Synthetic Route of C15H28O2In 2021, Kalana, U. L. D. Inush;Datta, Partha P.;Hewawasam, Rukshika S.;Kiesewetter, Elizabeth T.;Kiesewetter, Matthew K. published 《Organocatalytic ring-opening polymerization of thionolactones: anything O can do, S can do better》. 《Polymer Chemistry》published the findings. The article contains the following contents:
The H-bond mediated organocatalytic ring-opening polymerizations (ROPs) of four new thionolactone monomers are discussed. The kinetic and thermodn. behavior of the ROPs is considered in the context of the parent lactone monomers. Organocatalysts facilitate the retention of the S/O substitution as well as the synthesis of copolymers. The thionoester moieties in the polymer backbone serve as a chem. handle for a facile crosslinking reaction, and the porosity of the resulting crosslinked polymer can be tuned by altering the thioester d. in the (co)polymer. The crosslinked polymers are shown to be degradable in water, and an Au3+ recovery application is demonstrated. The experimental procedure involved many compounds, such as Oxacyclohexadecan-2-one (cas: 106-02-5) .
Oxacyclohexadecan-2-one(cas:106-02-5) is a natural product found in Lonicera japonica and Angelica archangelica.Synthetic Route of C15H28O2 It is a macrocyclic lactone that can be used as a flavoring agent and fragrance ingredient due to its musk flavor/odor.
Reference:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics