Yang, Xintuo published the artcilePalladium(II)-Catalyzed Enantioselective Hydrooxygenation of Unactivated Terminal Alkenes, Application In Synthesis of 583-04-0, the main research area is terminal alkene carboxylic acid palladium catalyst enantioselective hydrooxygenation; ester preparation.
A novel Pd(II)-catalyzed enantioselective Markovnikov hydrooxygenation of unactivated terminal alkenes using a substituted pyridinyl oxazoline (Pyox) ligand was developed. Herein it was discovered that the (EtO)2MeSiH/BQ redox system is vital for the highly selective and efficient hydrooxygenation, where the alkylpalladium(II) species generated from enantioselective oxypalladation step was reduced by silane. This method provides efficient access to optically pure alc. esters from easily available alkenes with excellent enantioselectivities and features a broad substrate scope.
Journal of the American Chemical Society published new progress about Alcohols Role: SPN (Synthetic Preparation), PREP (Preparation). 583-04-0 belongs to class esters-buliding-blocks, name is Allyl benzoate, and the molecular formula is C10H10O2, Application In Synthesis of 583-04-0.
Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics