Recently I am researching about BETA-HYDROXYLATION; ACTIVE ALDEHYDES; REDOX BEHAVIOR; AMINES; ENALS, Saw an article supported by the Institute for Basic Science [IBS-R010-A2]. Published in ROYAL SOC CHEMISTRY in CAMBRIDGE ,Authors: Kim, I; Im, H; Lee, H; Hong, S. The CAS is 103-25-3. Through research, I have a further understanding and discovery of Methyl 3-phenylpropionate. Safety of Methyl 3-phenylpropionate
By employing an N-heterocyclic carbene (NHC) catalyst, we developed a versatile catalytic system that enables deaminative cross-coupling reactions of aldehydes with redox-active pyridinium salts. Katritzky pyridinium salts behave as single-electron oxidants capable of generating alkyl radicals enabled by the redox properties of the enolate form of Breslow intermediates. The resultant alkyl radical undergoes efficient recombination with the NHC-bound aldehyde-derived carbonyl carbon radical for the formation of a C-C bond. The mild and transition metal-free reaction conditions tolerate a broad range of functional groups, and its utility has been further demonstrated by the modification of a series of peptide feedstocks and application to the three-component dicarbofunctionalization of olefins.
Safety of Methyl 3-phenylpropionate. Welcome to talk about 103-25-3, If you have any questions, you can contact Kim, I; Im, H; Lee, H; Hong, S or send Email.
Reference:
Patent; SANOFI; US2011/294788; (2011); A1;,
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