Category: 103-25-3

Recently I am researching about OXIDATIVE CARBONYLATION; ADIPIC ACID; HYDROFORMYLATION; METHOXYCARBONYLATION; ALKENES; CO; LIGAND; CARBON; PD, Saw an article supported by the Evonik Industries; German Federal Ministry BMBFFederal Ministry of Education & Research (BMBF); State of Mecklenburg-Western Pommerania; China CSC Scholarship [201704910879]. Published in ROYAL SOC CHEMISTRY in CAMBRIDGE ,Authors: Yang, J; Liu, JW; Ge, Y; Huang, WH; Schneider, C; Duhren, R; Franke, R; Neumann, H; Jackstell, R; Beller, M. The CAS is 103-25-3. Through research, I have a further understanding and discovery of Methyl 3-phenylpropionate. Computed Properties of C10H12O2

Hydroxy- and alkoxycarbonylation reactions constitute important industrial processes in homogeneous catalysis. Nowadays, palladium complexes constitute state-of-the-art catalysts for these transformations. Herein, we report the first efficient platinum-catalysed alkoxycarbonylations of olefins including sterically hindered and functionalized ones. This atom-efficient catalytic transformation provides straightforward access to a variety of valuable esters in good to excellent yields and often with high selectivities. In kinetic experiments the activities of Pd- and Pt-based catalysts were compared. Even at low catalyst loading, Pt shows high catalytic activity.

Computed Properties of C10H12O2. Welcome to talk about 103-25-3, If you have any questions, you can contact Yang, J; Liu, JW; Ge, Y; Huang, WH; Schneider, C; Duhren, R; Franke, R; Neumann, H; Jackstell, R; Beller, M or send Email.

Reference:
Patent; SANOFI; US2011/294788; (2011); A1;,
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

An article Floral Scent and Nectar Sugar Composition of Temnadenia odorifera (Apocynoideae, Apocynaceae) WOS:000453745200019 published article about CHEMICAL ECOLOGY; VOLATILES; PLANT; BIODIVERSITY; RECOGNITION; GENERATION; DIVERSITY; CHEMISTRY; EVOLUTION; PATTERNS in [Silva, Rafael F.; Tinoco, Natalia A. B.; Tsukui, Anna; Rezende, Claudia M.] Univ Fed Rio de Janeiro, Inst Quim, Lab Anal Aromas, BR-21941909 Rio De Janeiro, RJ, Brazil; [Silva, Rafael F.; Bizzo, Humberto R.] Univ Fed Rio de Janeiro, Inst Pesquisas Prod Nat, BR-21941902 Rio De Janeiro, RJ, Brazil; [Kosehnitzke, Cristiana; Silva-Batista, Inara C.] Univ Fed Rio de Janeiro, Museu Nacl, Dept Bot, BR-20940040 Rio De Janeiro, RJ, Brazil; [Bizzo, Humberto R.] Embrapa Agroind Alimentos, Av Amer 29501, BR-23020470 Rio De Janeiro, RJ, Brazil in 2019.0, Cited 44.0. The Name is Methyl 3-phenylpropionate. Through research, I have a further understanding and discovery of 103-25-3. Computed Properties of C10H12O2

Temnadenia odorifera is an endemic species from the Brazilian Atlantic Forest. This study was developed in order to identify the volatile compounds emitted by the living flowers and nectar, to evaluate the temporal pattern of scent emission, and the sugars composition of its nectar. Analyses of the flower scent by dynamic headspace in vivo, of nectar sugar composition and studies on floral biology were performed. Twenty-three volatile compounds were identified in the flowers scent. The total amount of odor emitted by flowers varied significantly throughout anthesis, ranging from 10232.7 ng g(-1) (9 to 12 h) to 620.2 ng g(-1) (15 to 18 h). 2-Phenylethanol and (E)-cinnamyl alcohol were the major compounds. Concentration ratio between disaccharides and the sum of hexoses ranged from 2.3 to 3.04, which can be correlated to the physiological needs inherent to big bees, the most frequent insects in T. odorifera. Analysis of the chemical composition of T. odorifera flowers provided a broader understanding of the mechanisms responsible for plant-insect interactions.

Welcome to talk about 103-25-3, If you have any questions, you can contact Silva, RF; Tinoco, NAB; Tsukui, A; Kosehnitzke, C; Silva-Batista, IC; Rezende, CM; Bizzo, HR or send Email.. Computed Properties of C10H12O2

Reference:
Patent; SANOFI; US2011/294788; (2011); A1;,
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

I found the field of Chemistry very interesting. Saw the article Pd-Catalyzed Selective Carbonylation of gem-Difluoroalkenes: A Practical Synthesis of Difluoromethylated Esters published in 2019.0. Name: Methyl 3-phenylpropionate, Reprint Addresses Beller, M (corresponding author), Univ Rostock, Leibniz Inst Katalyse, Albert Einstein Str 29a, D-18059 Rostock, Germany.. The CAS is 103-25-3. Through research, I have a further understanding and discovery of Methyl 3-phenylpropionate

The first catalyst for the alkoxycarbonylation of gem-difluoroalkenes is described. This novel catalytic transformation proceeds in the presence of Pd(acac)(2)/1,2-bis((di-tert-butylphosphan-yl)methyl)benzene (btbpx) (L4) and allows for an efficient and straightforward access to a range of difluoromethylated esters in high yields and regioselectivities. The synthetic utility of the protocol is showcased in the practical synthesis of a Cyclandelate analogue using this methodology as the key step.

Name: Methyl 3-phenylpropionate. Welcome to talk about 103-25-3, If you have any questions, you can contact Liu, JW; Yang, J; Ferretti, F; Jackstell, R; Beller, M or send Email.

Reference:
Patent; SANOFI; US2011/294788; (2011); A1;,
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

I found the field of Pharmacology & Pharmacy; Chemistry very interesting. Saw the article Synthesis of N ‘-propylhydrazide analogs of hydroxamic inhibitors of histone deacetylases (HDACs) and evaluation of their impact on activities of HDACs and replication of hepatitis C virus (HCV) published in 2019.0. Category: esters-buliding-blocks, Reprint Addresses Kozlov, MV (corresponding author), Russian Acad Sci, Engelhardt Inst Mol Biol, Vavilova 32, Moscow 119991, Russia.. The CAS is 103-25-3. Through research, I have a further understanding and discovery of Methyl 3-phenylpropionate

N’-Propylhydrazide analogs of hydroxamic inhibitors of histone deacetylases (HDACs), including tubastatin A, vorinostat and belinostat, were synthesized. All prepared compounds inhibited HDAC1/2/3, but not HDAC6, except for one hydrazide analog of HDAC4/5/7 inhibitor that was completely inactive. A novel 4-substituted derivative of N’-propylbenzohydrazide with extremely high anti-HCV activity was discovered.

Welcome to talk about 103-25-3, If you have any questions, you can contact Kozlov, MV; Konduktorov, KA; Shcherbakova, AS; Kochetkov, SN or send Email.. Category: esters-buliding-blocks

Reference:
Patent; SANOFI; US2011/294788; (2011); A1;,
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

In 2019.0 APPL ORGANOMET CHEM published article about SELECTIVE HYDROGENATION; HETEROGENEOUS CATALYST; PD NANOPARTICLES; FACILE SYNTHESIS; N-ALKYLATION; REDUCTION; ACID; EFFICIENT; SUZUKI; OXIDATION in [Patel, Heta A.; Rawat, Maitreyee; Patel, Arun L.; Bedekar, Ashutosh V.] Maharaja Sayajirao Univ Baroda, Fac Sci, Dept Chem, Vadodara 390002, India in 2019.0, Cited 110.0. The Name is Methyl 3-phenylpropionate. Through research, I have a further understanding and discovery of 103-25-3. COA of Formula: C10H12O2

Polyaniline coated on particles of celite is used as support to load palladium catalyst. This heterogenized Celite center dot PANI center dot Pd system, is used as an efficient catalyst for chemoselective hydrogenation reactions. The catalyst is characterized by usual spectral, analytical techniques and studied for hydrogenation reactions at ambient conditions. The mild reaction conditions allow the control over the reactions and excellent selectivity is achieved in number of conversions. Hydrogenation of a carbon-carbon double bond was favored over other polar pi-bond systems, while labile functional groups such as benzyl ether, benzyl esters, cyano, nitro and halogen remained unaffected. Primary amines were converted to N,N-dimethyl amines with formaldehyde, the double bond of coumarin was selectively hydrogenated without opening of the lactone functionality.

About Methyl 3-phenylpropionate, If you have any questions, you can contact Patel, HA; Rawat, M; Patel, AL; Bedekar, AV or concate me.. COA of Formula: C10H12O2

Reference:
Patent; SANOFI; US2011/294788; (2011); A1;,
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

An article Reductive Allylic Defluorinative Cross-Coupling Enabled by Ni/Ti Cooperative Catalysis WOS:000492114600037 published article about NUCLEOPHILIC 5-ENDO-TRIG CYCLIZATION; FUNCTIONALIZED GEM-DIFLUOROALKENES; DIFLUOROMETHYL 2-PYRIDYL SULFONE; F BOND ACTIVATION; C-F; DIAZO-COMPOUNDS; BIOLOGICAL-ACTIVITY; 4-EXO CYCLIZATIONS; ALKYL-HALIDES; NICKEL in [Lin, Zhiyang; Lan, Yun; Wang, Chuan] Univ Sci & Technol China, Hefei Natl Lab Phys Sci Microscale, Dept Chem, Ctr Excellence Mol Synth, 96 Jinzhai Rd, Hefei 230026, Anhui, Peoples R China in 2019.0, Cited 107.0. The Name is Methyl 3-phenylpropionate. Through research, I have a further understanding and discovery of 103-25-3. Safety of Methyl 3-phenylpropionate

Unactivated alkyl chlorides are abundant building blocks in organic synthesis, but they have been rarely engaged in cross-electrophile coupling. Herein, we report a Ni/Ti-cocatalyzed reductive allylic defluorinative cross -coupling between trifluoromethyl alkenes and unactivated alkyl chlorides and bromides, enabling the efficient preparation of diverse functional-group-rich gem-difluoroalkenes. Notably, synthesis of the gem-difluoroalkene analogues of azaperone, haloperidol, and benperidol was also accomplished using our method as a key step.

Safety of Methyl 3-phenylpropionate. Bye, fridends, I hope you can learn more about C10H12O2, If you have any questions, you can browse other blog as well. See you lster.

Reference:
Patent; SANOFI; US2011/294788; (2011); A1;,
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

In 2020.0 CHEM COMMUN published article about METHYL BENZOATE; CARBOXYLIC-ACIDS; HYDROSILYLATION REACTIONS; CARBONYL-COMPLEXES; HYDROGENATION; KETONES; MNO/GAMMA-AL2O3; PHOTOCHEMISTRY; MECHANISM; HYDRIDE in [Wei, Duo] Univ Rennes, CNRS, ISCR, UMR 6226, F-35000 Rennes, France; [Wei, Duo; Buhaibeh, Ruqaya; Canac, Yves; Sortais, Jean-Baptiste] Univ Toulouse, UPS, CNRS, LCC CNRS, Toulouse, France; [Sortais, Jean-Baptiste] Inst Univ France, 1 Rue Descartes, F-75231 Paris 05, France in 2020.0, Cited 52.0. The Name is Methyl 3-phenylpropionate. Through research, I have a further understanding and discovery of 103-25-3. Safety of Methyl 3-phenylpropionate

The selective reduction of esters to aldehydes,viathe formation of stable alkyl silyl acetals, was, for the first time, achieved with both manganese, -Mn-2(CO)(10)- and rhenium -Re-2(CO)(10)- catalysts in the presence of triethylsilane as reductant. These two methods provide a direct access to a large variety of aliphatic and aromatic alkyl silyl acetals (30 examples) and to the corresponding aldehydes (13 examples) upon hydrolysis. The reactions proceeded in excellent yields and high selectivity at room temperature under photo-irradiation conditions (LED, 365 nm, 40 W, 9 h).

Safety of Methyl 3-phenylpropionate. About Methyl 3-phenylpropionate, If you have any questions, you can contact Wei, D; Buhaibeh, R; Canac, Y; Sortais, JB or concate me.

Reference:
Patent; SANOFI; US2011/294788; (2011); A1;,
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

An article Copper-Catalyzed C-H Fluorination/Functionalization Sequence Enabling Benzylic C-H Cross Coupling with Diverse Nucleophiles WOS:000562077400009 published article about BONDS; ACTIVATION; AMINATION; FUNCTIONALIZATION in [Vasilopoulos, Aristidis; Golden, Dung L.; Buss, Joshua A.; Stahl, Shannon S.] Univ Wisconsin, Dept Chem, 1101 Univ Ave, Madison, WI 53706 USA in 2020.0, Cited 46.0. Computed Properties of C10H12O2. The Name is Methyl 3-phenylpropionate. Through research, I have a further understanding and discovery of 103-25-3

Site-selective transformation of benzylic C-H bonds into diverse functional groups is achieved via Cu-catalyzed C-H fluorination with N-fluorobenzenesulfonimide (NFSI), followed by substitution of the resulting fluoride with various nucleophiles. The benzyl fluorides generated in these reactions are reactive electrophiles in the presence of hydrogen-bond donors or Lewis acids, allowing them to be used without isolation in C-O, C-N, and C-C coupling reactions.

Computed Properties of C10H12O2. Welcome to talk about 103-25-3, If you have any questions, you can contact Vasilopoulos, A; Golden, DL; Buss, JA; Stahl, SS or send Email.

Reference:
Patent; SANOFI; US2011/294788; (2011); A1;,
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

An article Ni-catalyzed direct alcoholysis of N-acylpyrrole-type tertiary amides under mild conditions WOS:000516508500001 published article about CROSS-COUPLINGS; ENANTIOSELECTIVE ADDITION; ESTERIFICATION; ACTIVATION; CONVERSION; REAGENTS; ALKENES in [Chen, Hang; Chen, Dong-Huang; Huang, Pei-Qiang] Xiamen Univ, Coll Chem & Chem Engn, Collaborat Innovat Ctr Chem Ene Mat, Dept Chem,Fujian Prov Key Lab Chem Biol, Xiamen 361005, Peoples R China in 2020.0, Cited 50.0. The Name is Methyl 3-phenylpropionate. Through research, I have a further understanding and discovery of 103-25-3. Computed Properties of C10H12O2

N-Acylpyrrole-type amides are a class of versatile building blocks in asymmetric synthesis. We report that by employing Ni(COD)(2)/2,2 ‘-bipyridine (5 mol%) catalytic system, the direct, catalytic alcoholysis of N-acylpyrrole-type aromatic and aliphatic amides with both primary and secondary alcohols can be achieved efficiently under very mild conditions (rt, 1 h) even at gram scale. By increasing the catalyst loading to 10 mol%, prolonging reaction time (18 h), and/or elevating reaction temperature to 50 degrees C/80 degrees C, the reaction could be extended to both complex and hindered N-acylpyrroles as well as to N-acylpyrazoles, Nacylindoles, and to other (functionalized) primary and secondary alcohols. In all cases, only 1.5 equiv. of alcohol were used. The value of the method has been demonstrated by the racemization-free, catalytic alcoholysis of chiral amides yielded from other asymmetric methodologies.

Bye, fridends, I hope you can learn more about C10H12O2, If you have any questions, you can browse other blog as well. See you lster.. Computed Properties of C10H12O2

Reference:
Patent; SANOFI; US2011/294788; (2011); A1;,
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

Recently I am researching about SELECTIVE HYDROGENATION; HETEROGENEOUS CATALYST; PD NANOPARTICLES; FACILE SYNTHESIS; N-ALKYLATION; REDUCTION; ACID; EFFICIENT; SUZUKI; OXIDATION, Saw an article supported by the University Grants CommissionUniversity Grants Commission, India [42-240/2013]. Product Details of 103-25-3. Published in WILEY in HOBOKEN ,Authors: Patel, HA; Rawat, M; Patel, AL; Bedekar, AV. The CAS is 103-25-3. Through research, I have a further understanding and discovery of Methyl 3-phenylpropionate

Polyaniline coated on particles of celite is used as support to load palladium catalyst. This heterogenized Celite center dot PANI center dot Pd system, is used as an efficient catalyst for chemoselective hydrogenation reactions. The catalyst is characterized by usual spectral, analytical techniques and studied for hydrogenation reactions at ambient conditions. The mild reaction conditions allow the control over the reactions and excellent selectivity is achieved in number of conversions. Hydrogenation of a carbon-carbon double bond was favored over other polar pi-bond systems, while labile functional groups such as benzyl ether, benzyl esters, cyano, nitro and halogen remained unaffected. Primary amines were converted to N,N-dimethyl amines with formaldehyde, the double bond of coumarin was selectively hydrogenated without opening of the lactone functionality.

Bye, fridends, I hope you can learn more about C10H12O2, If you have any questions, you can browse other blog as well. See you lster.. Product Details of 103-25-3

Reference:
Patent; SANOFI; US2011/294788; (2011); A1;,
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics