Category: 111-11-5

Zhang, Guoqi published the artcileRedox-Noninnocent Ligand-Supported Vanadium Catalysts for the Chemoselective Reduction of C=X (X = O, N) Functionalities, Safety of Methyl octanoate, the main research area is vanadium ligand catalyst reduction ketone aldehyde imine ester carboxamide.

Catalysis is the second largest application for V after its use as an additive to improve steel production Mol. complexes of vanadium(V) are particularly useful and efficient catalysts for oxidation processes; however, their ability to catalyze reductive transformations has yet to be fully explored. Here the authors report the first examples of polar organic functionality reduction mediated by V. Open-shell VIII complexes that feature a π-radical monoanionic 2,2′:6′,2”-terpyridine ligand (Rtpyâ€?- functionalized at the 4′-position (R = (CH3)3SiCH2, Ph) catalyze mild and chemoselective hydroboration and hydrosilylation of functionalized ketones, aldehydes, imines, esters, and carboxamides with turnover numbers (TONs) of up to âˆ?000 and turnover frequencies (TOFs) of up to âˆ?00 h-1. Computational evaluation of the precatalyst synthesis and activation revealed underappreciated complexity associated with the redox-active tpy chelate.

Journal of the American Chemical Society published new progress about Aldehydes Role: RCT (Reactant), RACT (Reactant or Reagent). 111-11-5 belongs to class esters-buliding-blocks, name is Methyl octanoate, and the molecular formula is C9H18O2, Safety of Methyl octanoate.

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

Tang, Bo published the artcileA β-cyclodextrin covalent organic framework used as a chiral stationary phase for chiral separation in gas chromatography, Product Details of C9H18O2, the main research area is cyclodextrin covalent organic framework chiral stationary phase gas chromatog.

Chiral covalent organic frameworks (CCOFs) featuring chirality, stability, and good porosity have attracted a considerable amount of attention due to their important applications, such as asym. catalysis, chiral separation, and chiral recognition. In this study, a β-cyclodextrin (β-CD) covalent organic framework (β-CD-COF) diluted with polysiloxane OV-1701 was explored as a novel chiral stationary phase (CSP) for gas chromatog. (GC) separation of racemates. The β-CD-COF coated capillary column had excellent selectivity, not only for the separation of linear alkanes, linear alcs., fatty acid Me esters mixture, the Grob mixture and positional isomers, but also for the resolution of chiral compounds, including chiral alcs., aldehydes, ethers, and amino acid derivatives In addition, the β-CD-COF-coated capillary column presented good repeatability and reproducibility. This work indicated the great potential of the CCOFs coated capillary column for the chromatog. separation of enantiomers.

Chinese Chemical Letters published new progress about Alcohols, chiral Role: ANT (Analyte), ANST (Analytical Study). 111-11-5 belongs to class esters-buliding-blocks, name is Methyl octanoate, and the molecular formula is C9H18O2, Product Details of C9H18O2.

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

Balachandran, S. published the artcileEnhancement of aqueous solubility and extraction of lauric acid using hydrotropes and its interaction studies by COSMO-RS model, Category: esters-buliding-blocks, the main research area is enhancement aqueous solubility extraction lauric acid hydrotrope.

In this study, conductor like screening model for real solvents was used to analyze the ability of hydrogen bond donor, hydrogen bond acceptor and electron affinity of all the studied species such as water, lauric acid (LA), sodium benzoate (SB), sodium salicylate (SS), nicotinamide (NI), and urea (UA). Further, the different hydrotropes solutions were prepared with different concentrations (0-3.0 mol/L) in order to analyze the solubility of lauric acid at different temperatures (303-313 K). Subsequently, hydrotropes based extraction of lauric acid from cold press coconut oil (CPCO) and com.-grade edible coconut oil (CGECO) was conducted at 313 K and 0.1 MPa. GC-MS anal. has been carried out on cold press coconut oil, com. grade edible coconut oil and hydrotropically extracted samples to characterize the different fatty acid compounds present in it. It was observed that the sodium benzoate hydrotrope solution extracted samples has lauric acid as a significant component in the GC-MS spectra when compared to the extracted samples of sodium salicylate hydrotrope solution

Journal of Dispersion Science and Technology published new progress about Coconut oil Role: NUU (Other Use, Unclassified), USES (Uses). 111-11-5 belongs to class esters-buliding-blocks, name is Methyl octanoate, and the molecular formula is C9H18O2, Category: esters-buliding-blocks.

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

Feng, Xuanyu published the artcileAluminum Hydroxide Secondary Building Units in a Metal-Organic Framework Support Earth-Abundant Metal Catalysts for Broad-Scope Organic Transformations, Application In Synthesis of 111-11-5, the main research area is metal organic framework catalyst organic transformation.

The intrinsic heterogeneity of alumina (Al2O3) surface presents a challenge for the development of alumina-supported single-site heterogeneous catalysts and hinders the characterization of catalytic species at the mol. level as well as the elucidation of mechanistic details of the catalytic reactions. Here we report the use of aluminum hydroxide secondary building units (SBUs) in the MIL-53(Al) metal-organic framework (MOF) with the formula Al(μ2-OH)(BDC) (BDC = 1,4-benzenedicarboxylate) as a uniform and structurally defined functional mimic of Al2O3 surface for supporting Earth-abundant metal (EAM) catalysts. The μ2-OH groups in MIL-53(Al) SBUs were readily deprotonated and metalated with CoCl2 and FeCl2 to afford MIL-53(Al)-CoCl and MIL-53(Al)-FeCl precatalysts which were characterized by powder X-ray diffraction, nitrogen sorption, elemental anal., d. functional theory, and extended X-ray fine structure spectroscopy. Activation with NaBEt3H converted MIL-53(Al)-CoCl to MIL-53(Al)-CoH which effectively catalyzed hydroboration of alkynes and nitriles and hydrosilylation of esters. XPS and X-ray absorption near-edge spectroscopy (XANES) indicated the presence of AlIII and CoII centers in MIL-53(Al)-CoH while deuterium labeling studies suggested σ-bond metathesis as a key step for the MIL-53(Al)-CoH-catalyzed addition reactions. MIL-53(Al)-FeCl competently catalyzed oxidative Csp3-H amination and Wacker-type alkene oxidation XANES anal. revealed the oxidation of FeII to FeIII centers in the activated MIL-53(Al)-FeCl catalyst and suggested that oxidative Csp3-H amination occurs via the formation of FeIII-OtBu species by single electron transfer between FeII centers in MIL-53(Al)-FeCl and (tBuO)2 with concomitant generation of 1 equiv of tBuO· radical, C-H activation through hydrogen atom abstraction to generate alkyl radicals, protonation of FeIII-OtBu by aniline to generate MIL-53(Al)-FeIII-anilide, and finally C-N coupling between the FeIII-anilide and alkyl radical to form the Csp3-H amination product and regenerate the FeII catalyst. These highly active single-site MOF-based solid catalysts were readily recovered and reused up to five times without significant decrease in catalytic activity. This work thus demonstrates the great potential of using the aluminum hydroxide SBUs in MOFs to support EAM catalysts for important organic transformations.

ACS Catalysis published new progress about Alcohols Role: SPN (Synthetic Preparation), PREP (Preparation). 111-11-5 belongs to class esters-buliding-blocks, name is Methyl octanoate, and the molecular formula is C9H18O2, Application In Synthesis of 111-11-5.

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

Sousa, Sara C. A. published the artcileBench-Stable Manganese NHC Complexes for the Selective Reduction of Esters to Alcohols with Silanes, HPLC of Formula: 111-11-5, the main research area is alc preparation chemoselective; ester reduction manganese catalyst.

Selective reduction of esters to alcs. RCH2OH [R = cyclohexyl, Ph, 4-ClC6H4, etc.] was accomplished through Mn(I)-mediated hydrosilylation reaction. The manganese tricarbonyl complex [Mn(bis-NHC)(CO)3Br] resulted an active pre-catalyst for the reduction of a variety of esters using phenylsilane and the cheap and readily available polymethylhydrosiloxane.

Advanced Synthesis & Catalysis published new progress about Alcohols Role: SPN (Synthetic Preparation), PREP (Preparation). 111-11-5 belongs to class esters-buliding-blocks, name is Methyl octanoate, and the molecular formula is C9H18O2, HPLC of Formula: 111-11-5.

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

Wang, Xin published the artcileSystematic study of the material, structure and lacquering techniques of lacquered wooden coffins from the Eastern Regius Tombs of the Qing Dynasty, China, SDS of cas: 111-11-5, the main research area is mercury sulfide lacquered wooden coffin lacquering pigment.

This paper presents a series of detailed anal. results from lacquered wooden coffins of Emperor Qianlong’s concubines (Huixian, Shujia) and second empress (Wulanala) excavated from the Eastern Regius Tombs of the Qing Dynasty, China. The anal. is focused on the materials used in the lacquered wooden coffins, specifically investigating the pigments, lacquers, organic additives and lacquering techniques using digital microscopy, SEM-EDS, XRD, micro-Raman spectroscopy, FT-IR and THM-Py-GC/MS. The results demonstrate that the mineral pigments were mainly HgS, As2S3, the golden area in the lacquer film layers mainly contained elements Au and Ag, the lacquer ash layers mainly included several layers of stucco and fiber layers arranged alternately, the lacquer sap was urushi, and heat-bodied tung oil was also present in the lacquer. Furthermore, several kinds of lacquering techniques, which demonstrated traditional Chinese lacquering and the rigid hierarchy of funerals in feudal dynasties, are also identified in this investigation.

Microchemical Journal published new progress about Attenuated-total-reflectance Fourier-transform IR spectroscopy. 111-11-5 belongs to class esters-buliding-blocks, name is Methyl octanoate, and the molecular formula is C9H18O2, SDS of cas: 111-11-5.

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

He, Yongrui published the artcileSeparation performance of a new triptycene-based stationary phase with polyethylene glycol units and its application to analysis of the essential oil of Osmanthus fragrans Lour, Recommanded Product: Methyl octanoate, the main research area is Osmanthu essential oil gase chromatog stationary phase triptycene PEG; Essential oil; Gas chromatography; Operational temperature range; Structural and positional isomers; Triptycene-based stationary phase.

This work presents a new triptycene-based stationary phase (TP-PEG) combining the three-dimensional (3D) triptycene (TP) framework with polyethylene glycol (PEG) moieties for gas chromatog. (GC) separations Its statically coated capillary column showed high column efficiency of 5263 plates/m determined by naphthalene at 120°C. Its Rohrschneider-McReynolds constants and Abraham solvation system constants were measured to characterize its polarity and mol. interactions with analytes of different types. As evidenced, the TP-PEG column showed high-resolution performance for the isomers of anilines, phenols, halobenzenes and alkanes with distinct advantages over the PEG columns, particularly those critical isomers such as 3,5-/2,3-xylidine (R = 2.94), m-/p-chlorotoluene (R = 1.92), p-/m-cresol (R = 1.89), 2,2-dimethylbutane/2-methylpentane (R = 1.51), 2,2,3-trimethylbutane /2,3-dimethyl pentane (R = 1.74) and 2,3-dimethylpentane/n-heptane (R = 1.92). In addition, it exhibited good column repeatability and reproducibility with the relative standard deviation (RSD) values of 0.02%-0.09% for run-to-run, 0.13%-0.22% for day-to-day and 2.7%-4.1% for column-to-column, resp., and a wide operational temperature range (30°C-280°C) . Its application to GC-MS anal. of the essential oil of Osmanthus fragrans has proven its good potential for practical anal. of complex samples.

Journal of Chromatography A published new progress about Alkanes Role: PUR (Purification or Recovery), PREP (Preparation). 111-11-5 belongs to class esters-buliding-blocks, name is Methyl octanoate, and the molecular formula is C9H18O2, Recommanded Product: Methyl octanoate.

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

Shao, Yan published the artcileComposition and profiles of volatile organic compounds during waste decomposition by the anaerobic bacteria purified from landfill, Application In Synthesis of 111-11-5, the main research area is volatile organic compound waste decomposition anaerobic bacteria landfill; Anaerobic bacteria; Concentration variation; Landfill gas; VOCs; Waste degradation.

Volatile organic compounds (VOCs) become concerned pollutants in landfill gases, and their composition and concentration varied significantly during waste decomposition Many environmental factors are known to affect VOC emissions, while the effect of indigenous bacteria in wastes on VOC production remains elusive. In this study, a simplified anaerobic degradation experiment, with the single substrate and the purified bacteria from a landfill, was set up to measure the degradation process and the dynamic changes of VOCs. The experiment excluded the abiotic factors for VOC variation. The two isolated bacteria, identified as Sporanaerobacter acetigenes and Clostridium sporogenes, could anaerobically ferment amino acids by Stickland reaction. They produced 51 and 57 species of VOCs in the experiment, resp. The concentration changes of VOCs over bacterial growth and fermentation were clustered into four types by principal component anal.: three profiles were regular, similar to the variation of nitrate, hydrogen sulfide, and the major fermentation products (carbon dioxide, ammonium, and volatile organic acids), resp.; while one profile was unique to any degradation indicator. The various concentration profiles indicated different origins for VOCs, possibly from the extracellular environment, fermentation, and secondary reactions. The findings provide insights into the understanding of VOC diversity and variability during waste decomposition

Waste Management (Oxford, United Kingdom) published new progress about Amino acids Role: OCU (Occurrence, Unclassified), OCCU (Occurrence). 111-11-5 belongs to class esters-buliding-blocks, name is Methyl octanoate, and the molecular formula is C9H18O2, Application In Synthesis of 111-11-5.

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

Niu, Yunwei published the artcileEvaluation of the perceptual interaction among ester aroma compounds in cherry wines by GC-MS, GC-O, odor threshold and sensory analysis: An insight at the molecular level, HPLC of Formula: 111-11-5, the main research area is wine ester aroma compound; Aroma intensity; Ester compounds; Olfactory threshold; Perceptual interaction.

The ester aroma profiles of five Chinese cherry wines and the perceptual interaction among esters were investigated in this study. 24 esters were identified by Gas chromatog.-olfactometry (GC-O) and Gas Chromatog.-Mass Spectrometer (GC-MS). According to addition/omission anal., seven volatile compounds among them were selected and studied using sensory profiling and multivariate statistic methods such as Principal Component Anal. (PCA). In sensory anal., a significant reduction of olfactory threshold for total aromatic reconstitution was induced by the addition among each of them in Feller’s additive model, which demonstrated their synergistic effects. The σ/τ plot showed that most of them were followed by a partial addition behavior. Furthermore, PCA indicated that the addition among each of them had a significant effect on fruity, floral, sweet and fermentation aroma intensity. Specifically, Et decanoate and Me salicylate at sub-threshold concentrations were also likely to contribute to overall aroma. The results of perceptual interaction were mainly influenced by chem. structure and mol. polarity.

Food Chemistry published new progress about Esters Role: ANT (Analyte), PRP (Properties), ANST (Analytical Study). 111-11-5 belongs to class esters-buliding-blocks, name is Methyl octanoate, and the molecular formula is C9H18O2, HPLC of Formula: 111-11-5.

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

Das, Uttam Kumar published the artcileDehydrogenative Cross-Coupling of Primary Alcohols To Form Cross-Esters Catalyzed by a Manganese Pincer Complex, SDS of cas: 111-11-5, the main research area is primary alc manganese pincer complex catalyst dehydrogenative cross coupling; cross ester preparation.

Base-metal-catalyzed dehydrogenative cross-coupling of primary alcs. to form cross-esters as major products, liberating hydrogen gas, is reported. The reaction is catalyzed by a pincer complex of earth-abundant manganese in the presence of catalytic base, without any hydrogen acceptor or oxidant. Mechanistic insight indicates that a dearomatized complex is the actual catalyst, and indeed this independently prepared dearomatized complex catalyzes the reaction under neutral conditions.

ACS Catalysis published new progress about Carboxylic esters Role: SPN (Synthetic Preparation), PREP (Preparation). 111-11-5 belongs to class esters-buliding-blocks, name is Methyl octanoate, and the molecular formula is C9H18O2, SDS of cas: 111-11-5.

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics