Tailoring the pore geometry and chemistry in microporous metal-organic frameworks for high methane storage working capacity was written by Shao, Kai;Pei, Jiyan;Wang, Jia-Xin;Yang, Yu;Cui, Yuanjing;Zhou, Wei;Yildirim, Taner;Li, Bin;Chen, Banglin;Qian, Guodong. And the article was included in Chemical Communications (Cambridge, United Kingdom) in 2019.Application In Synthesis of Dimethyl 5-ethynylisophthalate This article mentions the following:
We realized that tailoring the pore size/geometry and chem., by virtue of alkynyl or naphthalene replacing Ph within a series of isomorphic MOFs, can optimize methane storage working capacities, affording an exceptionally high working capacity of 203 cm3 (STP)/cm3 at 298 K and 5-80 bar. In the experiment, the researchers used many compounds, for example, Dimethyl 5-ethynylisophthalate (cas: 313648-56-5Application In Synthesis of Dimethyl 5-ethynylisophthalate).
Dimethyl 5-ethynylisophthalate (cas: 313648-56-5) belongs to esters. Volatile esters with characteristic odours are used in synthetic flavours, perfumes, and cosmetics. Certain volatile esters are used as solvents for lacquers, paints, and varnishes. Because of their lack of hydrogen-bond-donating ability, esters do not self-associate. Consequently, esters are more volatile than carboxylic acids of similar molecular weight.Application In Synthesis of Dimethyl 5-ethynylisophthalate
Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics