Category: 103-25-3

In 2019.0 ASIAN J ORG CHEM published article about DONOR-ACCEPTOR CYCLOPROPANES; DIELS-ALDER REACTIONS; DIASTEREOSELECTIVE SYNTHESIS; THIOCARBONYL COMPOUNDS; DERIVATIVES; CYCLIZATION; RING in [Matsumoto, Yohei; Tsuji, Taro; Nakatake, Daiki; Yazaki, Ryo; Ohshima, Takashi] Kyushu Univ, Grad Sch Pharmaceut Sci, Maidashi Higashi Ku, Fukuoka, Fukuoka 8128582, Japan in 2019.0, Cited 35.0. The Name is Methyl 3-phenylpropionate. Through research, I have a further understanding and discovery of 103-25-3. Quality Control of Methyl 3-phenylpropionate

The utility of thionoester as a 1,2-dipolarophile for [4+2] cycloaddition with cyclobutanones is described. The [4+2] cycloaddition reaction provided tetrahydrothiopyran, which is found in biologically active natural products, in high yield with high diastereoselectivity by using readily available TiCl4. This synthetic method was applicable to a wide range of thionoesters and cyclobutanones. The ketone and S,O-ketal functionalities of the product could be reduced with excellent diastereoselectivity. Furthermore, the C-O bond was transformed into a C-C bond, affording contiguous tetrasubstituted carbon centers.

Quality Control of Methyl 3-phenylpropionate. About Methyl 3-phenylpropionate, If you have any questions, you can contact Matsumoto, Y; Tsuji, T; Nakatake, D; Yazaki, R; Ohshima, T or concate me.

Reference:
Patent; SANOFI; US2011/294788; (2011); A1;,
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

Yang, JF; Sekiguchi, Y; Yoshikai, N in [Yang, Junfeng; Sekiguchi, Yoshiya; Yoshikai, Naohiko] Nanyang Technol Univ, Sch Phys & Math Sci, Div Chem & Biol Chem, Singapore 637371, Singapore; [Yang, Junfeng] Fudan Univ, Dept Chem, 2005 Songhu Rd, Shanghai 2000438, Peoples R China published Cobalt-Catalyzed Enantioselective and Chemodivergent Addition of Cyclopropanols to Oxabicyclic Alkenes in 2019.0, Cited 71.0. Category: esters-buliding-blocks. The Name is Methyl 3-phenylpropionate. Through research, I have a further understanding and discovery of 103-25-3.

We report herein cobalt-catalyzed enantioselective and chemodivergent reactions between a cyclopropanol and an oxabicyclic alkene via a cobalt homoenolate, which afford either an alkylative ring-opening product or a hydroalkylation product, with the counterion of the cobalt catalyst being a major chemoselectivity-controlling factor. A catalyst generated from cobalt(II) chloride and a chiral diphosphine promotes alkylative ring opening to afford 1,2-dihydronaphthalen-1-ol derivatives in good yields with high enantioselectivity. By contrast, a catalyst generated from cobalt(II) acetate and the same diphosphine ligand, with the assistance of methanol, selectively affords hydroalkylation products with retention of the bicyclic structure at a comparable level of enantioselectivity.

Category: esters-buliding-blocks. About Methyl 3-phenylpropionate, If you have any questions, you can contact Yang, JF; Sekiguchi, Y; Yoshikai, N or concate me.

Reference:
Patent; SANOFI; US2011/294788; (2011); A1;,
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

Formula: C10H12O2. In 2019.0 ORG LETT published article about CATALYZED CARBONYLATIVE SYNTHESIS; BENZYLIC AMINES; CROSS-COUPLINGS; ALKYL IODIDES; FUNCTIONALIZATION; TRANSFORMATIONS; HETEROCYCLES; RADICALS; ALCOHOLS in [Li, Chong-Liang; Wu, Xiao-Feng] Zhejiang Sci Tech Univ, Dept Chem, Xiasha Campus, Hangzhou 310018, Peoples R China; [Li, Chong-Liang; Wu, Xiao-Feng] Univ Rostock, Leibniz Inst Katalyse eV, Albert Einstein Str 29a, D-18059 Rostock, Germany; [Jiang, Xuan; Lu, Liang-Qiu; Xiao, Wen-Jing] Cent China Normal Univ, Coll Chem, Minist Educ, Key Lab Pesticide & Chem Biol, 152 Luoyu Rd, Wuhan 430079, Hubei, Peoples R China in 2019.0, Cited 51.0. The Name is Methyl 3-phenylpropionate. Through research, I have a further understanding and discovery of 103-25-3.

The first cobalt-catalyzed deaminative alkoxycarbonylation reaction was described for the conversion of readily available primary alkyl amines to synthetically versatile esters with moderate to high yields. This transformation shows good functional group compatibility and can serve as a powerful tool for the modification of alkyl amine-containing complex natural products and drug molecules.

About Methyl 3-phenylpropionate, If you have any questions, you can contact Li, CL; Jiang, X; Lu, LQ; Xiao, WJ; Wu, XF or concate me.. Formula: C10H12O2

Reference:
Patent; SANOFI; US2011/294788; (2011); A1;,
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

Recommanded Product: Methyl 3-phenylpropionate. In 2020.0 J ORG CHEM published article about COUPLING REACTION; HYDROCARBONS; HALOGENATION; ACID; HALIDES; MILD; 9-MESITYL-10-METHYLACRIDINIUM; SUCCINIMIDYL; COMPLEXES; OXIDATION in [Xiang, Ming; Zhou, Chao; Yang, Xiu-Long; Chen, Bin; Tung, Chen-Ho; Wu, Li-Zhu] Chinese Acad Sci, Tech Inst Phys & Chem, Key Lab Photochem Convers & Optoelect Mat, Beijing 100190, Peoples R China; [Xiang, Ming; Zhou, Chao; Yang, Xiu-Long; Chen, Bin; Tung, Chen-Ho; Wu, Li-Zhu] Chinese Acad Sci, Univ Chinese Acad Sci, Beijing 100190, Peoples R China; [Xiang, Ming; Zhou, Chao; Yang, Xiu-Long; Chen, Bin; Tung, Chen-Ho; Wu, Li-Zhu] Univ Chinese Acad Sci, Sch Future Technol, Beijing 100049, Peoples R China in 2020.0, Cited 48.0. The Name is Methyl 3-phenylpropionate. Through research, I have a further understanding and discovery of 103-25-3.

By combining N-chlorosuccinimide (NCS)” as the safe chlorine source with Acr(+)-Mes as the photocatalyst, we successfully achieved benzylic C-H bond chlorination under visible light irradiation. Furthermore, benzylic chlorides could be converted to benzylic ethers smoothly in a one-pot manner by adding sodium methoxide. This mild and scalable chlorination method worked effectively for diverse toluene derivatives, especially for electron-deficient substrates. Careful mechanistic studies supported that NCS provided a hydrogen abstractor N-centered succinimidyl radical, which was responsible for the cleavage of the benzylic C-H bond, relying on the reducing ability of Acr(center dot)-Mes.

About Methyl 3-phenylpropionate, If you have any questions, you can contact Xiang, M; Zhou, C; Yang, XL; Chen, B; Tung, CH; Wu, LZ or concate me.. Recommanded Product: Methyl 3-phenylpropionate

Reference:
Patent; SANOFI; US2011/294788; (2011); A1;,
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

An article Trizaine-based dehydrative condensation reagents bearing carbon-substituents WOS:000518870900002 published article about TRIAZINES; AMINES in [Kitamura, Masanori; Komine, Sayaka; Yamada, Kohei; Kunishima, Munetaka] Kanazawa Univ, Fac Pharmaceut Sci, Inst Med Pharmaceut & Hlth Sci, Kakuma Machi, Kanazawa, Ishikawa 9201192, Japan in 2020.0, Cited 24.0. The Name is Methyl 3-phenylpropionate. Through research, I have a further understanding and discovery of 103-25-3. Recommanded Product: Methyl 3-phenylpropionate

Herein, we report on the synthesis of alkyl-, aryl-, and alkynyl-substituted chlorotriazines and their ammonium salts, and demonstrate their utility in dehydrative condensation reactions. Although the electrophilicity of these reagents is mainly dependent on the hybridization of the carbon-substituents, it was found that bulky 2,6-dimethylphenyl group-substituted reagents resulted in the highest product yields because of a slight increase in reagent electrophilicity and/or steric hindrance favorable for desired dehydrative condensation reactions. (C) 2019 Elsevier Ltd. All rights reserved.

Recommanded Product: Methyl 3-phenylpropionate. About Methyl 3-phenylpropionate, If you have any questions, you can contact Kitamura, M; Komine, S; Yamada, K; Kunishima, M or concate me.

Reference:
Patent; SANOFI; US2011/294788; (2011); A1;,
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

An article Diversion of the Arbuzov reaction: alkylation of C-Cl instead of phosphonic ester formation on the fullerene cage WOS:000477986000022 published article about CHLOROFULLERENE C60CL6; DERIVATIVES; VIRUS; FUNCTIONALIZATION; INHIBITION; CHEMISTRY; BIOLOGY; C-60; 1ST in [Kraevaya, Ol’ga A.; Troshin, Pavel A.] Skolkovo Inst Sci & Technol, Nobel St 3, Moscow 143026, Russia; [Kraevaya, Ol’ga A.; Martynenko, Vyacheslav M.; Shestakov, Alexander F.; Troshin, Pavel A.] RAS, IPCP, Semenov Prospect 1, Chernogolovka 141432, Russia; [Peregudov, Alexander S.; Godovikov, Ivan] RAS, INEOS, Vavylova St 28,B-334, Moscow 119991, Russia; [Troyanov, Sergey I.] Moscow Lomonosov State Univ, Dept Chem, Moscow, Russia; [Fedorova, Natalya E.; Klimova, Regina R.; Kushch, Alla A.] Minist Hlth Russian Federat, Honored Academcian NF Gamaleya Natl Res Ctr Epide, Gamaleya St 18, Moscow 123098, Russia; [Sergeeva, Vasilina A.; Kameneva, Larisa V.; Ershova, Elizaveta S.; Kostyuk, Svetlana V.] RAMS, Res Ctr Med Genet, Moskvoreche St 1, Moscow 115478, Russia; [Claes, Sandra; Schols, Dominique] Katholieke Univ Leuven, Rega Inst Med Res, Herestr 49, B-3000 Leuven, Belgium; [Shestakov, Alexander F.] Moscow Lomonosov State Univ, Fac Fundamental Phys & Chem Engn, GSP 1,1-51 Leninskie Gory, Moscow 119991, Russia in 2019.0, Cited 43.0. The Name is Methyl 3-phenylpropionate. Through research, I have a further understanding and discovery of 103-25-3. COA of Formula: C10H12O2

We report an inversed Arbuzov reaction of the fullerene derivatives C60Ar5Cl with trialkyl phosphites P(OR)(3) producing alkylated fullerene derivatives C60Ar5R (R = Me, Et, iPr, nBu) with almost quantitative yields. This reaction provides a convenient synthetic route for the preparation of a large variety of functionalized fullerene derivatives with tailored properties, e.g. water-soluble compounds demonstrating promising antiviral activities against HCMV, HSV1, HIV and several influenza virus strains.

COA of Formula: C10H12O2. About Methyl 3-phenylpropionate, If you have any questions, you can contact Kraevaya, OA; Peregudov, AS; Troyanov, SI; Godovikov, I; Fedorova, NE; Klimova, RR; Sergeeva, VA; Kameneva, LV; Ershova, ES; Martynenko, VM; Claes, S; Kushch, AA; Kostyuk, SV; Schols, D; Shestakov, AF; Troshin, PA or concate me.

Reference:
Patent; SANOFI; US2011/294788; (2011); A1;,
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

An article CuO-catalyzed oxidation of aryl acetates with aqueous tert-butyl hydroperoxide for the synthesis of alpha-ketoesters WOS:000484663600003 published article about KETO ESTERS; ALKYLBENZENES; KETOAMIDES in [Jiang, Jin] Sichuan Univ Sci & Engn, Sch Chem & Environm Engn, Zigong 643000, Peoples R China in 2019.0, Cited 21.0. Formula: C10H12O2. The Name is Methyl 3-phenylpropionate. Through research, I have a further understanding and discovery of 103-25-3

A practical method to access alpha-ketoesters from readily available aryl acetates is developed. In this approach, aqueous tert-butyl hydroperoxide and CuO are employed. No additional solvents are required and it was found that the peroxide side products in the reaction can be decomposed by pyridine.

Formula: C10H12O2. About Methyl 3-phenylpropionate, If you have any questions, you can contact Jiang, J or concate me.

Reference:
Patent; SANOFI; US2011/294788; (2011); A1;,
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

An article Celite-Polyaniline supported palladium catalyst for chemoselective hydrogenation reactions WOS:000464452800023 published article about SELECTIVE HYDROGENATION; HETEROGENEOUS CATALYST; PD NANOPARTICLES; FACILE SYNTHESIS; N-ALKYLATION; REDUCTION; ACID; EFFICIENT; SUZUKI; OXIDATION in [Patel, Heta A.; Rawat, Maitreyee; Patel, Arun L.; Bedekar, Ashutosh V.] Maharaja Sayajirao Univ Baroda, Fac Sci, Dept Chem, Vadodara 390002, India in 2019.0, Cited 110.0. The Name is Methyl 3-phenylpropionate. Through research, I have a further understanding and discovery of 103-25-3. SDS of cas: 103-25-3

Polyaniline coated on particles of celite is used as support to load palladium catalyst. This heterogenized Celite center dot PANI center dot Pd system, is used as an efficient catalyst for chemoselective hydrogenation reactions. The catalyst is characterized by usual spectral, analytical techniques and studied for hydrogenation reactions at ambient conditions. The mild reaction conditions allow the control over the reactions and excellent selectivity is achieved in number of conversions. Hydrogenation of a carbon-carbon double bond was favored over other polar pi-bond systems, while labile functional groups such as benzyl ether, benzyl esters, cyano, nitro and halogen remained unaffected. Primary amines were converted to N,N-dimethyl amines with formaldehyde, the double bond of coumarin was selectively hydrogenated without opening of the lactone functionality.

About Methyl 3-phenylpropionate, If you have any questions, you can contact Patel, HA; Rawat, M; Patel, AL; Bedekar, AV or concate me.. SDS of cas: 103-25-3

Reference:
Patent; SANOFI; US2011/294788; (2011); A1;,
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

Recently I am researching about CATALYZED METHYLATION; DIMETHYL CARBONATE; IONIC LIQUIDS; AMINES; DERIVATIVES; METHANOL; ACID; TRIFLUOROMETHYLATION; GENERATION; DIOXIDE, Saw an article supported by the Doctor Startup Project of Guangdong University of Petrochemical Technology [2017rc07]; Young Creative Talents Training Project of Guangdong University of Petrochemical Technology [2017qn27]; Science and Technology Plan of Maoming [917316]. HPLC of Formula: C10H12O2. Published in WILEY-V C H VERLAG GMBH in WEINHEIM ,Authors: Zheng, X; Zeng, JC; Xiong, MD; Huang, JW; Li, CY; Zhou, RJ; Xiao, DD. The CAS is 103-25-3. Through research, I have a further understanding and discovery of Methyl 3-phenylpropionate

A methylation reagent for compounds bearing N-H, O-H, and S-H functionalities was developed. Methyl trifluoroacetate (MTFA) was commonly considered as trifluoroacetylating reagent or trifluoromethylating reagent. In this work, we report the methylation behavior of MTFA under mild conditions with good functional group tolerance, allowing the transformation of a wide range of substrates, including N,H-heteroaromatic compounds, phenolic compounds, carboxylic acids, thiophenols, secondary amides and imides, in high yields. This method was preliminarily applied to the chemoselective methylation of bifunctionalized secondary amide.

About Methyl 3-phenylpropionate, If you have any questions, you can contact Zheng, X; Zeng, JC; Xiong, MD; Huang, JW; Li, CY; Zhou, RJ; Xiao, DD or concate me.. HPLC of Formula: C10H12O2

Reference:
Patent; SANOFI; US2011/294788; (2011); A1;,
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

Recently I am researching about CARBON-CARBON BONDS; ARYL KETONES; ACTIVATION; EXCHANGE, Saw an article supported by the Education Department of Shaanxi Provincial Government [2018JM2012]; Shaanxi Provincial Education Department [17JS129, 17JK0773]; Key Science and Technology Innovation Team of Shaanxi Province [2017KCT-37]. Name: Methyl 3-phenylpropionate. Published in WILEY-V C H VERLAG GMBH in WEINHEIM ,Authors: Jiang, C; Wu, WQ; Lu, H; Yu, TY; Xu, WH; Wei, H. The CAS is 103-25-3. Through research, I have a further understanding and discovery of Methyl 3-phenylpropionate

A Rh-III-catalyzed Hiyama cross-coupling reaction has been successfully developed. Cleavage of the less polar C-C bond provides an efficient strategy to enable ketones to be as electrophilic reagents, and the corresponding substituted indoles with diverse functional groups are efficiently synthesized in good to high yields.

About Methyl 3-phenylpropionate, If you have any questions, you can contact Jiang, C; Wu, WQ; Lu, H; Yu, TY; Xu, WH; Wei, H or concate me.. Name: Methyl 3-phenylpropionate

Reference:
Patent; SANOFI; US2011/294788; (2011); A1;,
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics