Chakraborty, Soumi published the artcileRedox-active ligand based Mn(I)-catalyst for hydrosilylative ester reduction, SDS of cas: 110-42-9, the main research area is manganese phenalenyl preparation redox active catalyst; ester hydrosilylation polymethylhydrosiloxane manganese catalyst; alc preparation.
Herein a Mn(I) catalyst bearing a redox-active phenalenyl-based ligand is reported for the efficient hydrosilylation of esters to alcs. using polymethylhydrosiloxane as the inexpensive silane source under mild conditions. Mechanistic investigations suggest a strong ligand-metal cooperation where a ligand-based single electron transfer (SET) process initiates the reaction through Si-H bond activation.
Chemical Communications (Cambridge, United Kingdom) published new progress about Alcohols Role: SPN (Synthetic Preparation), PREP (Preparation). 110-42-9 belongs to class esters-buliding-blocks, name is Methyl decanoate, and the molecular formula is C11H22O2, SDS of cas: 110-42-9.
Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics