Category: 103-25-3

An article N-Heterocyclic carbene-catalyzed beta-addition of enals to 3-alkylenyloxindoles: synthesis of oxindoles with all-carbon quaternary stereocenters WOS:000474306200015 published article about ORGANOCATALYTIC MICHAEL ADDITION; 4 CONTIGUOUS STEREOCENTERS; ASYMMETRIC-SYNTHESIS; ISATYLIDENE-3-ACETALDEHYDES APPLICATION; 1,6-MICHAEL ADDITION; GAMMA-BUTYROLACTONES; CONSTRUCTION; BEARING; ACCESS; 3-METHYL-4-NITRO-5-ALKENYL-ISOXAZOLES in [Zhang, Chun-Lin; Han, You-Feng; Ye, Song] Chinese Acad Sci, Beijing Natl Lab Mol Sci, CAS Key Lab Mol Recognit & Funct, CAS Res Educ Ctr Excellence Mol Sci,Inst Chem, Beijing 100190, Peoples R China; [Han, You-Feng; Ye, Song] Univ Chinese Acad Sci, Beijing 100049, Peoples R China in 2019.0, Cited 64.0. COA of Formula: C10H12O2. The Name is Methyl 3-phenylpropionate. Through research, I have a further understanding and discovery of 103-25-3

The N-heterocyclic carbene-catalyzed beta-addition of enals to 3-alkylenyloxindoles was developed. All of the beta-aryl, beta-alkenyl and beta-alkyl enals worked well for the reaction to give the corresponding 3,3-disubstituted oxindoles bearing contiguous all-carbon quaternary and tertiary stereocenters in good yields with moderate to high diastereoselectivities and excellent enantioselectivities.

COA of Formula: C10H12O2. About Methyl 3-phenylpropionate, If you have any questions, you can contact Zhang, CL; Han, YF; Ye, S or concate me.

Reference:
Patent; SANOFI; US2011/294788; (2011); A1;,
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

COA of Formula: C10H12O2. I found the field of Chemistry very interesting. Saw the article Rh-Catalyzed Direct Carboxylation of Alkenyl C-H Bonds of Alkenylpyrazoles published in 2020.0, Reprint Addresses Iwasawa, N (corresponding author), Tokyo Inst Technol, Dept Chem, Meguro Ku, 2-12-1 O Okayama, Tokyo 1528551, Japan.. The CAS is 103-25-3. Through research, I have a further understanding and discovery of Methyl 3-phenylpropionate.

The Rh-catalyzed direct carboxylation of alkenyl C-H bonds was achieved by using pyrazole as a removable directing group. In the presence of 5 mol% RhCl3 . 3H(2)O, 6 mol% P(Mes)(3), and 2 equiv. of AlMe2(OMe), the alkenyl C-H bond of various alkenylpyrazoles was directly carboxylated in good yields under CO2 atmosphere. Furthermore, several useful transformations of the pyrazole moiety of the product were achieved to afford synthetically useful carboxylic acid derivatives in good yields.

COA of Formula: C10H12O2. About Methyl 3-phenylpropionate, If you have any questions, you can contact Saitou, T; Jin, YH; Isobe, K; Suga, T; Takaya, J; Iwasawa, N or concate me.

Reference:
Patent; SANOFI; US2011/294788; (2011); A1;,
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

Authors Liu, Z; Zhang, YS; Wei, Y; Shi, M in WILEY-V C H VERLAG GMBH published article about OXIDATIVE COUPLING REACTION; FACILE SYNTHESIS; C-H; COPPER; AMINOOXYGENATION; DIAMINATION; ANALOGS; KETONES; ACTIVATION; ANNULATION in [Liu, Zhen; Shi, Min] East China Univ Sci & Technol, Sch Chem & Mol Engn, Key Lab Adv Mat, Meilong Rd 130, Shanghai 200237, Peoples R China; [Liu, Zhen; Shi, Min] East China Univ Sci & Technol, Sch Chem & Mol Engn, Inst Fine Chem, Meilong Rd 130, Shanghai 200237, Peoples R China; [Zhang, Yan-Shun; Wei, Yin; Shi, Min] Univ Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Organometall Chem, Chinese Acad Sci,Ctr Excellence Mol Synth, 345 Lingling Rd, Shanghai 200032, Peoples R China in 2020.0, Cited 41.0. SDS of cas: 103-25-3. The Name is Methyl 3-phenylpropionate. Through research, I have a further understanding and discovery of 103-25-3

Polysubstituted imidazolinones were synthesized in a facile metal-free cascade nucleophilic cyclization of easily available amidines and 2-substituted acrylates. This protocol is distinguished by simple, mild, and catalyst-free reaction conditions with a broad substrate scope, affording the desired products in moderate to good yields and providing an efficient strategy for synthesis of polysubstituted imidazolinone.

About Methyl 3-phenylpropionate, If you have any questions, you can contact Liu, Z; Zhang, YS; Wei, Y; Shi, M or concate me.. SDS of cas: 103-25-3

Reference:
Patent; SANOFI; US2011/294788; (2011); A1;,
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

In 2020.0 J AGR FOOD CHEM published article about AROMA COMPOUNDS; VOLATILE COMPOUNDS; RAW; MUSHROOM; SING. in [Murray, Anne F.; Moore, Andrew J.; Munafo, John P., Jr.] Univ Tennessee, Dept Food Sci, Knoxville, TN 37996 USA in 2020.0, Cited 25.0. The Name is Methyl 3-phenylpropionate. Through research, I have a further understanding and discovery of 103-25-3. Computed Properties of C10H12O2

The American Matsutake, Tricholoma magnivelare (Peck) Redhead, is an edible wild mushroom with a distinctive aroma described as mushroom and spice with subtle floral and citrus nuances. In this study, a total of 36 odorants were identified from T. magnivelare using solvent-assisted flavor evaporation and aroma extract dilution analysis. Stable isotope dilution assays were performed to quantitate 14 odorants with flavor dilution factors >= 64. Odorants with high odor activity values (OAVs) included 1-octen-3-one (OAV 2125), linalool (OAV 650), (2E,4E)-nona-2,4-dienal (OAV 304), and 1-octen-3-ol (OAV 206). An odor simulation model matched the odor profile of the fresh mushroom. Omission studies showed that linalool, hexanal, (2E,4E)-nona2,4-dienal, methyl (E)-3-phenylprop-2-enoate, and 1-octen-3-one or 1-octen-3-ol were essential to the aroma of T. magnivelare. Chiral chromatography showed that a-pinene was a scalemic mixture of 34% (R)-(+) to 66% (S)-(-), while 1-octen-3-ol was present as 95% (R)-(-) to 5% (S)-(+), and linalool was 96% (R)-(-) to 4% (S)-(+). These results establish the base for future investigations into the aroma chemistry of other members of the genus Tricholoma.

Computed Properties of C10H12O2. About Methyl 3-phenylpropionate, If you have any questions, you can contact Murray, AF; Moore, AJ; Munafo, JP or concate me.

Reference:
Patent; SANOFI; US2011/294788; (2011); A1;,
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

SDS of cas: 103-25-3. I found the field of Food Science & Technology very interesting. Saw the article Chemical characterization of four Brazilian brown propolis: An insight in tracking of its geographical location of production and quality control published in 2019.0, Reprint Addresses Narain, N (corresponding author), Univ Fed Sergipe, Lab Flavor & Chromatog Anal, Sao Cristovao, Sergipe, Brazil.. The CAS is 103-25-3. Through research, I have a further understanding and discovery of Methyl 3-phenylpropionate.

The aim of this work was to undertake a detailed analysis on chemical constituents of brown propolis, originating from four different states (Bahia, Minas Gerais, Parana and Sergipe) of Brazil. The volatile profile was determined by using HS-SPME-GC-MS along with the determination of total phenolic compounds content, flavonoids and antioxidant activity. A total of 315 volatile compounds were identified, however, several of them have not been reported so far in the Brazilian brown propolis. The terpenes represented the major class with 40.92-84.66% of the total area in the chromatograms. PCA analysis of the majority of compounds successfully indicated the volatile profile of each propolis sample according to their geographical origin. The analysis of volatile compounds and its characterization also varied significantly and confirmed that these depended on the geographical area of collection of propolis. The data generated in this work may help in establishing criteria for quality control and tracking the specific region of propolis production in different states of Brazil.

SDS of cas: 103-25-3. About Methyl 3-phenylpropionate, If you have any questions, you can contact Olegario, LS; Andrade, JKS; Andrade, GRS; Denadai, M; Cavalcanti, RL; da Silva, MAAP; Narain, N or concate me.

Reference:
Patent; SANOFI; US2011/294788; (2011); A1;,
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

I found the field of Chemistry very interesting. Saw the article Synthesis of chromans and kinetic resolution of 2-aryl-3-nitro-2H-chromenes via the NHC-bound azolium homoenolate pathway published in 2019.0. Product Details of 103-25-3, Reprint Addresses Maji, B (corresponding author), Indira Gandhi Natl Tribal Univ, Dept Chem, Amarkantak 484886, Madhya Pradesh, India.. The CAS is 103-25-3. Through research, I have a further understanding and discovery of Methyl 3-phenylpropionate

Beyond the tandem oxa-Michael strategy, an N-heterocyclic carbene-catalyzed kinetic resolution approach to access highly diastereo- and enantioenriched 2-aryl-3-nitro-chromane derivatives has been developed. An efficient strategy for the kinetic resolution of racemic 2-aryl-3-nitro-2H-chromenes was also successfully achieved. This catalytic kinetic resolution method allows the synthetically valuable chiral scaffolds, chromane and 2H-chromene, to be accessed in a single catalytic and asymmetric transformation, through the NHC-bound azolium homoenolate pathway.

Product Details of 103-25-3. About Methyl 3-phenylpropionate, If you have any questions, you can contact Bhattacharya, A; Shukla, PM; Kaushik, LK; Maji, B or concate me.

Reference:
Patent; SANOFI; US2011/294788; (2011); A1;,
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

HPLC of Formula: C10H12O2. In 2020.0 CHEM COMMUN published article about CARBOXYLIC-ACIDS; REDUCTION; EFFICIENT; CARBONYL; HYDROSILYLATION; HYDROGENATION; HYDROBORATION; COMPLEXES; LIGAND; MILD in [Pattanaik, Sandip; Chidambaram, Gunanathan] HBNI, Natl Inst Sci Educ & Res NISER, Sch Chem Sci, Bhubaneswar 752050, Khurda, India in 2020.0, Cited 51.0. The Name is Methyl 3-phenylpropionate. Through research, I have a further understanding and discovery of 103-25-3.

Efficient and selective reduction of esters to aldehydes and alcohols is reported in which a simple cobalt pincer catalyst catalyses both transformations using diethylsilane as a reductant. Remarkably, the reaction selectivity is controlled by the stoichiometry of diethylsilane.

About Methyl 3-phenylpropionate, If you have any questions, you can contact Pattanaik, S; Chidambaram, G or concate me.. HPLC of Formula: C10H12O2

Reference:
Patent; SANOFI; US2011/294788; (2011); A1;,
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

COA of Formula: C10H12O2. Recently I am researching about CATALYZED TRANSFER HYDROGENATION; STEREOSELECTIVE TRANSFER SEMIHYDROGENATION; HIGHLY-ACTIVE HYDROGENATION; ORGANIC FRAMEWORK NODES; SITE COBALT CATALYSTS; BORANE-AMINE ADDUCTS; SELECTIVE HYDROGENATION; CONJUGATE REDUCTION; AMMONIA-BORANE; ASYMMETRIC HYDROGENATION, Saw an article supported by the Ministry of Science and Technology of ChinaMinistry of Science and Technology, China [2016YFE0132600]; Henan Center for Outstanding Overseas Scientists [GZS2020001]; National Innovation and Entrepreneurship Training Program for College students [201910459064]; Zhengzhou University. Published in WILEY-V C H VERLAG GMBH in WEINHEIM ,Authors: Wang, Y; Cao, XY; Zhao, LY; Pi, C; Ji, JF; Cui, XL; Wu, YJ. The CAS is 103-25-3. Through research, I have a further understanding and discovery of Methyl 3-phenylpropionate

A generalized, simple and efficient transfer hydrogenation of unsaturated bonds has been developed using HBP in and various proton reagents as hydrogen sources. The substrates, including alkenes, alkynes, aromatic heterocycles, aldehydes, ketones, imines, azo, nitro, epoxy and nitrile compounds, are all applied to this catalytic system. Various groups, which cannot survive under the Pd/C/H-2 combination, are tolerated. The activity of the reactants was studied and the trends are as follows:styrene>diphenylmethanimine>benzaldehyde>azobenzene>nitrobenzene>quinoline>acetophenone>benzonitrile. Substrates bearing two or more different unsaturated bonds were also investigated and transfer hydrogenation occurred with excellent chemoselectivity. Nano-palladium catalystin situgenerated from Pd(OAc)(2) and HBP in extremely improved the TH efficiency. Furthermore, chemoselective anti-Markovnikov hydrodeuteration of terminal aromatic olefins was achieved using D2O and HBP in via in situ HD generation and discrimination.

COA of Formula: C10H12O2. About Methyl 3-phenylpropionate, If you have any questions, you can contact Wang, Y; Cao, XY; Zhao, LY; Pi, C; Ji, JF; Cui, XL; Wu, YJ or concate me.

Reference:
Patent; SANOFI; US2011/294788; (2011); A1;,
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

An article Taking electrodecarboxylative etherification beyond Hofer-Moest using a radical C-O coupling strategy WOS:000607085800015 published article about DECARBOXYLATIVE ALLYLIC ETHERIFICATION; OXIDATIVE DECARBOXYLATION; CARBOXYLIC-ACIDS; ANODIC-OXIDATION; ELECTROCHEMICAL SYNTHESIS; ALIPHATIC-ACIDS; MALONIC-ACID; ARYL; COMPLEXES; ELECTROLYSIS in [Martinez, Angel Manu; Hayrapetyan, Davit; van Lingen, Tim; Dyga, Marco; Goossen, Lukas J.] Ruhr Univ Bochum, Fak Chem & Biochem, Univ Str 150, D-44801 Bochum, Germany in 2020.0, Cited 75.0. COA of Formula: C10H12O2. The Name is Methyl 3-phenylpropionate. Through research, I have a further understanding and discovery of 103-25-3

Established electrodecarboxylative etherification protocols are based on Hofer-Moest-type reaction pathways. An oxidative decarboxylation gives rise to radicals, which are further oxidised to carbocations. This is possible only for benzylic or otherwise stabilised substrates. Here, we report the electrodecarboxylative radical-radical coupling of lithium alkylcarboxylates with 1-hydroxybenzotriazole at platinum electrodes in methanol/pyridine to afford alkyl benzotriazole ethers. The substrate scope of this electrochemical radical coupling extends to primary and secondary alkylcarboxylates. The benzotriazole products easily undergo reductive cleavage to the alcohols. They can also serve as synthetic hubs to access a wide variety of functional groups. This reaction prototype demonstrates that electrodecarboxylative C-O bond formation can be taken beyond the intrinsic substrate limitations of Hofer-Moest mechanisms.

About Methyl 3-phenylpropionate, If you have any questions, you can contact Martinez, AM; Hayrapetyan, D; van Lingen, T; Dyga, M; Goossen, LJ or concate me.. COA of Formula: C10H12O2

Reference:
Patent; SANOFI; US2011/294788; (2011); A1;,
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

I found the field of Chemistry very interesting. Saw the article N-Heterocyclic carbene-catalyzed beta-addition of enals to 3-alkylenyloxindoles: synthesis of oxindoles with all-carbon quaternary stereocenters published in 2019.0. SDS of cas: 103-25-3, Reprint Addresses Ye, S (corresponding author), Chinese Acad Sci, Beijing Natl Lab Mol Sci, CAS Key Lab Mol Recognit & Funct, CAS Res Educ Ctr Excellence Mol Sci,Inst Chem, Beijing 100190, Peoples R China.; Ye, S (corresponding author), Univ Chinese Acad Sci, Beijing 100049, Peoples R China.. The CAS is 103-25-3. Through research, I have a further understanding and discovery of Methyl 3-phenylpropionate

The N-heterocyclic carbene-catalyzed beta-addition of enals to 3-alkylenyloxindoles was developed. All of the beta-aryl, beta-alkenyl and beta-alkyl enals worked well for the reaction to give the corresponding 3,3-disubstituted oxindoles bearing contiguous all-carbon quaternary and tertiary stereocenters in good yields with moderate to high diastereoselectivities and excellent enantioselectivities.

SDS of cas: 103-25-3. About Methyl 3-phenylpropionate, If you have any questions, you can contact Zhang, CL; Han, YF; Ye, S or concate me.

Reference:
Patent; SANOFI; US2011/294788; (2011); A1;,
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics