Garmendia, Sofiem published the artcileSelf-catalyzed folding of single chain nanoparticles (SCNPs) by NHC-mediated intramolecular benzoin condensation, Application of Benzyl acetate, the main research area is styrene vinylbenzaldehyde vinylbenzylethylbenzimidazolium chloride based catalyst benzyl acetate preparation.
A self-catalyzed folding strategy to form single chain nanoparticles (SCNPs) was developed via an intramol. N-heterocyclic carbene (NHC)-mediated benzoin condensation. Benzaldehyde, styrene and benzimidazolium chloride units were randomly incorporated into a poly(ionic liquid)-based (PIL) copolymer precursor by reversible addition-fragmentation chain transfer (RAFT) copolymerization Post-chem. modification of this linear precursor by insertion of a non-innocent acetate counter-anion into the benzimidazolium moieties conferred thermolatent catalytic behavior owing to the equilibrium between benzimidazolium acetate units and corresponding NHC ones. Upon heating, catalytically active NHCs allowed the formation of benzoin-type intramol. cross-links, thus folding linear chains into SCNPs. NHC moieties became deactivated after cooling to room temperature, which enabled easy isolation and purification of the covalently and intramolecularly cross-linked SCNPs. Importantly, the latent NHC moieties were proven to retain their catalytic activity when arranged into SCNPs as evidenced through their reactivation by simple heating. The catalytic activity of these SCNPs was further confirmed by implementing another NHC-organocatalyzed reaction, namely, transesterification reaction between vinyl acetate and benzyl alc. This work represents the first example of catalysis by a parent linear precursor which drives its own folding and remains catalytically active.
Polymer Chemistry published new progress about Hydrodynamic radius. 140-11-4 belongs to class esters-buliding-blocks, name is Benzyl acetate, and the molecular formula is C9H10O2, Application of Benzyl acetate.
Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics