Category: 111-11-5

Li, Fuzeng published the artcileFlotation and adsorption mechanism studies of antimony sulfide with 5-heptyl-1,3,4-oxadiazole-2-thione as a collector, Quality Control of 111-11-5, the main research area is antimony sulfide heptyl oxadiazole thione collector flotation adsorption.

Oxadiazole-thione compounds include the conjugated N-, O- and S-donor atoms and possess special metal-chelating properties. In the paper, an alkyl oxadiazole-thione surfactant, 5-heptyl-1,3,4-oxadiazole-2-thione (HpODT) was designed and synthesized as a chelating collector used for the recovery of antimony sulfide. Micro-flotation tests showed that the HpODT has better recovery and selectivity for antimony sulfide against iron and cadmium sulfide in comparison with sodium iso-Bu xanthate (SIBX). The adsorption anal. indicated that the adsorption of HpODT on antimony sulfide was a spontaneous-exothermic chemisorption process. The UV absorption spectrum (UVAS) revealed that HpODT might anchor on antimony sulfide surfaces by adsorption monolayers. The zeta potential and FTIR inferred recommended a chemisorption of antimony sulfide to HpODT. XPS afforded distinct proofs that the conjugated N- and S-donor atoms of HpODT coordinate with the surface antimony atoms of antimony sulfide to generate the hydrophobic HpODT-Sb surface complexes.

Minerals Engineering published new progress about Adsorption. 111-11-5 belongs to class esters-buliding-blocks, name is Methyl octanoate, and the molecular formula is C9H18O2, Quality Control of 111-11-5.

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

Huang, Qing published the artcileNitric acid functionalization of petroleum coke to access inherent sulfur, Quality Control of 111-11-5, the main research area is petcoke nitric sulfuric acid catalyst treatment dibenzothiophene oxidation.

Sulfonated carbon-based catalysts have been identified as promising solid acid catalysts, and petroleum coke (petcoke), a byproduct of the oil industry, is a potential feedstock for these catalysts. In this study, sulfur-containing (6.5 wt%) petcoke was used as a precursor for these catalysts through direct functionalization (i.e., without an activation step) with nitric acid to access the inherent sulfur. Catalysts were also prepared using sulfuric acid and a mixture of nitric and sulfuric acid (1:3 vol ratio). Fourier transform IR spectroscopy, XPS, and titration were used to identify and quantify the acid sites. The activities of the prepared catalysts were determined for the esterification of octanoic acid with methanol. Petcoke had few -SO3H groups, and correspondingly no catalytic activity for the reaction. All acid treatments increased the number of -SO3H groups and promoted esterification. Treatment with nitric acid alone resulted in the oxidation of the inherent sulfur in petcoke to produce ∼0.7 mmol/g of strong acid sites and a total acidity of 5.3 mmol/g. The acidity (strong acid and total) was lower with sulfuric acid treatment but this sample was more active for the esterification reaction (TOF of 31 h-1 compared to 7 h-1 with nitric acid treatment).

Catalysts published new progress about Adsorption. 111-11-5 belongs to class esters-buliding-blocks, name is Methyl octanoate, and the molecular formula is C9H18O2, Quality Control of 111-11-5.

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

Ma, Gamaliel Junren published the artcileElucidating How Different Amphipathic Stabilizers Affect BSA Protein Conformational Properties and Adsorption Behavior, HPLC of Formula: 111-11-5, the main research area is amphipath stabilizer bovine serum albumin protein conformation adsorption.

Natural proteins such as bovine serum albumin (BSA) are readily extracted from biol. fluids and widely used in various applications such as drug delivery and surface coatings. It is standard practice to dope BSA proteins with an amphipathic stabilizer, most commonly fatty acids, during purification steps to maintain BSA conformational properties. There have been extensive studies investigating how fatty acids and related amphiphiles affect solution-phase BSA conformational properties, while it is far less understood how amphipathic stabilizers might influence noncovalent BSA adsorption onto solid supports, which is practically relevant to form surface coatings. Herein, we systematically investigated the binding interactions between BSA proteins and different molar ratios of caprylic acid (CA), monocaprylin (MC), and Me caprylate (ME) amphiphiles-all of which have 8-carbon-long, saturated hydrocarbon chains with distinct headgroups-and resulting effects on BSA adsorption behavior on silica surfaces. Our findings revealed that anionic CA had the greatest binding affinity to BSA, which translated into greater solution-phase conformational stability and reduced adsorption-related conformational changes along with relatively low packing densities in fabricated BSA adlayers. On the other hand, nonionic MC had moderate binding affinity to BSA and could stabilize BSA conformational properties in the solution and adsorbed states while also enabling BSA adlayers to form with higher packing densities. We discuss physicochem. factors that contribute to these performance differences, and our findings demonstrate how rational selection of amphiphile type and amount can enable control over BSA adlayer properties, which could lead to improved BSA protein-based surface coatings.

Langmuir published new progress about Adsorption. 111-11-5 belongs to class esters-buliding-blocks, name is Methyl octanoate, and the molecular formula is C9H18O2, HPLC of Formula: 111-11-5.

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

Wang, Liwen published the artcileSiO2 supported Ni-In intermetallic compounds: Efficient for selective hydrogenation of fatty acid methyl esters to fatty alcohols, SDS of cas: 111-11-5, the main research area is SiO2 nickel indium hydrogenation fatty acid methyl ester alc.

Ni/SiO2 and SiO2 supported Ni2In, NiIn and Ni2In3 intermetallic compounds (IMCs) were prepared by the sol-gel method and tested for the selective hydrogenation of Me esters to fatty alcs. It was found that the Ni phyllosilicate formed during the sol-gel process leads to high Ni dispersion. In IMCs, the Ni atoms are homogeneously isolated by the In ones and the charge is transferred from In to Ni. In the selective hydrogenation, decarbonylation/decarboxylation dominatingly occur on Ni/SiO2, while SiO2 supported IMCs mainly give fatty alcs., and the yield of fatty alc. can reach above 94%. We suggest that it is the synergetic effect between Ni and In that facilitates the selective hydrogenation to yield fatty alcs. The catalyst stability was also investigated, and the catalyst deactivation is mainly ascribed to the carbonaceous deposit.

Applied Catalysis, B: Environmental published new progress about Adsorption. 111-11-5 belongs to class esters-buliding-blocks, name is Methyl octanoate, and the molecular formula is C9H18O2, SDS of cas: 111-11-5.

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

Khan, Ihtisham Wali published the artcileBiodiesel production by valorizing waste non-edible wild olive oil using heterogeneous base catalyst: Process optimization and cost estimation, Application In Synthesis of 111-11-5, the main research area is biodiesel valorizing waste wild olive oil heterogeneous base catalyst.

The current research investigates sustainable biodiesel production from non-edible wild olive oil via novel Na/SiO2/TiO2 heterogeneous catalyst. The catalyst was synthesized by Sol-Gel and wet impregnation method. Furthermore, the designed catalyst was evaluated by various spectroscopic techniques like SEM, EDX, XPS, FTIR, BET and XRD. The impact of various influencing parameters such as catalyst loading, reaction temperature, oil/methanol molar ratio and reaction time were scrutinized and the maximum 97% yield was achieved at the reaction conditions of 1:20 WOSO/MeOH molar ratio, 9 wt% catalyst loading at 70°C and 120 min of reaction time. The synthesized biodiesel was confirmed from GC-MS anal., whereas the various physiochem. properties of synthesized biodiesel were explored by ASTMD 5761 and EN 1404 methods. The plausible reaction mechanism of Na/SiO2/TiO2 catalyzed WOSO was also proposed. Finally, the cost estimation of the designed catalyst investigates its com. viability for low cost biodiesel production using non-edible WOSO feedstock.

Fuel published new progress about Adsorption. 111-11-5 belongs to class esters-buliding-blocks, name is Methyl octanoate, and the molecular formula is C9H18O2, Application In Synthesis of 111-11-5.

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

Soudagar, Manzoore Elahi. M. published the artcileThe effects of graphene oxide nanoparticle additive stably dispersed in dairy scum oil biodiesel-diesel fuel blend on CI engine: performance, emission and combustion characteristics, Product Details of C9H18O2, the main research area is graphene oxide nanoparticle biodiesel diesel blend engine combustion emission.

In the present investigation, the effects of graphene oxide nanoparticles on performance and emissions of a CI engine fueled with dairy scum oil biodiesel was studied. Nanofuel blend was prepared by dispersing graphene oxide in varying quantities in dairy scum oil Me ester (DSOME)-diesel blend. Sodium dodecyl sulfate (SDS) was used as a surfactant for a steady dispersion of graphene oxide nanoparticles in the fuel blends. The dispersion and homogeneity were characterized by UV-visible spectrometry. An ideal graphene-to-surfactant ratio was defined, highest absolute value UV-absorbency was seen for a mass fraction of 1:4. The concentration of surfactant above or below this ratio resulted in reduction in the stability of dispersion. Graphene oxide nanoparticles were amalgamated with dairy scum oil biodiesel at proportions of 20, 40 and 60 ppm using ultrasonication technique. Experiments were performed at a constant speed and varying the brake power and load condtions. The results were notable enhancements in the performance and emissions characteristics, the brake thermal efficiency improved by 11.56%, a reduction in brake specific fuel consumption by 8.34%, unburnt hydrocarbon by 21.68%, smoke by 24.88%, carbon monoxide by 38.662% for the nanofuel blend DSOME2040 and oxides of nitrogen emission by 5.62% for fuel DSOME(B20). Similarly, the addition of graphene nanoparticles in DSOME fuel blends resulted in significant reduction in the combustion duration, ignition delay period, improvement in the peak pressure and heat release rate at maximum load condition. Finally, it is concluded that nano-graphene oxide nanoparticles can be introduced as a suitable substitute fuel additive for dairy scum oil biodiesel blends to enhance the overall engine performance and emissions characteristics.

Fuel published new progress about Absorption. 111-11-5 belongs to class esters-buliding-blocks, name is Methyl octanoate, and the molecular formula is C9H18O2, Product Details of C9H18O2.

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

Morales, M. L. published the artcileVolatile metabolites produced by different flor yeast strains during wine biological ageing, Product Details of C9H18O2, the main research area is volatile metabolite yeast strain wine biol aging; Flor yeast; GC-MS analysis; Heatmap; Sherry wine; Volatile compound.

Sherry white wine called Fino is produced by dynamic biol. ageing under the action of flor yeasts using traditional practices aimed at ensuring uniform quality and characteristics over time. These kinds of yeasts provide typical sensory properties to Fino wines. Although there are studies of the volatile composition of these wines submitted to biol. ageing in wood barrels, there is a lack of knowledge on the particular volatile profile produced by different flor yeast strains from Sherry zone wineries. For this reason, the aim of this study was to analyze the volatile profiles produced by 15 pure culture flor velum yeasts, with the goal of observing their suitability for obtaining high quality Fino sherry wines. Volatile composition was determined by dual sequential stir bar sorptive extraction, followed by GC-MS anal. All yeast strains studied produced the increase of most acetals, highlighting acetaldehyde diethylacetal which was the compound that most increased. Among terpenes, nerolidol and farnesol underwent remarkable increases. However, results showed that in a month of biol. ageing, significant differences were observed among the volatile metabolites produced by flor yeast strains studied. Only some of them stood out for their high production of volatile compounds characteristic of Sherry Fino wines, which are good candidates for producing starter cultures.

Food Research International published new progress about Metabolites. 111-11-5 belongs to class esters-buliding-blocks, name is Methyl octanoate, and the molecular formula is C9H18O2, Product Details of C9H18O2.

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

Lei, Lyu published the artcileBio-modified rubberized asphalt binder: A clean, sustainable approach to recycle rubber into construction, Application of Methyl octanoate, the main research area is recycle rubber biomodified rubberized asphalt binder.

This paper introduces a hybrid utilization of scrap tires and bio-oil made from biomass waste to create bio-modified rubberized asphalt for use in roadway construction. This in turn promotes clean and sustainable manufacturing while enhancing resource conservation and durability of pavements. The durability of pavements is impacted by the resistance of their asphalt binder to moisture damage and aging. This study examines the moisture resistance of bio-modified rubberized asphalt when exposed to thermal aging and UV aging. Study results show that thermal aging significantly weakens the cohesive properties of rubberized asphalt binder, while UV aging reduces its adhesive properties when exposed to water. Bio-modification of rubberized asphalt binder was found to be effective to improve resistance to cohesive damage by three times based on the rheol. test, and resistance to adhesive damage by 70% as measured by the moisture-induced shear-thinning index. The observed improvement is attributed to the bio-oil’s role as a sacrificial agent, delaying the reaction of free radicals and asphalt. Also, computational modeling shows that bio-oil mols. supersede asphalt mols. in adsorption to stones aggregates creating a stable bridge between stone and asphalt. The outcome of this study promotes clean and sustainable manufacturing while turning two waste streams (rubber and biomass waste) into a product (bio-modified rubber) in support of resource conservation and sustainability.

Journal of Cleaner Production published new progress about Absorption. 111-11-5 belongs to class esters-buliding-blocks, name is Methyl octanoate, and the molecular formula is C9H18O2, Application of Methyl octanoate.

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

Mezo, Emerencia published the artcileThe role of ionic liquid interaction in the separation of fatty acid methyl esters-polyunsaturated geometric isomers in GC-MS, Recommanded Product: Methyl octanoate, the main research area is fatty acid methyl ester ionic liquid chromatog column interaction.

Knowledge of the type and level of saturated and unsaturated fatty acids in food and clin. matrixes is of practical importance, but the wide variety of fatty acids makes analyses very complex. The discrimination of the geometric isomers of fatty acid needs proper and effective separation conditions. The efficiency of three different stationary phases was evaluated by GC-MS methods in the separation of fatty acids in their Me ester forms. Significant differences were observed in the efficiencies of polysiloxane-based (non-polar HP-5MS and medium/high polarity DB-225MS) and ionic liquid-based (SLB-IL111) columns. Baseline separation of the geometric isomers of linoleic acid Me ester was obtained by the extremely polar SLB-IL111 column, showing a preference over the other two columns. The optimization of the exptl. conditions (response linearity, limit of detection, limit of quantification, system suitability, intraday and interday repeatability and accuracy) showed the separation power of the ionic liquid interaction in the analyses by using short (25-30 m long) columns. By deducting the general principles of the interaction, predictions can be made for the separation of other isomers. The results facilitate the precise identification of various types of fatty acids in real samples for nutritional information.

Separations published new progress about Calibration. 111-11-5 belongs to class esters-buliding-blocks, name is Methyl octanoate, and the molecular formula is C9H18O2, Recommanded Product: Methyl octanoate.

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

Ramsey, Imogen published the artcileAssessing the sensory and physicochemical impact of reverse osmosis membrane technology to dealcoholize two different beer styles, Computed Properties of 111-11-5, the main research area is beer dealcoholization sensory physicochem impact reverse osmosis membrane technol; Dealcoholization; Non-alcoholic beer; Physicochemical; Reverse osmosis; Sensory.

A pilot scale dealcoholisation unit fitted with reverse osmosis (RO) membranes was used to directly compare two beer matrixes (stout, lager, ∼ 5% ABV) and their dealcoholized counterparts (∼0.5% ABV), for physicochem. properties (volatiles, pH, ABV, polyphenols, bitterness) and sensory profiles using a trained descriptive panel (n = 12). The efficiency and consistency of RO membranes were evaluated by replicate dealcoholisation trials (n = 3) for each beer. Statistical anal. revealed significant reductions (p < 0.05) in key volatile compounds with linear structures (Et octanoate, octan-1-ol) compared to those with increased levels of branching (3-methylbutyl acetate, 2-methylpropan-1-ol). Significant reductions (p < 0.0001) in fruity/estery, alc./solvent, malty, sweetness and body sensory attributes were also discovered. Finally, longer processing times for the stout across replicate trials suggested membrane clogging, while differences in volatile reduction suggested membrane fouling. This novel research proposes compound structure, rather than compound size, impacts RO membrane permeability and resulting sensory quality. Food Chemistry: X published new progress about Beer. 111-11-5 belongs to class esters-buliding-blocks, name is Methyl octanoate, and the molecular formula is C9H18O2, Computed Properties of 111-11-5.

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics