Synthesis and characterization of poly(hexamethylene 2,6-naphthalate)-block-poly(tetrahydrofuran) copolymers with shape memory effect was written by Walkowiak, Konrad;Irska, Izabela;Paszkiewicz, Sandra. And the article was included in Materials Research Bulletin in 2022.Recommanded Product: 6683-19-8 This article mentions the following:
Shape memory polymers (SMPs) are able to return to their previous shape after deformation under certain conditions. Several block copolymers can exhibit shape memory behavior. The blocks in copolymers are usually immiscible, which leads to phase separation into rigid and flexible segments. For that reason, these materials combine the mech. properties of elastomers with the processing properties of thermoplastic. Thus, a poly(hexamethylene 2,6-naphthalate) (PHN) and a series of poly(hexamethylene 2,6-naphthalate)-block-poly(tetrahydrofuran) (PHN-b-N-pTHF) copolymers were synthesized via melt polycondensation. The content of the N-pTHF flexible segment varied from 15 to 50 weight%. The materials were characterized with the use of Fourier transformed IR spectroscopy, differential scanning calorimetry, dynamic mech. thermal anal., X-ray diffraction anal., the tensile tests (static and cyclic), and the cyclic thermo-mech. anal. The PHN-b-N-pTHF 50/50 was proved to be a promising thermoplastic shape memory polymer (SMP). In the experiment, the researchers used many compounds, for example, 2,2-Bis(((3-(3,5-di-tert-butyl-4-hydroxyphenyl)propanoyl)oxy)methyl)propane-1,3-diyl bis(3-(3,5-di-tert-butyl-4-hydroxyphenyl)propanoate) (cas: 6683-19-8Recommanded Product: 6683-19-8).
2,2-Bis(((3-(3,5-di-tert-butyl-4-hydroxyphenyl)propanoyl)oxy)methyl)propane-1,3-diyl bis(3-(3,5-di-tert-butyl-4-hydroxyphenyl)propanoate) (cas: 6683-19-8) belongs to esters. Esters are widespread in nature and are widely used in industry. In nature, fats are in general triesters derived from glycerol and fatty acids. Esters are responsible for the aroma of many fruits, including apples, durians, pears, bananas, pineapples, and strawberries. Liquid esters of low volatility serve as softening agents for resins and plastics. Esters also include many industrially important polymers. Polymethyl methacrylate is a glass substitute sold under the names Lucite and Plexiglas; polyethylene terephthalate is used as a film (Mylar) and as textile fibres sold as Terylene, Fortrel, and Dacron.Recommanded Product: 6683-19-8
Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics