Yang, Tsanhsi published the artcileInvestigation of isoprenoid benzoates and naphthoates by reversed-phase liquid chromatography. Isocratic elution characteristics of benzoates and naphthoates of C5-C20 terpenoid alcohols, Application of 3-Methylbut-2-en-1-yl benzoate, the publication is Journal of Chromatography (1984), 121-32, database is CAplus and MEDLINE.
Conditions for derivatization of C5-C20 isoprenoid alcs. and the reversed-phase liquid chromatog. properties of the corresponding benzoate and naphthoate esters are described. A non-linear response of log k‘ to changes in the composition of the mobile phase was observed on a Radial-Pak C18 column. In general, the capacity factors (k‘) increased with increases in C content and degree of saturation in the hydrocarbon chain, and decreased with increases in branching and Z double bond content. Replacement of a single H in the Me group at C-3 of geranyl benzoate with F had little effect on k‘, while the difluoro- and trifluoromethyl derivatives showed regular increases in k‘. The large extinction coefficients of the aromatic ester moieties, especially the 2-naphthoates, provide high sensitivity of UV detection.
Journal of Chromatography published new progress about 5205-11-8. 5205-11-8 belongs to esters-buliding-blocks, auxiliary class Alkenyl,Benzene,Ester, name is 3-Methylbut-2-en-1-yl benzoate, and the molecular formula is C65H82N2O18S2, Application of 3-Methylbut-2-en-1-yl benzoate.
Referemce:
https://en.wikipedia.org/wiki/Ester,
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