Liu, Yixuan published the artcileCatalytic Stereoselective Conversion of Biomass-Derived 4′-Methoxypropiophenone to Trans-Anethole with a Bifunctional and Recyclable Hf-Based Polymeric Nanocatalyst, Application In Synthesis of 539-88-8, the main research area is methoxypropiophenone transanethole hafnium polymeric nanocatalyst catalytic stereoselective conversion; bifunctional catalysis; biomass conversion; dehydration; transfer hydrogenation; unconventional MOFs/polymeric materials.
Anethole (AN) is widely used as an odor cleaner in daily necessities, and can also be applied in the fields of food additives, drug synthesis, natural preservatives, and polymeric materials′ preparation Considering environmental and economic benefits, the use of biomass raw materials with non-precious metal catalysts to prepare high-value fine chems. is a very promising route. Here, we developed an acid-base bifunctional polymeric material (PhP-Hf (1:1.5)) composed of hafnium and phenylphosphonate in a molar ratio of 1:1.5 for catalytic conversion of biomass-derived 4′-methoxypropiophenone (4-MOPP) to AN via cascade Meerwein-Pondorf-Verley (MPV) reduction and dehydration reactions in a single pot. Compared with the traditional catalytic systems that use high-pressure hydrogen as a hydrogen donor, alc. can be used as a safer and more convenient hydrogen source and solvent. Among the tested alcs., 2-pentanol was found to be the best candidate in terms of pronounced selectivity. A high AN yield of 98.1% at 99.8% 4-MOPP conversion (TOF: 8.5 h-1) could be achieved over PhP-Hf (1:1.5) at 220 °C for 2 h. Further exploration of the reaction mechanism revealed that the acid and base sites of PhP-Hf (1:1.5) catalyst synergistically promote the MPV reduction step, while the Bronsted acid species significantly contribute to the subsequent dehydration step. In addition, the PhP-Hf polymeric nanocatalyst can be recycled at least five times, showing great potential in the catalytic conversion of biomass.
Polymers (Basel, Switzerland) published new progress about Biomass. 539-88-8 belongs to class esters-buliding-blocks, name is Ethyl 4-oxopentanoate, and the molecular formula is C7H12O3, Application In Synthesis of 539-88-8.
Referemce:
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Ester – an overview | ScienceDirect Topics