Moss, Robert A.; Wilk, Boguslawa; Krogh-Jespersen, Karsten; Blair, John T.; Westbrook, John D. published the artcile< Organoiodinane reagents for phosphate cleavage: experimental and computational studies>, Formula: C19H34O2, the main research area is MO oxidoiodoxolone; LFER oxidobenziodoxolone catalysis phosphate hydrolysis; iodoxolone oxido MO hydrolysis catalyst.
Several analogs of 1-oxido-1,2-benziodoxol-3(1H)-one (I; the valence tautomer of o-iodosobenzoate), were examined for their ability to cleave p-nitrophenyl di-Ph phosphate in aqueous micellar cetyltrimethylammonium chloride at pH 8. These included the 5,5-di-Me (II) and 5,5-bis(trifluoromethyl) (III) analogs, as well as the parent 1-oxidoiodoxol-(3H)-ones IV [R = Cl (V), H (VI)]. The kinetic reactivity order was I > V > VI > III >> II. The results are discussed in terms of the relative acidities shown by the I-OH forms of the catalysts and the nucleophilicities of their I-O- conjugate bases. Ab initio MO calculations were performed on VI, its conjugate acid, the deoxo analogs VII (R = H), and VIII (R = H) and their di-Me and bis(trifluoromethyl) derivatives [VII (R = Me, CF3) and VIII (R = Me, CF3)] to aid this anal. The electronic structures of these species are discussed in detail.
Journal of the American Chemical Society published new progress about Hydrolysis. 112-63-0 belongs to class esters-buliding-blocks, and the molecular formula is C19H34O2, Formula: C19H34O2.
Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics