Li, Nan published the artcileCobalt-Catalyzed Deprotection of Allyl Carboxylic Esters Induced by Hydrogen Atom Transfer, Related Products of esters-buliding-blocks, the main research area is carboxylic acid preparation chemoselective; allyl carboxylic ester deprotection cobalt catalyst.
A brief, efficient method has been developed for the removal of the allyl protecting group from allyl carboxylic esters RC(O)OCH2CH=CH2 (R = cyclohexyl, Ph, thiophen-2-yl, 2H-1,3-benzodioxol-5-yl, etc.) using a Co(II)/TBHP/(Me2SiH)2O catalytic system. This facile strategy displays excellent chemoselectivity, functional group tolerance, and high yields. This transformation probably occurs through the hydrogen atom transfer process, and a Co(III)-six-membered cyclic intermediate is recommended.
Organic Letters published new progress about Carboxylic acids Role: SPN (Synthetic Preparation), PREP (Preparation). 583-04-0 belongs to class esters-buliding-blocks, name is Allyl benzoate, and the molecular formula is C10H10O2, Related Products of esters-buliding-blocks.
Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics