An article Chemoselective Hydrogenation of alpha,beta-Unsaturated Carbonyls Catalyzed by Biomass-Derived Cobalt Nanoparticles in Water WOS:000459333500023 published article about N-HETEROCYCLIC CARBENE; SELECTIVE HYDROGENATION; CONJUGATE REDUCTION; HIGHLY EFFICIENT; OXIDE CATALYSTS; COMPLEXES; KETONES; LOUREIRIN; ALDEHYDES; NITROARENES in [Song, Tao; Ma, Zhiming; Yang, Yong] Chinese Acad Sci, Qingdao Inst Bioenergy & Bioproc Technol, Qingdao 266101, Peoples R China; [Ma, Zhiming] Univ Chinese Acad Sci, Beijing 100049, Peoples R China in 2019.0, Cited 71.0. HPLC of Formula: C10H10O2. The Name is Methyl 3-phenyl-2-propenoate. Through research, I have a further understanding and discovery of 103-26-4
Herein, we report highly chemoselective hydrogenation of alpha,beta-unsaturated carbonyls to saturated carbonyls catalyzed by cobalt nanoparticles supported on the biomass-derived carbon from bamboo shoots with molecular hydrogen in water, which is the first prototype using a heterogeneous non-noble metal catalyst for such organic transformation as far as we know. The optimal cobalt nanocatalyst, CoOx@NC-800, manifested remarkable activity and selectivity for hydrogenation of C=C in alpha,beta-unsaturated carbonyls under mild conditions. A broad set of alpha,beta-aromatic and aliphatic unsaturated carbonyls were selectively reduced to their corresponding saturated carbonyls in up to 99 % yields with good tolerance of various functional groups. Meanwhile, a new straightforward one-pot cascade synthesis of saturated carbonyls was realized with high activity and selectivity via the cross-aldol condensation of ketones with aldehydes followed by selective hydrogenation. More importantly, this one-pot strategy is applicable for the expedient synthesis of Loureirin A, a versatile bioactive and medicinal molecule, from readily available starting materials, further highlighting the practical utility of the catalyst. In addition, the catalyst can be easily separated for successive reuses without significant loss in both activity and selectivity.
HPLC of Formula: C10H10O2. Welcome to talk about 103-26-4, If you have any questions, you can contact Song, T; Ma, ZM; Yang, Y or send Email.
Reference:
Article; Weng, Shiue-Shien; Ke, Chih-Shueh; Chen, Fong-Kuang; Lyu, You-Fu; Lin, Guan-Ying; Tetrahedron; vol. 67; 9; (2011); p. 1640 – 1648;,
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