Synthesis of new tripodal tri-functionalized hydrotris(indazol-1-yl)borate ligands and x-ray structures of their cyclopentadieneruthenium complexes was written by Carella, Alexandre;Vives, Guillaume;Cox, Tara;Jaud, Joel;Rapenne, Gwenael;Launay, Jean-Pierre. And the article was included in European Journal of Inorganic Chemistry in 2006.Name: Ethyl 3-amino-4-methylbenzoate This article mentions the following:
Two tripodal ligands designed to anchor complexes onto surfaces were synthesized. K hydrotris[6-(ethoxycarbonyl)indazolyl]borate and K hydrotris{6-[(ethylthio)methyl]indazolyl}borate exhibit three pendant groups oriented to anchor complexes onto an oxide and a metallic surface, resp. They integrate ester or thioether functions at the 6-position of the indazoles. Their complexation with [RuCp(MeCN)3]PF6 yielded two piano-stool-shaped complexes that were characterized by x-ray diffraction. Comparison with the synthesized unfunctionalized analog showed that the three 6-substituted functions do not interfere with the coordination site and are particularly well oriented for surface deposition. In the experiment, the researchers used many compounds, for example, Ethyl 3-amino-4-methylbenzoate (cas: 41191-92-8Name: Ethyl 3-amino-4-methylbenzoate).
Ethyl 3-amino-4-methylbenzoate (cas: 41191-92-8) belongs to esters. Volatile esters with characteristic odours are used in synthetic flavours, perfumes, and cosmetics. Certain volatile esters are used as solvents for lacquers, paints, and varnishes. Acyl chlorides and acid anhydrides alcoholysis is another way to produce esters. Acyl chlorides and acid anhydrides react with alcohols to produce esters. Anydrous conditions are recommended since both acyl chlorides and acid anhydrides react with water.Name: Ethyl 3-amino-4-methylbenzoate
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