Narobe, Rok;Murugesan, Kathiravan;Haag, Christoph;Schirmer, Tobias Emanuel;Koenig, Burkhard published 《C(sp3)-H Ritter amination by excitation of in-situ generated iodine(
Visible light excitation of iodine(III)-BF3 complex enables the formation of carbocations from C(sp3)-H bonds. The complexes were generated catalytically from iodoarene, carboxylate ligand, the oxidizing agent Selectfluor and the Lewis acid BF3. This modular catalytic system allowed the formation of synthetically valuable amine derivatives without a metal- or photocatalyst.Methyl 3-methylbenzoate (cas: 99-36-5) were involved in the experimental procedure.
Methyl 3-methylbenzoate (cas: 99-36-5) is a common ester. Esters are widespread in nature and are widely used in industry. Several billion kilograms of polyesters are produced industrially annually, important products being polyethylene terephthalate, acrylate esters, and cellulose acetate.Safety of Methyl 3-methylbenzoate
Reference:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics