile could up to 86.99%. Meanwhile, the exptl. results showed the increase of temperature of catalyst bed could result in the increase of the conversation of salicylamide, but much more byproduct could be formed when the temperature of catalyst bed was too high. The experimental process involved the reaction of Phenyl Salicylate(cas: 118-55-8).Formula: C13H10O3

The Article related to salicylamide immobilize phosphoric acid catalyst direct dehydration, salicylic nitrile preparation, Benzene, Its Derivatives, and Condensed Benzenoid Compounds: Nitriles, Isonitriles, and Acyl Cyanides and other aspects.Formula: C13H10O3

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On July 15, 2018, Lunkenheimer, P.; Wehn, R.; Koehler, M.; Loidl, A. published an article.Synthetic Route of 118-55-8 The title of the article was Fast dynamics in glass-forming salol investigated by dielectric spectroscopy. And the article contained the following:

We analyze dielec.-loss spectra of glass forming salol extending up to 400GHz allowing for the detection of the high-frequency min., where the fast critical dynamics predicted by the mode-coupling theory of the glass transition should prevail. Indeed, we find such a min. which, moreover, well fulfills the critical scaling predicted by the theory. This includes the spectral shape of the min., the critical temperature dependence of the min. frequency and amplitude, and the critical temperature dependence of the α-relaxation rate at high temperatures The min. exponents a and b leading to a system parameter λ≈0.63 and the critical temperature Tc=256K are all in reasonable agreement with previous investigations of salol using different methods. Salol was one of the first materials where mode-coupling theory was tested and initial dielec. measurements were taken as an argument against the universal applicability of this theory. The experimental process involved the reaction of Phenyl Salicylate(cas: 118-55-8).Synthetic Route of 118-55-8

The Article related to glass salol dielec spectrum dynamics, Electric Phenomena: Dielectric and Electret Properties (Including Electric Moments, and Polarizability) and other aspects.Synthetic Route of 118-55-8

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On April 30, 2021, Ashton, Gage P.; Charsley, Edward L.; Harding, Lindsay P.; Parkes, Gareth M. B. published an article.SDS of cas: 118-55-8 The title of the article was DSC temperature calibration over the range -125°C to 50°C. And the article contained the following:

The lack of Nationally Certified Reference Materials for the calibration of DSC equipment in the sub-ambient range has been addressed by the introduction of a Certified Reference Material of purified cyclohexane by the National Metrol. Institute of Japan. This sample, in conjunction with the CRM material Ph salicylate and the ITS-90 fixed point material mercury, has enable a DSC-thermomicroscopy system to be accurately calibrated over the temperature range -90°C to 50°C. The DSC has then been used to measure values for the solid-solid transitions in the potential Certified Reference Materials ammonium sulfate, adamantane and ammonium dihydrogen phosphate, which have the advantage of being thermally stable and easy to handle, and for the m.p. of di-Ph ether. In addition, the effect of temperature cycling on these materials has been investigated. The experimental process involved the reaction of Phenyl Salicylate(cas: 118-55-8).SDS of cas: 118-55-8

The Article related to differential scanning calorimetry temperature calibration, Thermodynamics, Thermochemistry, and Thermal Properties: Calorimetry, Thermal Analysis, Thermogravimetry and other aspects.SDS of cas: 118-55-8

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On December 9, 2021, Wu, Minjian; Wang, Xuepu; Pan, Yingtong; Li, Jiuyang; Li, Xun; Sun, Yan; Zou, Yunlong; Zhang, Hefeng; Zhang, Kaka published an article.Application In Synthesis of Phenyl Salicylate The title of the article was Two-Component Design Strategy: Achieving Intense Organic Afterglow and Diverse Functions in Coronene-Matrix Systems. And the article contained the following:

A two-component design strategy developed by us and other research groups, where a second component is used to control the triplet excited state properties of the luminescent component (the first component), has been shown to allow a flexible choice of building blocks to prepare high-performance afterglow materials with intriguing properties. Here, we report the realization of intense organic afterglow and diverse functions by extending this two-component strategy to dopant-matrix systems, which feature small kF, small kP, and very small knr + kq. With coronene mols. and deuterated coronene being fixed as luminescent dopants, variation of organic matrixes reveals that either small-mol. organic matrixes or polymeric matrixes can be used to accommodate coronene mols. and largely reduce knr + kq values, leading to the emergence of very bright organic afterglow at ambient conditions. The obtained coronene-matrix materials have been found to be readily processed into desired shapes, large-area thin films, and aqueous afterglow dispersions by melt casting and other techniques, function as efficient afterglow donors for the fabrication of red afterglow materials, and exhibit promising time-gated bioimaging functionality to avoid interference from strong fluorescence backgrounds. The experimental process involved the reaction of Phenyl Salicylate(cas: 118-55-8).Application In Synthesis of Phenyl Salicylate

The Article related to organic afterglow coronene matrix system, Optical, Electron, and Mass Spectroscopy and Other Related Properties: Spectrometers and Optical Apparatus and other aspects.Application In Synthesis of Phenyl Salicylate

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On December 31, 2020, Hao, Xiaopeng; Song, Jian; Ding, Lei; Wen, Ping; Sun, Jianping; Liu, Yang; Yuan, Zundong; Duan, Yuning; Zhang, Yong published an article.COA of Formula: C13H10O3 The title of the article was Spaceborne radiance temperature standard blackbody for Chinese high-precision infrared spectrometer. And the article contained the following:

As a radiance temperature standard source for the Chinese high-resolution spectrum IR spectrometer, the National Institute of Metrol., China, developed a spaceborne radiance temperature standard blackbody (SRTSB) combined with a series of miniature phase change fixed points (MPCFPs) for temperature calibration and emissivity verification using a thermal radiation loop (TRL). The MPCFPs of the SRTSB contain H2O, Ga, Ga-Sn alloy, and Ph salicylate. The TRL is used to measure the emissivity of the spaceborne blackbody on the basis of controlling environmental radiation. Exptl. results show that the blackbody emissivity is higher than 0.998 and the temperature control stability is better than 5 mK. Temperature control uniformity at the cavity bottom and axial are better than or equal to 11 mK and 38 mK, resp., in the working temperature range of 268.15 K to 331.15 K.. The repeatability of the MPCFPs is less than 5 mK, and the results of the continuous phase transition of the MPCFPs are in a clear temperature plateau. The expanded uncertainty of the SRTSB is lower than or equal to 0.084 K (k = 2). The experimental process involved the reaction of Phenyl Salicylate(cas: 118-55-8).COA of Formula: C13H10O3

The Article related to spaceborne radiance temperature standard blackbody thermal radiation loop, Radiation Chemistry, Photochemistry, and Photographic and Other Reprographic Processes: Information Recording and Storage and other aspects.COA of Formula: C13H10O3

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Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics