An article Targeted Synthesis of Regioisomerically Pure Dodecasubstituted Type I Porphyrins through the Exploitation of Peri-interactions WOS:000538764000077 published article about CONFORMATIONAL CONTROL; DISTORTION; ISOMERS in [Kielmann, Marc; Flanagan, Keith J.; Senge, Mathias O.] Univ Dublin, Trinity Coll Dublin, Sch Chem, Trinity Biomed Sci Inst,SFI Tetrapyrrole Lab, Dublin 2, Ireland in 2020.0, Cited 45.0. Category: esters-buliding-blocks. The Name is Methyl 3-phenyl-2-propenoate. Through research, I have a further understanding and discovery of 103-26-4
A targeted synthesis of dodecasubstituted type I porphyrins that utilizes the reaction of unsymmetrical 3,4-difunctionalized pyrroles and sterically demanding aldehydes was developed. This way, type I porphyrins could be obtained as the only type isomers, likely due to a minimization of the steric strain arising from peri-interactions. Uniquely, this method does not depend on lengthy precursor syntheses, the separation of isomers, or impractical limitations of the scale. In addition, single-crystal X-ray analysis was used to elucidate the structural features of the macrocycles.
Welcome to talk about 103-26-4, If you have any questions, you can contact Kielmann, M; Flanagan, KJ; Senge, MO or send Email.. Category: esters-buliding-blocks
Reference:
Article; Weng, Shiue-Shien; Ke, Chih-Shueh; Chen, Fong-Kuang; Lyu, You-Fu; Lin, Guan-Ying; Tetrahedron; vol. 67; 9; (2011); p. 1640 – 1648;,
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