Today I want to share an article with you. The article is 《Synergetic Chemical and Physical Programming for Reversible Shape Memory Effect in a Dynamic Covalent Network with Two Crystalline Phases》,you can find this article in 《ACS Macro Letters》. The following contents are mentioned:
A recently emerged reversible shape memory effect greatly extends the capability of shape memory polymers and their practical potential. Phys. confinement and chem. fixation are individually known to be effective in introducing network anisotropy essential for reversible shape memory. Herein, we demonstrate that synergetic combination of these two mechanisms effectively diversifies the shape-shifting behavior. Specifically, we introduce a transesterification catalyst into a network containing two crystalline phases: poly(ε-caprolactone) (PCL) and poly(ω-pentadecalactone) (PPDL). The reversible shape memory behavior of the resulting system can be programed via the phys. confinement by the PPDL phase and the chem. plasticity by the dynamic ester exchange. We illustrate that the two programming mechanisms can operate in a noninterfering way that allows achieving a synergetic benefit, notably realizing a zero-set reversible shape memory behavior. Our study points to a direction in diversifying the behaviors of reversible shape memory polymers and expands the scope for potential engineering devices.Oxacyclohexadecan-2-one (cas: 106-02-5) were involved in the experimental procedure.
Oxacyclohexadecan-2-one(cas:106-02-5) is a natural product found in Lonicera japonica and Angelica archangelica.Category: esters-buliding-blocks It is a macrocyclic lactone that can be used as a flavoring agent and fragrance ingredient due to its musk flavor/odor.
Reference:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics