Julia, Marc published the artcileOxidation of carbanions with lithium tert-butyl peroxide, Name: Ethyltert-butylacetate, the publication is Synlett (1993), 233-4, database is CAplus.
Lithium tert-Bu peroxide reacts with several carbanions, leading to the corresponding alcs. via oxygen transfer. Lithiated arenes can be converted into phenols. An easy and convenient preparation of ynolates opening the way to ketenes, esters or silyl ynol ethers from acetylides is reported. Lithiated hydroperoxides display an electrophilic behavior at oxygen that can be compared with the electrophilic properties of carbenoids.
Synlett published new progress about 5340-78-3. 5340-78-3 belongs to esters-buliding-blocks, auxiliary class Aliphatic Chain, name is Ethyltert-butylacetate, and the molecular formula is C8H16O2, Name: Ethyltert-butylacetate.
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