Category: 113602-62-3

Wasserman, Harry H. published the artcileSinglet oxygen reactions of 2-carbalkoxy-3-methoxypyrroles, Name: Methyl 3-hydroxy-1-methyl-1H-pyrrole-2-carboxylate, the main research area is singlet oxygen reaction carbalkoxymethoxypyrrole; pyrrolecarboxylate methoxy singlet oxygen.

The reaction of singlet oxygen with 3-methoxy-2-carbalkoxypyrroles leads to 2,5-oxygenation, 2,3-epoxides, or 2,3-oxidative cleavage, depending on substitution patterns and reaction conditions. Thus, pyrrole I gave 45% hydroxy lactam II, 35% cleavage product MeO2CCH:CHN(CH2Ph)COCO2CMe3, and 10% 2,3-epoxide. Dipyrrolyl compound III gave the cleavage compound; the desired bis-lactam was not formed.

Tetrahedron Letters published new progress about singlet oxygen reaction carbalkoxymethoxypyrrole; pyrrolecarboxylate methoxy singlet oxygen. 113602-62-3 belongs to class esters-buliding-blocks, name is Methyl 3-hydroxy-1-methyl-1H-pyrrole-2-carboxylate, and the molecular formula is C7H9NO3, Name: Methyl 3-hydroxy-1-methyl-1H-pyrrole-2-carboxylate.

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

Wasserman, Harry H. published the artcileSinglet oxygen in synthesis. Formation of d,l- and meso-Isochrysohermidin from a 3,3′-bipyrrole precursor, COA of Formula: C7H9NO3, the main research area is isochrysohermidin synthesis oxidation; bipyrrole oxidation singlet oxygen isochrysohermidin synthesis.

A synthesis of the d,l and meso forms of isochrysohermidin is outlined which employs the singlet oxygen oxidation of pyrroles as the key step. The bipyrrole precursor I was synthesized from a 3-hydroxy monopyrrole which, in turn, was prepared by addition of methylamine to a vinyl vicinal tricarbonyl.

Tetrahedron published new progress about Oxidation. 113602-62-3 belongs to class esters-buliding-blocks, name is Methyl 3-hydroxy-1-methyl-1H-pyrrole-2-carboxylate, and the molecular formula is C7H9NO3, COA of Formula: C7H9NO3.

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics