Dias, Luiz C.’s team published research in Synlett in | CAS: 106391-88-2

Synlett published new progress about 106391-88-2. 106391-88-2 belongs to esters-buliding-blocks, auxiliary class Amine,Aliphatic hydrocarbon chain,Amide,Aldehyde, name is (R)-tert-Butyl (3-methyl-1-oxobutan-2-yl)carbamate, and the molecular formula is C10H19NO3, Quality Control of 106391-88-2.

Dias, Luiz C. published the artcileChiral allylsilane additions to chiral N-Boc-α-amino aldehydes, Quality Control of 106391-88-2, the publication is Synlett (2000), 37-40, database is CAplus.

Addition of chiral allylsilane (S)-Me3SiCH2C(:CH2)CHMeCH2OCH2Ph to chiral N-(tert-butoxycarbonyl) α-amino aldehydes in the presence of SnCl4 in CH2Cl2 at -78° affords 1,2-syn homoallylic alcs., potential intermediates for the synthesis of hydroxyethylene peptide isosteres. The diastereoselectivity depends on the aldehyde absolute configuration, with (R)-α-amino aldehydes (matched case/anti-Felkin addition) exhibiting higher stereoselectivity than its enantiomer (mismatched case/Felkin addition).

Synlett published new progress about 106391-88-2. 106391-88-2 belongs to esters-buliding-blocks, auxiliary class Amine,Aliphatic hydrocarbon chain,Amide,Aldehyde, name is (R)-tert-Butyl (3-methyl-1-oxobutan-2-yl)carbamate, and the molecular formula is C10H19NO3, Quality Control of 106391-88-2.

Referemce:
https://en.wikipedia.org/wiki/Ester,
Ester – an overview | ScienceDirect Topics