Benzyl benzodithioate (cas: 27249-90-7) belongs to esters. Esters are widespread in nature and are widely used in industry. In nature, fats are in general triesters derived from glycerol and fatty acids. Esters are responsible for the aroma of many fruits, including apples, durians, pears, bananas, pineapples, and strawberries. Cyclic esters are called lactones, regardless of whether they are derived from an organic or inorganic acid. One example of an organic lactone is γ-valerolactone.Formula: C14H12S2
RAFT Polymerization of Acrylamides Containing Proline and Hydroxyproline Moiety: Controlled Synthesis of Water-Soluble and Thermoresponsive Polymers was written by Mori, Hideharu;Kato, Ikumi;Matsuyama, Motonobu;Endo, Takeshi. And the article was included in Macromolecules (Washington, DC, United States) in 2008.Formula: C14H12S2 This article mentions the following:
Two acrylamides containing proline and hydroxyproline moiety, N-acryloyl-L-proline (A-Pro-OH) and N-acryloyl-4-trans-hydroxy-L-proline (A-Hyp-OH), were polymerized by reversible addition-fragmentation chain transfer (RAFT) process to afford well-defined amino acid based polymers. Two chain transfer agents (CTAs), benzyl dithiobenzoate (CTA 1) and benzyl 1-pyrrolecarbodithioate (CTA 2), were compared for the direct polymerization of these monomers without protecting chem. With 2,2′-azobis(isobutyronitrile) as an initiator, the dithiocarbamate-type RAFT agent (CTA 2) was efficient for the controlled synthesis of poly(A-Pro-OH)s, which can be regarded as a weak polyelectrolyte. Controlled character of the polymerization of A-Hyp-OH, which has a carboxylic acid and a hydroxyl group in the monomer unit, in the presence of CTA 1 was confirmed by the formation of narrow polydispersity products and the linear relationship between the mol. weight and conversion. Water-soluble poly(A-Hyp-OH)s with number-average mol. weights between 8.2 × 103 and 2.21 × 104 and relatively low polydispersities were obtained, depending on the monomer/CTA ratio. Their methylated samples, poly(A-Pro-OMe) and poly(A-Hyp-OMe), and random copolymers showed characteristic thermal phase transitions in aqueous solutions In the experiment, the researchers used many compounds, for example, Benzyl benzodithioate (cas: 27249-90-7Formula: C14H12S2).
Benzyl benzodithioate (cas: 27249-90-7) belongs to esters. Esters are widespread in nature and are widely used in industry. In nature, fats are in general triesters derived from glycerol and fatty acids. Esters are responsible for the aroma of many fruits, including apples, durians, pears, bananas, pineapples, and strawberries. Cyclic esters are called lactones, regardless of whether they are derived from an organic or inorganic acid. One example of an organic lactone is γ-valerolactone.Formula: C14H12S2
Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics