Tetrabutylammonium Iodide/I2 Mediated Convenient and Green Synthesis of Substituted Organic Isothiocyanates was written by Srivastava, Nitin. And the article was included in Organic Preparations and Procedures International in 2021.Computed Properties of C4H7NS The following contents are mentioned in the article:
An efficient process for the synthesis of organic isothiocyanates RNCS (R = t-Bu, cyclohexyl, 1-naphthyl, etc.) by reacting substituted amines RNH2 with carbon disulfide in the presence of tetrabutylammonium iodide (TBAI) as a phase transfer catalyst and by using iodine as an inexpensive and readily available desulfurizing agent has been reported. This study involved multiple reactions and reactants, such as Isopropylisothiocyanate (cas: 2253-73-8Computed Properties of C4H7NS).
Isopropylisothiocyanate (cas: 2253-73-8) belongs to esters. Esters perform as high-grade solvents for a broad array of plastics, plasticizers, resins, and lacquers, and are one of the largest classes of synthetic lubricants on the commercial market. Polyesters are important plastics, with monomers linked by ester moieties. Many esters have the potential for conformational isomerism, but they tend to adopt an s-cis (or Z) conformation rather than the s-trans (or E) alternative, due to a combination of hyperconjugation and dipole minimization effects. The preference for the Z conformation is influenced by the nature of the substituents and solvent, if present. Lactones with small rings are restricted to the s-trans (i.e. E) conformation due to their cyclic structure.Computed Properties of C4H7NS
Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics